rac-2-ethyl-1-trimethylsilyoxy-hexane | 18023-53-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: rac-2-ethyl-1-trimethylsilyoxy-hexane
• 英文别名: 2-ethylhexanol trimethylsilyl ether；(2-ethyl-hexyloxy)-trimethyl-silane；(2-Aethyl-hexyloxy)-trimethyl-silan；Silane, [(2-ethylhexyl)oxy]trimethyl-；2-ethylhexoxy(trimethyl)silane
• CAS: 18023-53-5
• 化学式: C₁₁H₂₆OSi
• 分子量: 202.412
• InChiKey: PDACHFOTOFNHBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.05
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  rac-2-ethyl-1-trimethylsilyoxy-hexane 在 chromium(VI) oxide 作用下， 以 吡啶 、 二氯甲烷 为溶剂， 反应 1.0h， 生成 2-乙基已基醛
  参考文献：
  名称：

  Mahrwald, Rainer; Theil, Fritz; Schick, Hans, Journal fur praktische Chemie (Leipzig 1954), 1986, vol. 328, # 5/6, p. 777 - 783

  摘要：

  DOI：
• 作为产物：
  描述：

  2-乙基己醇 、 六甲基二硅氮烷 生成 rac-2-ethyl-1-trimethylsilyoxy-hexane
  参考文献：
  名称：

  Consensus Among Economists: Revisited

  摘要：

  The authors explore consensus among economists on specific propositions on the basis of a fall 2000 survey of American Economic Association members. Because some propositions are drawn from earlier studies, the results illustrate the dynamics of opinion within the profession. The authors generally find consensus within the profession, although the degree of consensus varies between propositions that are international, macroeconomic, and microeconomic in nature. Consensus is particularly strong for propositions of free international trade and capital flows. In contrast, macroeconomic propositions exhibit a lower degree of consensus, partly because of increased agreement with monetarist and supply-side propositions over time. The profession displays substantial skepticism concerning claims of the "New Economy.".

  DOI：

  10.1080/00220480309595230

文献信息

• Clean nitrations: Novel syntheses of nitramines and nitrate esters by nitrodesilylation reactions using dinitrogen pentoxide (N 2 O 5 )
  作者：Ross W. Millar、Simon P. Philbin

  DOI：10.1016/s0040-4020(97)00093-8

  日期：1997.3

  with conventional substrates (amines or alcohols). These nitrodesilylation reactions proceed cleanly and in good yield, and the scope of the reaction is illustrated by. 29 examples, some of which produce high energy compounds, notably plasticisers and an energetic polymer precursor. These reactions are therefore potentially clean nitrations for the manufacture of energetic compounds which will minimise

  在这种新型的硝化方法中，使用惰性溶剂中的五氧化二氮（N 2 O 5）作为硝化剂，从而无需使用强酸作为反应介质。N 2 O 5分别在甲硅烷基胺和甲硅烷基醚中裂解杂原子-硅键，得到所需的高能基团（分别为硝胺或硝酸酯），而不会释放常规底物（胺或醇）会发生的酸。这些氮代甲硅烷基化反应清洁且收率良好，反应范围如下所示。29个实例，其中一些可以生产高能化合物，尤其是增塑剂和高能聚合物前体。因此，这些反应是潜在的清洁硝化反应，可用于生产高能化合物，这将在将来最大程度地降低这种活性对环境的影响。
• Reaction of Carbonyl Compounds with Trialkylsilyl Phenylselenide and Tributylstannyl Hydride under Radical Conditions
  作者：Yutaka Nishiyama、Hiroyuki Kajimoto、Kazuya Kotani、Takuma Nishida、Noboru Sonoda

  DOI：10.1021/jo025681q

  日期：2002.8.1

  of carbonyl compounds has been developed. When carbonyl compounds were allowed to react with trimethylsilyl phenylselenide and tributylstannyl hydride in the presence of a catalytic amount of AIBN as the radical initiator, hydrosilylation of the carbonyl compounds efficiently proceeded to give the corresponding silyl ethers in moderate to good yields. In the absence of carbonyl compounds, the triethylsilyl

  已经开发出一种用于羰基化合物的氢化硅烷化的新方法。当在催化量的AIBN作为自由基引发剂的存在下使羰基化合物与三甲基甲硅烷基苯基硒化物和三丁基锡烷基氢化物反应时，羰基化合物的氢化硅烷化有效地进行，以中等至良好的产率得到了相应的甲硅烷基醚。在不存在羰基化合物的情况下，通过PhSeSiEt（3）与Bu（3）SnH的反应获得氢化三乙基甲硅烷基。尽管在自由基条件下在苯甲醛存在下用三丁基锡锡氢化物处理了三丁基锗烷基苯硒化物而不是PhSeSiMe（3），但未获得氢化麦芽酰化的产物，并且主要形成了三丁基锗锡氢化物。
• Jin, Tong-Shou; Li, Yan-Wei; Sun, Guang, Journal of Chemical Research - Part S, 2002, # 9, p. 456 - 458
  作者：Jin, Tong-Shou、Li, Yan-Wei、Sun, Guang、Li, Tong-Shuang

  DOI：——

  日期：——
• MAHRWALD R.; THEIL F.; SCHICK H.; SCHWARZ S.; PALME H. -J.; WEBER G., J. PRAKT. CHEM., 328,(1986) N 5-6, 777-783
  作者：MAHRWALD R.、 THEIL F.、 SCHICK H.、 SCHWARZ S.、 PALME H. -J.、 WEBER G.

  DOI：——

  日期：——
• Consensus Among Economists: Revisited
  作者：Dan Fuller、Doris Geide-stevenson

  DOI：10.1080/00220480309595230

  日期：2003.1

  The authors explore consensus among economists on specific propositions on the basis of a fall 2000 survey of American Economic Association members. Because some propositions are drawn from earlier studies, the results illustrate the dynamics of opinion within the profession. The authors generally find consensus within the profession, although the degree of consensus varies between propositions that are international, macroeconomic, and microeconomic in nature. Consensus is particularly strong for propositions of free international trade and capital flows. In contrast, macroeconomic propositions exhibit a lower degree of consensus, partly because of increased agreement with monetarist and supply-side propositions over time. The profession displays substantial skepticism concerning claims of the "New Economy.".