Cyclohexylmethylphenylchlorsilan | 64358-61-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Cyclohexylmethylphenylchlorsilan
• 英文别名: chlorocyclohexylmethylphenylsilane；Chloro-cyclohexyl-methyl-phenylsilane
• CAS: 64358-61-8
• 化学式: C₁₃H₁₉ClSi
• 分子量: 238.832
• InChiKey: RRIJYGKANSGTOP-UHFFFAOYSA-N

物化性质

• 沸点：
  302.7±11.0 °C(Predicted)
• 密度：
  1.02±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.04
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Cyclohexylmethylphenylchlorsilan 在 lithium 、 sodium iodide 作用下， 以 丁酮 为溶剂， 反应 9.0h， 生成 2-[(cyclohexyl-methyl-phenylsilyl)methoxy]-N,N-diethylethanamine
  参考文献：
  名称：

  Ruehlmann, Klaus; Schilling, Petra, Zeitschrift fur Chemie, 1986, vol. 26, # 12, p. 447 - 448

  摘要：

  DOI：
• 作为产物：
  描述：

  溴代环己烷 、 甲基苯基二氯硅烷 在 magnesium 作用下， 生成 Cyclohexylmethylphenylchlorsilan
  参考文献：
  名称：

  Ruehlmann, Klaus; Schilling, Petra, Zeitschrift fur Chemie, 1986, vol. 26, # 12, p. 447 - 448

  摘要：

  DOI：

文献信息

• TRANSITION METAL COMPLEX, PREPARATION METHOD FOR SAID TRANSITION METAL COMPLEX, TRIMERIZATION CATALYST, PREPARATION METHOD FOR 1-HEXENE, PREPARATION METHOD FOR ETHYLENE POLYMER, SUBSTITUTED CYCLOPENTADIENE COMPOUND, AND PREPARATION METHOD FOR SAID SUBSTITUTED CYCLOPENTADIENE COMPOUND
  申请人：Sumitomo Chemical Co., Ltd

  公开号：EP2484685B1

  公开（公告）日：2017-11-01
• Desymmetrization of Cyclohexadienylsilanes. Regio-, Diastereo-, and Enantioselective Access to Sugar Mimics
  作者：Rémy Angelaud、Odile Babot、Trevor Charvat、Yannick Landais

  DOI：10.1021/jo991225z

  日期：1999.12.1

  Desymmetrization of cyclohexadienylsilanes available from Birch reduction of the corresponding arylsilanes is efficiently carried out using Sharpless asymmetric dihydroxylation and aminohydroxylation. Complete diastereocontrol and reasonable enantiocontrol have been attained during the preparation of the desired diols. An excellent regiocontrol has also been observed during aminohydroxylation of dienylsilanol 6b. The resulting diol 8 and hydroxycarbamate 27 have then been elaborated further, offering a straightforward access to various types of cyclitols, aminocyclitols, carbasugars, as well as the antibiotic palitantine 4. The complete functionalization of the original arylsilanes 5 is thus typically achieved in fewer than eight steps with high stereoselectivities and excellent overall yield.
• RUHLMANN K.; SCHILLING P., Z. CHEM., 26,(1986) N 12, 447-448
  作者：RUHLMANN K.、 SCHILLING P.

  DOI：——

  日期：——
• Ruehlmann, Klaus; Schilling, Petra, Zeitschrift fur Chemie, 1986, vol. 26, # 12, p. 447 - 448
  作者：Ruehlmann, Klaus、Schilling, Petra

  DOI：——

  日期：——