tert-butylsulfanyl tributyltin | 23728-82-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: tert-butylsulfanyl tributyltin
• 英文别名: Tributylstannyl tert-butyl sulfide；tributyl(tert-butylthio)stannane；Tri-n-butylzinn-tert-butylmercaptid；(n-Bu)3SnS(t-Bu)；tributyl[(1,1-dimethylethyl)thio]stannane；(tert-butylsulphanyl)tributyltin；tributyl(tert-butylsulfanyl)stannane
• CAS: 23728-82-7
• 化学式: C₁₆H₃₆SSn
• 分子量: 379.238
• InChiKey: DJWNZDKJIDCCJA-UHFFFAOYSA-M

物化性质

• 沸点：
  110 °C(Press: 0.1 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  6.86
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [RuCl(CO)(PPh3)(η-C5H5)] 、 tert-butylsulfanyl tributyltin 以 甲醇 为溶剂， 以19%的产率得到
  参考文献：
  名称：

  The synthesis of several new cyclopentadienyl-ruthenium t-butyl thiol complexes

  摘要：

  The air-sensitive complexes [CpRu(L)(L')(HSBu(t)]PF6 (L = L' = PPh(OMe)2, PPh2OMe, P(OMe)3; L = PPh3, L' = CO, P(OMe)3) are prepared by heating methanol solutions of CpRu(L)(L')Cl, HSBu(t), and NH4PF6. The cyclopentadienyl-ruthenium thiol complexes oxidized in air to form paramagnetic complexes, one of which, [CpRu(PPh2OMe)2SBu(t)]PF6, was isolated and characterized by a single crystal x-ray diffraction study. Crystals are monoclinic with space group P2(1)/c, a = 12.8070(25), b = 14.3160(36), c = 20.1768(50) angstrom, beta = 97.841(18)-degrees, and Z = 4. Data were refined to R = 0.0452 (6248 reflections). The Ru-S(1) bond length was 2.274(1) angstrom and the Ru-P bond lengths were 2.298(1) and 2.291(1) angstrom. The synthesis of CpRu(CO)(PPh3)SBu(t) is also reported.

  DOI：

  10.1016/0022-328x(91)86205-5
• 作为产物：
  描述：

  叔丁基硫醇 、 三丁基氧化锡 以 甲苯 为溶剂， 以80%的产率得到tert-butylsulfanyl tributyltin
  参考文献：
  名称：

  Thunecke, Frank; Schulze, Dirk; Borsdorf, Rolf, Zeitschrift fur Chemie, 1990, vol. 30, p. 444 - 445

  摘要：

  DOI：

文献信息

• Facile preparation of thiol esters from organotin mercaptides and acyl chlorides
  作者：David N. Harpp、T. Aida、T.H. Chan

  DOI：10.1016/s0040-4039(01)86433-9

  日期：——

  Organotin mercaptides condense with acyl chlorides to give thiol esters in excellent yield. Of note are efficient syntheses of -butyl and phenyl thiol esters.

  有机锡硫醇盐与酰氯缩合，以优异的收率得到硫醇酯。值得注意的是-丁基和苯基硫醇酯的有效合成。
• Synthesis and reactivity of rhenium carbonyl thiolate complexes, Et4N[Re2(μ-SR)3(CO)6]
  作者：P.M. Treichel、M.H. Tegen

  DOI：10.1016/0022-328x(88)87088-8

  日期：1988.12

  Compounds of the formula Et4N[Re2(μ-SR)3(CO)6], (R  Me, But, Ph, C6F5) may be prepared in good yields from reactions between various halocarbonylrhenate anions and either the thiolate anion or (n-Bu)3SnSR. These stable, white or off-white, Crystalline species undergo reactions with [Me3O]BF4 in the presence of phosphines to form cis-Re2(μ-SR)2(CO)6(L)2 (L  PMe3, PPh3, 12 dppm). When heated in benzene

  式Et 4 N [Re 2（μ-SR）3（CO）6 ]，（RMe，Bu t，Ph，C 6 F 5）的化合物可以由各种卤代羰基金属酸根阴离子与硫醇根阴离子或（n-Bu）3 SnSR。这些稳定的白色或类白色结晶物质在膦存在下与[Me 3 O] BF 4反应，形成顺式-Re 2（μ-SR）2（CO）6（L）2（LPMe 3，PPH 3，12 dppm）。当在苯中加热时，这些化合物会转化为反式异构体。相反，当它们在四氢呋喃中加热时，一氧化碳会流失，并且会分离出Re 2（μ-SR）2（μ-CO）（CO）4（L）2物质。
• SULFINYLAMINOBENZAMIDE AND SULFONYLAMINOBENZAMIDE DERIVATIVES
  申请人：Gilead Sciences, Inc.

  公开号：US20190359565A1

  公开（公告）日：2019-11-28

  Provided is a compound of Formula (I): wherein the variable groups are defined herein.

  提供的是一个化合物的化学式（I）：其中变量基团在此处定义。
• Palladium catalysed elaboration of codeine and morphine
  作者：Stephen G. Davies、Christopher J. Goodwin、Dirk Pyatt、Andrew D. Smith

  DOI：10.1039/b102581n

  日期：——

  Palladium catalysed coupling reactions of 6-O-tert-butyldimethylsilyl-1-bromocodeine and 6-O-tert-butyldimethylsilyl-3-trifluoromethylsulfonylmorphine allow a range of substituted analogues of codeine in the 1-position and morphine in the 3-position to be efficiently and selectively prepared.

  通过钯催化 6-O-叔丁基二甲基硅烷-1-溴可待因和 6-O-叔丁基二甲基硅烷-3-三氟甲基磺酰基吗啡的偶联反应，可以高效、选择性地制备一系列 1 位可待因和 3 位吗啡的取代类似物。
• McMurry intermolecular cross-coupling between an ester and a ketone: scope and limitations
  作者：Stéphane Sabelle、Jérôme Hydrio、Eric Leclerc、Charles Mioskowski、Pierre-Yves Renard

  DOI：10.1016/s0040-4039(02)00617-2

  日期：2002.5

  were faced with the synthesis of sterically hindered benzylic enol ethers. This issue was solved via the use of an intermolecular McMurry cross-coupling between an ester and a ketone. In this article, together with the synthesis of the chemiluminescent probe, the scope and limitations of this low valent titanium based carboncarbon double bond formation are discussed.

  在关于合成用于检测硫醇的带有二氧杂环丁烷的化学发光探针的研究过程中，我们面临着位阻苄基烯醇醚的合成。通过使用酯和酮之间的分子间McMurry交叉偶联解决了这个问题。在本文中，连同化学发光探针的合成，讨论了这种低价钛基碳碳双键形成的范围和局限性。