bis-(4-amino-3-methyl-phenyl)-diazene | 61594-49-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: bis-(4-amino-3-methyl-phenyl)-diazene
• 英文别名: 4.4'-Diamino-3.3'-dimethyl-azobenzol；Bis-(4-amino-3-methyl-phenyl)-diazen；2-Amino-5-azotoluol；4,4'-Diamino-3,3'-dimethylazobenzene；4-[(4-amino-3-methylphenyl)diazenyl]-2-methylaniline
• CAS: 61594-49-8
• 化学式: C₁₄H₁₆N₄
• 分子量: 240.308
• InChiKey: FLVSXYLSQXAKLN-UHFFFAOYSA-N

物化性质

• 沸点：
  468.9±45.0 °C(Predicted)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  76.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis-(4-amino-3-methyl-phenyl)-diazene 在 ammonium acetate 、 锌 作用下， 以 甲醇 为溶剂， 反应 0.08h， 以92%的产率得到2,5-二氨基甲苯
  参考文献：
  名称：

  Srinivasa; Abiraj; Gowda, D. Channe, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2004, vol. 43, # 1, p. 192 - 195

  摘要：

  DOI：
• 作为产物：
  描述：

  1-萘酚-4-磺酸 、 alkaline earth salt of/the/ methylsulfuric acid 生成 bis-(4-amino-3-methyl-phenyl)-diazene
  参考文献：
  名称：

  Rosenstiehl, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1901, vol. 132, p. 987

  摘要：

  DOI：

文献信息

• DE62352
  申请人：——

  公开号：——

  公开（公告）日：——
• Variable Noninnocence of Substituted Azobis(phenylcyanamido)diruthenium Complexes
  作者：Mohommad M. R. Choudhuri、Mahdi Behzad、Mousa Al-Noaimi、Glenn P. A. Yap、Wolfgang Kaim、Biprajit Sarkar、Robert J. Crutchley

  DOI：10.1021/ic502487x

  日期：2015.2.16

  The synthetic chemistry of substituted 4,4'-azobis(phenylcyanamide) ligands was investigated, and the complexes [Ru(tpy)(bpy)}(2)(mu-L)][PF6](2), where L = 2,2':5,5'-tetramethyl-4,4'-azobis(phenylcyanamido) (Me4adpc(2)), 2,2'-dimethyl-4,4'-azobis(phenylcyanamido) (Me(2)adpc(2)), unsubstituted (adpc2), 3,3'-dichloro-4,4'-azobis(phenylcyanamido) (Cl(2)adpc(2)), and 2,2':5,5'-tetrachloro-4,4'-azobis(phenylcyanamido) (Cl(4)adpc(2)), were prepared and characterized by cyclic voltammetry and visnear-IR (NIR) and IR spectroelectrochemistry. The room temperature electron paramagnetic resonance spectrum of [Ru(tpy)(bpy)}(2)(mu-Me(4)adpc)](3+) showed an organic radical signal and is consistent with an oxidation-state description [Ru-II, Me(4)adpc, Ru-II](3+), while that of [Ru(tpy)(bpy)}(2)(mu-Cl(2)adpc)](3+) at 10 K showed a low-symmetry Ru-III signal, which is consistent with the description [Ru-III, Cl(2)adpc(2), Ru-II](3+). IR spectroelectrochemistry data suggest that [Ru(tpy)(bpy)}(2)(mu-adpc)](3+) is delocalized and [Ru(tpy)(bpy)}(2)(mu-Cl(2)adpc)](3+) and [Ru(tpy)(bpy)}(2)(mu-Cl(4)adpc)](3+) are valence-trapped mixed-valence systems. A NIR absorption band that is unique to all [Ru(tpy)(bpy)}(2)(mu-L)](3+) complexes is observed; however, its energy and intensity vary depending on the nature of the bridging ligand and, hence, the complexes oxidation-state description.
• Srinivasa; Abiraj; Gowda, D. Channe, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2004, vol. 43, # 1, p. 192 - 195
  作者：Srinivasa、Abiraj、Gowda, D. Channe

  DOI：——

  日期：——
• Rosenstiehl, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1901, vol. 132, p. 987
  作者：Rosenstiehl

  DOI：——

  日期：——