11-[4-(phenylazo)phenyloxy]undecanamide | 500313-24-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 11-[4-(phenylazo)phenyloxy]undecanamide
• 英文别名: 11-(4-phenyldiazenylphenoxy)undecanamide
• CAS: 500313-24-6
• 化学式: C₂₃H₃₁N₃O₂
• 分子量: 381.518
• InChiKey: PSECSIIETYEQLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  28
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  77
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  11-[4-(phenylazo)phenyloxy]undecanamide 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 12.0h， 以76%的产率得到4-(11-aminoundecyloxy)azobenzene
  参考文献：
  名称：

  PHOTORESPONSIVE POLYMER, BUILT-UP TYPE DIACETYLENE POLYMER, CRYSTALS OF AMMONIUM CARBOXYLATES, AND PROCESSES FOR PRODUCTION OF THEM

  摘要：

  公开号：

  EP1431266B1
• 作为产物：
  描述：

  11-[4-(phenylazo)phenyloxy]undecanylchloride 在 氨 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 2.0h， 以74%的产率得到11-[4-(phenylazo)phenyloxy]undecanamide
  参考文献：
  名称：

  PHOTORESPONSIVE POLYMER, BUILT-UP TYPE DIACETYLENE POLYMER, CRYSTALS OF AMMONIUM CARBOXYLATES, AND PROCESSES FOR PRODUCTION OF THEM

  摘要：

  公开号：

  EP1431266B1

文献信息

• Photoresponsive polymer, built-up type diacetylene polymer, crystals of ammonium carboxylates, and processes for production of them
  申请人：Matsumoto Akikazu

  公开号：US20050038284A1

  公开（公告）日：2005-02-17

  A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH 2 NH 2 , where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by -Ar-N═N-Ar′-, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtaind. Also obtained is a crystal of ammonium carboxylate including at least one kind of carboxyl acid and at least one kind of amine, at least one kind of compound selected from (i) the at least one kind of carboxyl acid and (ii) the at least one kind of amine being a diacetylene derivative. The crystal of ammonium carboxylate is subjected to light or heat, to obtain a built-up type diacetylene polymer.

  将羧酸晶体和至少一种从胺和氨组成的化合物混合，无需液体介质。羧酸是共轭二烯，例如（Z，Z）-巴苯二酸，共轭二烯包括一个羧基。从胺和氨组成的至少一种含氮化合物是由RCH2NH2表示的一级胺，其中R是芳基，或者是包含五个或更多碳原子的正常烷基。此外，这样的胺是一个双价基团，由-Ar-N═N-Ar'表示，其中Ar和Ar'是独立的芳香族碳氢化合物双价基团，插入到聚巴苯二酸等聚合物的层状晶体中，该层状晶体包括一个羧基。通过这种方式，获得了一种新型光响应性聚合物。同时，获得了至少包含一种羧酸和至少一种胺的羧酸铵晶体，其中来自（i）至少一种羧酸和（ii）至少一种胺的化合物中的至少一种是二乙炔衍生物。将羧酸铵晶体暴露于光或热以获得堆积型二乙炔聚合物。
• Photoresponsive polymer,built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them
  申请人：Matsumoto Akikazu

  公开号：US20090253870A1

  公开（公告）日：2009-10-08

  A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH 2 NH 2 , where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained. Also obtained is a crystal of ammonium carboxylate including at least one kind of carboxyl acid and at least one kind of amine, at least one kind of compound selected from (i) the at least one kind of carboxyl acid and (ii) the at least one kind of amine being a diacetylene derivative. The crystal of ammonium carboxylate is subjected to light or heat, to obtain a built-up type diacetylene polymer.

  将羧酸晶体和至少一种从胺和氨组成的化合物混合在无液介质的情况下。羧酸是共轭二烯，例如(Z,Z)-巨环酸，共轭二烯包括一个羧基。从胺和氨组成的至少一种含氮化合物是由RCH2NH2表示的一级胺，其中R是芳基，或者是含有五个或更多碳原子的正常烷基。此外，这样的胺是一个双价基团，由—Ar—N═N—Ar′—表示，其中Ar和Ar′是独立的芳香族碳氢双价基团，被插入在聚合物的分层晶体中，例如聚巨环酸，分层晶体包括一个羧基。通过这种方式，获得了一种新型的光响应聚合物。同时获得了一种羧酸铵晶体，包括至少一种羧酸和至少一种胺，从(i)至少一种羧酸和(ii)至少一种胺中选出的至少一种化合物是二乙炔衍生物。将羧酸铵晶体经过光或热处理，获得一个堆积型二乙炔聚合物。
• Photoresponsive polymer, built-up type diacetylene polymer, crystal of ammonium carboxylate, and method for manufacturing them
  申请人：Japan Science and Technology Agency

  公开号：US07750084B2

  公开（公告）日：2010-07-06

  A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained. Also obtained is a crystal of ammonium carboxylate including at least one kind of carboxyl acid and at least one kind of amine, at least one kind of compound selected from (i) the at least one kind of carboxyl acid and (ii) the at least one kind of amine being a diacetylene derivative. The crystal of ammonium carboxylate is subjected to light or heat, to obtain a built-up type diacetylene polymer.

  将一个羧酸晶体和至少一种从胺和氨组成的化合物混合，不需要液体介质。羧酸是共轭二烯，例如（Z，Z）-巴苯二酸，共轭二烯包括一个羧基。从胺和氨组成的至少一种含氮化合物是由RCH2NH2表示的一级胺，其中R是芳基，或者是包含五个或更多碳原子的正常烷基。此外，这种胺是一个双价基团，由—Ar—N═N—Ar′—表示，其中Ar和Ar′是独立的芳香族碳氢双价基团，插入在聚巴苯二酸等聚合物的层状晶体中，该层状晶体包括一个羧基。通过这种方式，得到了一种新型光响应性聚合物。同时，得到了一种含有至少一种羧酸和至少一种胺的铵盐晶体，至少一种化合物从（i）至少一种羧酸和（ii）至少一种胺中选择，为二乙炔衍生物。将铵盐晶体暴露于光或热，得到了一种堆积型二乙炔聚合物。
• Photoresponsive polymer, built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them
  申请人：Japan Science and Technology Agency

  公开号：US07981968B2

  公开（公告）日：2011-07-19

  A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained.

  将羧酸晶体和至少一种从胺和氨组成的化合物混合，无需液体介质。羧酸是共轭二烯，例如（Z，Z）-须二烯酸，共轭二烯包括一个羧基。从胺和氨组成的至少一种含氮化合物是由RCH2NH2表示的一级胺，其中R是芳基，或者是包含五个或更多碳原子的正链烷基。此外，这样的胺是一个双价基团，并且由—Ar—N═N—Ar′—表示，其中Ar和Ar′是独立的芳香族碳氢双价基团，插层在聚须二烯酸等聚合物的层状晶体中，该层状晶体包括一个羧基。通过这种方式，获得了一种新型光响应聚合物。