Perhydrobenzoquinoline

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉类
• 英文名称: Perhydrobenzoquinoline
• 英文别名: 1,2,3,4,4a,5,6,6a,7,8,9,10,10a,10b-tetradecahydrobenzo[h]quinoline
• 化学式: C₁₃H₂₃N
• mdl: MFCD24393606
• 分子量: 193.33
• InChiKey: CJCYBBUYZBIYDB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Catalysts for polymerization or copolymerization of alpha-olefins, catalyst components thereof, and processes for polymerization of alpha-olefins with the catalysts
  申请人：Yoshikiyo Motozo

  公开号：US20050202958A1

  公开（公告）日：2005-09-15

  The invention has an object to provide a catalyst for polymerizing or copolymerizing an α-olefin, catalyst constituent thereof, and method of polymerizing α-olefins with the catalyst, for production of α-olefin polymers or copolymers with high hydrogen response, high polymarization reaction rate, high stereoregularity and excellent melt fluidity. The invention discloses a catalyst constituent of the catalyst for polymerizing or copolymerizing an α-olefin, represented by Formula 37 or 38: Si(OR 1 ) 3 (NR 2 R 3 )  Formula 37 (where in Formula 37, R 1 is a hydrocarbon group with 1 to 6 carbon atoms; R 2 is a hydrocarbon group with 1 to 12 carbon atoms or hydrogen; and R 3 is a hydrocarbon group with 1 to 12 carbon atoms) RNSi(OR 1 ) 3 Formula 38 (where in Formula 38, R 1 is a hydrocarbon group with 1 to 6 carbon atoms; and RN is a cyclicl amino group).

  本发明旨在提供一种用于聚合或共聚α-烯烃的催化剂、其催化剂成分和α-烯烃聚合的方法，用于生产具有高氢响应、高聚合反应速率、高立体规整度和优异熔融流动性的α-烯烃聚合物或共聚物。该发明公开了用于聚合或共聚α-烯烃的催化剂成分，由式37或38表示：Si（OR1）3（NR2R3）  式37（其中，在式37中，R1是具有1至6个碳原子的烃基；R2是具有1至12个碳原子或氢原子的烃基；R3是具有1至12个碳原子的烃基）RNSi（OR1）3  式38（其中，在式38中，R1是具有1至6个碳原子的烃基；RN是环状氨基基团）。
• Process for polymerization of alpha-olefin and alpha-olefin polymer
  申请人：Grand Polymer Co., Ltd.

  公开号：EP0959083A1

  公开（公告）日：1999-11-24

  A method for preparing an α-olefin polymer comprising the step of polymerizing or copolymerizing an α-olefin in the presence of a catalyst containing a solid catalyst constituent (A) which contains magnesium, titanium, a halogen element and an electron donor, an organoaluminum compound constituent (B), an organosilicon compound constituent (C) represented by the following general formula (1); and an organosilicon compound constituent (D) represented by the following general formulas (2) or (3) to prepare an α-olefin polymer         RnSi(OR)4-n     (1) (wherein R is a hydrocarbon group having 1 to 8 carbon atoms, n is integer of 1 or 2)    (wherein R1 is a hydrocarbon group having 1 to 8 carbon atoms, R2 is a hydrocarbon group having 1 to 8 carbon atoms, a hydrocarbylamino group having 2 to 24 carbon atoms, or a hydrocarbylalkoxy group having 1 to 24 carbon atoms, R3N is a polycyclic amino group having 7 to 40 carbon atoms, wherein the carbon atoms and the nitrogen atom form a cyclic skeleton).

  一种制备α-烯烃聚合物的方法，包括以下步骤：在催化剂存在下，使α-烯烃聚合或共聚，该催化剂包含含有镁、钛、卤素元素和电子供体的固体催化剂成分(A)，有机铝化合物成分(B)，由以下通式(1)表示的有机硅化合物成分(C)，以及由以下通式(2)或(3)表示的有机硅化合物成分(D)，以制备α-烯烃聚合物；和由以下通式 (2) 或 (3) 表示的有机硅化合物成分 (D)，以制备 α 烯烃聚合物 RnSi(OR)4-n (1) (其中 R 为具有 1 至 8 个碳原子的烃基，n 为 1 或 2 的整数） (其中 R1 是具有 1 至 8 个碳原子的烃基；R2 是具有 1 至 8 个碳原子的烃基、具有 2 至 24 个碳原子的烃基氨基或具有 1 至 24 个碳原子的烃基烷氧基；R3N 是具有 7 至 40 个碳原子的多环氨基，其中碳原子和氮原子形成环状骨架）。
• POLYPROPYLENE RESIN COMPOSITION
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1647575A1

  公开（公告）日：2006-04-19

  A polypropylene resin composition comprising (A) a crystalline propylene block copolymer having a content of a room temperature n-decane-soluble portion of 15 to 35% by weight and having MFR of 5 to 80 g/10min, in an amount of 94 to 55%, (B) an elastomeric polymer in an amount of 1 to 20% by weight and (C) an inorganic filler in an amount of 5 to 25% by weight, said composition having the property that a ratio of an Izod impact strength (J/m, IZ250-30) of a specimen obtained by maintaining the composition at 250°C for 30 minutes in a molten state in an injection molding machine and then molding the composition, said Izod impact strength being measured after 48 hours from the molding, to an Izod impact strength (J/m, IZ230-3) of a specimen obtained by maintaining the composition at 230°C for 3 minutes in a molten state in the same injection molding machine and then molding the composition by the same method, said Izod impact strength being measured after 48 hours from the molding, satisfies the following formula: 1.0≥(IZ250−30/IZ230−3)≥0.5.

  一种聚丙烯树脂组合物，包括(A)结晶丙烯嵌段共聚物，其室温正癸烷可溶部分含量为 15-35%（重量比），且 MFR 为 5-80g/10min，含量为 94-55%；(B)弹性聚合物，含量为 1-20%（重量比）；以及(C)无机填料，含量为 5-25%（重量比）、IZ250-30）与通过在注塑机中将熔融状态的组合物在 250°C 下保持 30 分钟，然后将组合物成型（所述伊佐德冲击强度在成型 48 小时后测量）而获得的试样的伊佐德冲击强度（J/m、在同一注塑机中，将熔融状态下的组合物在 230°C 下保持 3 分钟，然后用同样的方法将组合物成型，在成型 48 小时后测得的试样的伊佐德冲击强度（J/m，IZ230-3）满足下式：1.0≥(IZ250−30/IZ230−3)≥0.5.
• CATALYST AND CATALYST COMPONENT THEREOF
  申请人：Toho Titanium Co., Ltd.

  公开号：EP3020738A2

  公开（公告）日：2016-05-18

  The invention has an object to provide a catalyst for polymerizing or copolymerizing an α-olefin, catalyst constituent thereof, and method of polymerizing α-olefins with the catalyst, for production of α-olefin polymers or copolymers with high hydrogen response, high polymarization reaction rate, high stereoregularity and excellent melt fluidity. The invention discloses a catalyst constituent of the catalyst for polymerizing or copolymerizing an α-olefin, represented by Formula 37 or 38:          Formula 37     Si(OR1)3(NR2R3) (where in Formula 37 , R1 is a hydrocarbon group with 1 to 6 carbon atoms; R2 is a hydrocarbon group with 1 to 12 carbon atoms or hydrogen; and R3 is a hydrocarbon group with 1 to 12 carbon atoms)          Formula 38     RNSi(OR1)3 (where in Formula 38, R1 is a hydrocarbon group with 1 to 6 carbon atoms; and RN is a cyclic1 amino group).

  本发明的目的是提供一种用于α-烯烃聚合或共聚的催化剂、其催化剂组份以及用该催化剂聚合α-烯烃的方法，以生产具有高氢响应、高聚芳烃反应速率、高立体规整度和优异熔体流动性的α-烯烃聚合物或共聚物。本发明公开了一种用于α-烯烃聚合或共聚的催化剂成分，由式 37 或 38 表示： 式 37 Si(OR1)3(NR2R3) (式 37 中，R1 是具有 1 至 6 个碳原子的烃基；R2 是具有 1 至 12 个碳原子的烃基或 氢；R3 是具有 1 至 12 个碳原子的烃基) 式 38 RNSi(OR1)3 (式 38 中，R1 是具有 1 至 6 个碳原子的烃基；RN 是环 1 氨基）。
• Process for polymerization of alpha-olefin, a poly-alpha-olefin prepared thereby, and anaminosilane compound usable as the constituent of catalyst for the process
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0841348B1

  公开（公告）日：2003-07-02