C3H5Me2SiNH2 | 1338211-95-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: C3H5Me2SiNH2
• 英文别名: 3-[Amino(dimethyl)silyl]prop-1-ene；3-[amino(dimethyl)silyl]prop-1-ene
• CAS: 1338211-95-2
• 化学式: C₅H₁₃NSi
• 分子量: 115.25
• InChiKey: YFLGDNPDRUIQQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.34
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二甲基烯丙基硅烷 在 tris((4,4-dimethyl-2-oxazolinyl)phenylborate) MgMe 、 氨 作用下， 以 苯 为溶剂， 以55%的产率得到C3H5Me2SiNH2
  参考文献：
  名称：

  Tris(oxazolinyl)boratomagnesium-Catalyzed Cross-Dehydrocoupling of Organosilanes with Amines, Hydrazine, and Ammonia

  摘要：

  We report magnesium-catalyzed cross-dehydrocoupling of Si-H and N-H bonds to give Si-N bonds and H-2. A number of silazanes are accessible using this method, as well as silylamines from NH3 and silylhydrazines from N2H4. Kinetic studies of the overall catalytic cycle and a stoichiometric Si-N bond-forming reaction suggest nucleophilic attack by a magnesium amide as the turnover-limiting step.

  DOI：

  10.1021/ja207641b

文献信息

• Tris(oxazolinyl)boratomagnesium-Catalyzed Cross-Dehydrocoupling of Organosilanes with Amines, Hydrazine, and Ammonia
  作者：James F. Dunne、Steven R. Neal、Joshua Engelkemier、Arkady Ellern、Aaron D. Sadow

  DOI：10.1021/ja207641b

  日期：2011.10.26

  We report magnesium-catalyzed cross-dehydrocoupling of Si-H and N-H bonds to give Si-N bonds and H-2. A number of silazanes are accessible using this method, as well as silylamines from NH3 and silylhydrazines from N2H4. Kinetic studies of the overall catalytic cycle and a stoichiometric Si-N bond-forming reaction suggest nucleophilic attack by a magnesium amide as the turnover-limiting step.