1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane | 61204-04-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane
• 英文别名: Benzenamine, 4,4'-(2,2,2-trifluoro-1-phenylethylidene)bis-；4-[1-(4-aminophenyl)-2,2,2-trifluoro-1-phenylethyl]aniline
• CAS: 61204-04-4
• 化学式: C₂₀H₁₇F₃N₂
• 分子量: 342.364
• InChiKey: XESBFJAZUUSMGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane 、 氰化钠 生成 4,4'-(2,2,2-Trifluoro-1-phenylethane-1,1-diyl)dibenzonitrile
  参考文献：
  名称：

  Synthesis of multifunctional triarylfluoroethanes. 1. Condensation of fluoro ketones

  摘要：

  DOI：

  10.1021/jo00427a018
• 作为产物：
  描述：

  2,2,2-三氟苯乙酮 、 aniline hydrochloride 、 苯胺 生成 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane
  参考文献：
  名称：

  Synthesis of multifunctional triarylfluoroethanes. 1. Condensation of fluoro ketones

  摘要：

  DOI：

  10.1021/jo00427a018

文献信息

• AROMATIC ETHER AND ALKYNYL CONTAINING PHTHALONITRILES
  申请人：Laskoski Matthew

  公开号：US20110288254A1

  公开（公告）日：2011-11-24

  Compounds having the formulas below. R is an aromatic-containing group. Each M is an alkali metal. Each m is a positive integer. The value of n is a positive integer. The value p is 0 or 1. If p is 0 then n is 1. A thermoset made by curing a composition containing the below phthalonitrile monomers. A method of reacting a diphenyl acetylene compound with an excess of an aromatic diol in the presence of an alkali metal carbonate to form the above oligomer. A method of reacting a phenoxyphthalonitrile with an acetylene compound to form the phthalonitrile monomer below.

  具有以下化学式的化合物。其中R是含芳香基团的基团。每个M是一种碱金属。每个m是正整数。n的值为正整数。p的值为0或1。如果p为0，则n为1。通过固化含有以下邻苯二腈单体的组合物制成的热固性材料。一种方法是在碱金属碳酸盐的存在下，将二苯乙炔化合物与过量的芳香二醇反应，形成上述寡聚物。一种方法是将苯氧基邻苯二腈与乙炔化合物反应，形成以下邻苯二腈单体。
• Oligomeric hydroxy arylether phthalonitiles and synthesis thereof
  申请人：——

  公开号：US20040181028A1

  公开（公告）日：2004-09-16

  An aromatic ether oligomer or polyaromatic ether comprising the formula: 1 wherein Ar is an independently selected divalent aromatic radical; formed by reacting a dihydroxyaromatic with a dihaloaromatic; and wherein the reaction is performed in the presence of a copper compound and cesium carbonate. The polyaromatic ether is formed when neither the dihydroxyaromatic nor the dihaloaromatic is present in an excess amount. The aromatic ether oligomer is formed by using an excess of either dihydroxyaromatic or dihaloaromatic. A phthalonitrile monomer comprising the formula: 2 formed by reacting a 3- or 4-nitrophthalonitrile with a hydroxy-terminated aromatic ether oligomer. A thermoset formed by curing the phthalonitrile monomer. Processes for forming all the above.

  一种芳香醚寡聚物或聚芳香醚，包括以下公式： 1 其中Ar是独立选择的二价芳香基团；通过将二羟基芳香与二卤代芳香反应形成；反应在铜化合物和碳酸铯的存在下进行。当二羟基芳香和二卤代芳香均不以过量存在时，形成聚芳香醚。当使用过量的二羟基芳香或二卤代芳香时，形成芳香醚寡聚物。一种酞菁单体，包括以下公式： 2 通过将3-或4-硝基酞菁与羟基终止的芳香醚寡聚物反应形成。通过固化酞菁单体形成热固性物。以上所有的形成过程。
• Polycarbonamides of bis (2-(4-carboxyphenyl)hexafluoroisopropyl) - diphenyl ether
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0317940A2

  公开（公告）日：1989-05-31

  The application is directed to linear polycarbonamides derived from the condensation of 4,4'-bis[2-(4-carboxyphenyl)­hexafluoroisopropyl]diphenyl ether or a derivative thereof with a primary diamine; preferably an aromatic diamine. The linear polycarbonamides of the application are useful in preparing molded and extruded articles, films and fibers having high thermal stability, resistance to soiling, excellent mechanical properties, good transparency and radiation stability. In addition, they may be processed into useful articles at lower processing temperatures than the comparable polycarbonamides of the prior art.

  本申请涉及由 4,4'-双[2-(4-羧基苯基)六氟异丙基]二苯醚或其衍生物与伯胺（最好是芳香族二胺）缩合而得的线性聚碳酰胺。本申请中的线性聚碳酸酯可用于制备具有高热稳定性、抗污染性、优异的机械性能、良好的透明度和辐射稳定性的模塑和挤压制品、薄膜和纤维。此外，与现有技术中的同类聚碳酸酯相比，它们可以在较低的加工温度下加工成有用的物品。
• Photosensitive polyimide polymer compositions
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0317941A3

  公开（公告）日：1990-01-10

  A photosensitive polyimide polymer composition comprising a solvent soluble polyimide condensation product of an aromatic dianhydride and an aromatic diamine, a polyfunctional ethylenically unsaturated monomer and a photoinitiator. The solvent soluble polyimides of the composition are prepared from at least one compound selected from 2,2-hexafluoro-bis­(3,4-dicarboxyphenyl)tetracarboxylic dianhydride; 1,1-bis­[4-(1,2-dicarboxyphenyl)]-1-phenyl-2,2,2-trifluoroethane dianhydride; 2,2-hexafluoro-bis(3-aminophenyl)propane; 2,2-hexafluoro-bis(4-aminophenyl)propane; 2,2-hexafluoro-bis­[4-(3-aminophenoxy)phenyl]propane; 2,2-hexafluoro-bis­[4-(4-aminophenoxy)phenyl]propane and 1,1-bis-(4-aminopheny)-­1-phenyl-2,2,2-trifluoroethane or mixtures thereof.

  一种光敏聚酰亚胺聚合物组合物，由芳香族二酐和芳香族二胺的溶剂可溶聚酰亚胺缩合产物、多官能度乙烯基不饱和单体和光引发剂组成。组合物中的溶剂可溶聚酰亚胺由至少一种化合物制备，这些化合物选自 2,2-六氟双（3,4-二羧基苯基）四羧酸二酐、1,1-双[4-（1,2-二羧基苯基）]-1-苯基-2,2,2-三氟乙烷二酐；2,2-六氟双(3-氨基苯基)丙烷；2,2-六氟双(4-氨基苯基)丙烷；2,2-六氟双[4-(3-氨基苯氧基)苯基]丙烷；2,2-六氟双[4-(4-氨基苯氧基)苯基]丙烷和 1,1-双(4-氨基苯基)-1-苯基-2,2,2-三氟乙烷或它们的混合物。
• Polymers prepared from 4,4'-bis-(2-(amino (halo) phenoxyphenyl) hexafluoroisopropyl) diphenyl ether
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0317944A2

  公开（公告）日：1989-05-31

  The application relates to fluorine-containing polyimides, polyamide-acids/esters, polyamides, addition polyimides and imide oligomers which exhibit low melting points, better solubilities, low dielectric constants, superior thermal and thermal oxidative stability, and improved processing characteristics. The products of this application are characterized by the fact that they are derived from 4,4'-bis[2-(amino(halo)phenoxyphenyl)hexafluoroisopropyl]diphenyl ether.

  本申请涉及含氟聚酰亚胺、聚酰胺酸/酯、聚酰胺、加成聚酰亚胺和亚胺低聚物，它们具有低熔点、更好的溶解性、低介电常数、优异的热稳定性和热氧化稳定性，以及更好的加工特性。 这种应用产品的特点是它们来自 4,4'-双[2-（氨基（卤代）苯氧基苯基）六氟异丙基]二苯醚。