2-Bis(2,4,6-trimethylbenzoyl)phosphoryloxyethyl 7-methyl-9-oxothioxanthene-3-carboxylate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 英文名称: 2-Bis(2,4,6-trimethylbenzoyl)phosphoryloxyethyl 7-methyl-9-oxothioxanthene-3-carboxylate
• 英文别名: 2-bis(2,4,6-trimethylbenzoyl)phosphoryloxyethyl 7-methyl-9-oxothioxanthene-3-carboxylate
• 化学式: C₃₇H₃₅O₇PS
• 分子量: 654.7
• InChiKey: BAIZOWUKOAXWDG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  46
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  129
• 氢给体数：
  0
• 氢受体数：
  8

文献信息

• [EN] DERIVATIVES OF BISACYLPHOSPHINIC ACID, THEIR PREPARATION AND USE AS PHOTOINITIATORS<br/>[FR] DÉRIVÉS D'ACIDE BISACYLPHOSPHINIQUE, LEUR PRÉPARATION ET LEUR UTILISATION EN TANT QUE PHOTO-INITIATEURS
  申请人：BASF SE

  公开号：WO2014095724A1

  公开（公告）日：2014-06-26

  Bisacylphosphine oxide or bisacylphosphine sulfide compounds of formula (I) or (II) wherein R1, R2, R3, R1a, R2a and R3a independently of each other are C1-C4alkyl, C1-C4alkoxy or halogen; X is O, NR5 or S; or, if R4 is CI, F or Br, X is a direct bond; Y is O or S; n is 1 or 2; R4, if n is 1, for example is hydrogen, (CO)R6, (CO)OR6, (CO)NR5R6, (SO2)-R6, C1-C28alkyl, R4, if n = 2, is for example C1-C18alkylene; R5 is for example hydrogen, or C1-C12alkyl; R6 is for example C1-C12alkyl; R7, R8 and R9 independently of each other for example are C1-C4alkyl; R10 is for example C2-C18alkylene; X1 is O or S; m is 1, 2 or 3; Q represents one or two inorganic or organic cations with a charge of m+; are suitable photoinitiators, available by a claimed process.

  双酰基膦氧化物或双酰基膦硫化物化合物的结构式（I）或（II），其中R1、R2、R3、R1a、R2a和R3a彼此独立地是C1-C4烷基、C1-C4烷氧基或卤素；X为O、NR5或S；或者，如果R4是CI、F或Br，则X为直接键；Y为O或S；n为1或2；例如，如果n为1，则R4为氢、（CO）R6、（CO）OR6、（CO）NR5R6、（SO2）-R6、C1-C28烷基；如果n=2，则R4为例如C1-C18烷基；例如，R5为氢或C1-C12烷基；例如，R6为C1-C12烷基；例如，R7、R8和R9彼此独立地为C1-C4烷基；例如，R10为C2-C18烷基；X1为O或S；m为1、2或3；Q代表带有m+电荷的一个或两个无机或有机阳离子，是通过声明的过程得到的合适的光引发剂。
• DERIVATIVES OF BISACYLPHOSPHINIC ACID, THEIR PREPARATION AND USE AS PHOTOINITIATORS
  申请人：IGM Group B.V.

  公开号：EP3459957A1

  公开（公告）日：2019-03-27

  Bisacylphosphine oxide or bisacylphosphine sulfide compounds of formula (I) or (II) wherein R1, R2, R3, R1a, R2a and R3a independently of each other are C1-C4alkyl, C1-C4alkoxy or halogen; X is O, NR5 or S; or, if R4 is Cl, F or Br, X is a direct bond; Y is O or S; n is 1 or 2; R4, if n is 1, for example is hydrogen, (CO)R6, (CO)OR6, (CO)NR5R6, (SO2)-R6, C1-C28alkyl, R4, if n = 2, is for example C1-C18alkylene; R5 is for example hydrogen, or C1-C12alkyl; R6 is for example C1-C12alkyl; R7, R8 and R9 independently of each other for example are C1-C4alkyl; R10 is for example C2-C18alkylene; X1 is O or S; m is 1, 2 or 3; Q represents one or two inorganic or organic cations with a charge of m+; are suitable photoinitiators, available by a claimed process.

  式(I)或(II)的双酰基氧化膦或双酰基硫化膦化合物 其中 R1、R2、R3、R1a、R2a 和 R3a 相互独立地为 C1-C4烷基、C1-C4烷氧基或卤素；X 为 O、NR5 或 S；或者，如果 R4 为 Cl、F 或 Br，则 X 为直接键；Y 为 O 或 S；n 为 1 或 2；R4（如果 n 为 1）例如为氢、(CO)R6、(CO)OR6、(CO)NR5R6、(SO2)-R6、C1-C28 烷基，R4（如果 n = 2）例如为 C1-C18 烷基；R5例如是氢，或C1-C12烷基；R6例如是C1-C12烷基；R7、R8和R9彼此独立地例如是C1-C4烷基；R10例如是C2-C18烷烯；X1是O或S；m是1、2或3；Q代表一个或两个电荷为m+的无机或有机阳离子；这些都是适合的光引发剂，可通过所要求的工艺获得。