1,3,5-tris-(2-(3-mercaptopropyloxy)ethyl)isocyanurate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,3,5-tris-(2-(3-mercaptopropyloxy)ethyl)isocyanurate
• 英文别名: 1,3,5-Tris[2-(3-sulfanylpropoxy)ethyl]-1,3,5-triazinane-2,4,6-trione；1,3,5-tris[2-(3-sulfanylpropoxy)ethyl]-1,3,5-triazinane-2,4,6-trione
• 化学式: C₁₈H₃₃N₃O₆S₃
• 分子量: 483.675
• InChiKey: KJQCKIXVHCPAIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  30
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  91.6
• 氢给体数：
  3
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  在 甲醇 、 硫酸 作用下， 以94%的产率得到1,3,5-tris-(2-(3-mercaptopropyloxy)ethyl)isocyanurate
  参考文献：
  名称：

  新規なチオール基を有するイソシアヌレート化合物とその利用

  摘要：

  题目：提供一种含有新的含有硫醇基的异氰酸酯化合物作为硬化剂，具有优异的耐水解性的环氧树脂组合物。 解决方案：提供一种含有1,3,5-三[2-(3-巯基丙氧基)乙基]异氰酸酯作为环氧树脂硬化剂的环氧树脂组合物。 选择图：无

  公开号：

  JP2021004229A

文献信息

• POLYMERIZABLE COMPOSITION CONTAINING REACTIVE FLUORINATED SILICONE COMPOUND
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3127929A1

  公开（公告）日：2017-02-08

  The present invention provides a polymerizable composition suitable for producing a molding that maintains a high refractive index and a low Abbe's number, discoloration (thermal yellowing) resulting from high thermal hysteresis can be reduced, no Tg and a low CTE are exhibited, and has good mold release properties. A polymerizable composition comprising: 100 parts by mass of a reactive silicone compound (a) obtained by polycondensation, in the presence of an acid or a base, of a polycondensable compound containing at least a diarylsilicic acid compound A, an alkoxy silicon compound B having a phenyl group or a naphthyl group having at least one group having a polymerizable double bond, and an alkoxy silicon compound C containing a fluoro group; and 1 part by mass to 200 parts by mass of a (meth) acrylate compound (b), and a cured product and a material for high refractive index resin lens which are obtained from the polymerizable composition.

  本发明提供了一种可聚合组合物，适用于生产保持高折射率和低阿贝数、可减少高热滞后导致的变色（热黄变）、无 Tg 和低 CTE 的模塑件，并具有良好的脱模性能。可聚合组合物包括100 份（质量份）反应性有机硅化合物 (a)，该反应性有机硅化合物是在酸或碱存在下，由至少含有二元硅酸化合物 A、具有苯基或萘基的烷氧基硅化合物 B（该烷氧基硅化合物具有至少一个具有可聚合双键的基团）和含有氟基的烷氧基硅化合物 C 的可缩聚化合物缩聚而成；以及 1 份至 200 份质量的（甲基）丙烯酸酯化合物 (b)，以及由该可聚合组合物得到的固化产品和高折射率树脂透镜材料。
• POLYMERIZABLE COMPOSITION CONTAINING REACTIVE FLUORINE-CONTAINING SILICONE COMPOUND
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20170023704A1

  公开（公告）日：2017-01-26

  A polymerizable composition suitable for producing a molding that maintains a high refractive index and a low Abbe's number, discoloration (thermal yellowing) resulting from high thermal hysteresis can be reduced, no Tg and a low CTE are exhibited, and has good mold release properties. A polymerizable composition having: 100 parts by mass of a reactive silicone compound (a) obtained by polycondensation, in the presence of an acid or a base, of a polycondensable compound containing at least a diarylsilicic acid compound A, an alkoxy silicon compound B having a phenyl group or a naphthyl group having at least one group having a polymerizable double bond, and an alkoxy silicon compound C containing a fluoro group; and 1 part by mass to 200 parts by mass of a (meth) acrylate compound (b), and a cured product and material for high refractive index resin lens which are obtained from the polymerizable composition.
• US8779065B2
  申请人：——

  公开号：US8779065B2

  公开（公告）日：2014-07-15