1-but-3-enyl-3-[2-(oxiran-2-yl)ethyl]-5-[2-[(2S)-oxiran-2-yl]ethyl]-1,3,5-triazinane-2,4,6-trione

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1-but-3-enyl-3-[2-(oxiran-2-yl)ethyl]-5-[2-[(2S)-oxiran-2-yl]ethyl]-1,3,5-triazinane-2,4,6-trione
• 化学式: C₁₅H₂₁N₃O₅
• 分子量: 323.34
• InChiKey: LOANLUNQKIPLOM-PXYINDEMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  23
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  86
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• ISOCYANURATE EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING SAME, COMPOSITION INCLUDING SAME, CURED PRODUCT OF THE COMPOSITION, AND USE OF THE COMPOSITION
  申请人：Korea Institute Of Industrial Technology

  公开号：EP2774929A1

  公开（公告）日：2014-09-10

  The present invention relates to an alkoxysilyl-based isocyanurate epoxy compound, a method of preparing same, a composition including same, a cured product of the composition and a use of the composition. A complex including the compound illustrates good heat resistance, particularly, a low coefficient of thermal expansion (CTE), and a high glass transition temperature or Tg. A cured product of the composition illustrates flame retardancy and does not use a separate silane coupling agent. According to the present invention, an isocyanurate epoxy compound including an alkoxysilyl group and an epoxy group at a core; a method of preparing the epoxy compound prepared by epoxidation and alkoxysilylation of a starting material; an epoxy composition including the epoxy compound; and a cured product of the epoxy composition and a use of the epoxy composition, are provided. In the complex of the composition including the novel alkoxysilyl-based isocyanurate epoxy compound according to the present invention, chemical bonding efficiency may be improved when making a chemical bond between the alkoxysilyl group in the epoxy compound and a filler and when forming an epoxy complex through a chemical bond between alkoxysilyl groups in the epoxy compound having the alkoxysilyl group. Therefore, good heat resistance, that is, a low CTE and a high glass transition temperature or Tg may be shown. In addition, the cured product of the composition including the epoxy compound according to the present invention may show good flame retardancy.

  本发明涉及一种烷氧基硅烷基异氰脲酸酯环氧化合物、一种制备方法、一种包括该化合物的组合物、一种该组合物的固化产品和一种该组合物的用途。包括该化合物的复合物具有良好的耐热性，特别是热膨胀系数（CTE）低，玻璃化转变温度（Tg）高。该组合物的固化产品具有阻燃性，且无需使用单独的硅烷偶联剂。根据本发明，提供了一种异氰脲酸酯环氧化合物，其核心包括一个烷氧基硅烷基团和一个环氧基团；一种通过起始材料的环氧化和烷氧基硅烷化制备该环氧化合物的方法；一种包括该环氧化合物的环氧组合物；以及该环氧组合物的固化产物和该环氧组合物的用途。在包括根据本发明的新型烷氧基硅烷基异氰脲酸酯环氧化合物的组合物的复合物中，当环氧化合物中的烷氧基硅烷基与填料之间形成化学键时，以及当通过具有烷氧基硅烷基的环氧化合物中的烷氧基硅烷基之间的化学键形成环氧复合物时，可提高化学键效率。因此，可显示出良好的耐热性，即较低的 CTE 和较高的玻璃化转变温度或 Tg。此外，根据本发明，包括环氧化合物在内的组合物的固化产品可显示出良好的阻燃性。