nickel monofluoride | 13783-64-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: nickel monofluoride
• 英文别名: nickel fluoride；fluoronickel
• CAS: 13783-64-7
• 化学式: FNi
• 分子量: 77.6884
• InChiKey: GOVXUOILKBXQJW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.42
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  bis(hexafluoroacetylacetonazo)nickel(II) 以 gas 为溶剂， 生成 nickel monofluoride 、 镍
  参考文献：
  名称：

  Luminescent Photofragments of (1,1,1,5,5,5-Hexafluoro-2,4-pentanedionato) Metal Complexes in the Gas Phase

  摘要：

  The luminescence that is observed under gas phase photolytic deposition conditions is studied for Cr(hfac)(3), Ni(hfac)(2), and Pt(hfac)(2). This luminescence is analyzed under a variety of conditions, including the relatively high pressures of an evacuated gas cell and the collision-free conditions of a molecular beam. The effects of inert buffer gas are also studied. Features in these spectra indicate that, in general, multiple photolysis processes occur. Some simple fragments that are produced from these compounds are identified, including bare metal atoms (Ni, Cr), metal monofluorides (NiF, CrF), CH (in the case of Ni(hfac)(2)), and metal carbide from Pt(hfac)(2). It is postulated that the difference in the observed photofragmentation pathway in the case of platinum is due to sigma bonding to the beta carbon of the hfac moiety as opposed to the bidentate bonding of the other two metals. Possible mechanisms are presented. Detailed analysis of the spectra allows characterization of the internal energy of the platinum carbide photofragment.

  DOI：

  10.1021/ic971340x

文献信息

• Devore; McQuaid; Gole, High temperature science, 1990, vol. 30, # 2-3, p. 83 - 94
  作者：Devore、McQuaid、Gole

  DOI：——

  日期：——
• Luminescent Photofragments of (1,1,1,5,5,5-Hexafluoro-2,4-pentanedionato) Metal Complexes in the Gas Phase
  作者：David S. Talaga、Stephen D. Hanna、Jeffrey I. Zink

  DOI：10.1021/ic971340x

  日期：1998.6.1

  The luminescence that is observed under gas phase photolytic deposition conditions is studied for Cr(hfac)(3), Ni(hfac)(2), and Pt(hfac)(2). This luminescence is analyzed under a variety of conditions, including the relatively high pressures of an evacuated gas cell and the collision-free conditions of a molecular beam. The effects of inert buffer gas are also studied. Features in these spectra indicate that, in general, multiple photolysis processes occur. Some simple fragments that are produced from these compounds are identified, including bare metal atoms (Ni, Cr), metal monofluorides (NiF, CrF), CH (in the case of Ni(hfac)(2)), and metal carbide from Pt(hfac)(2). It is postulated that the difference in the observed photofragmentation pathway in the case of platinum is due to sigma bonding to the beta carbon of the hfac moiety as opposed to the bidentate bonding of the other two metals. Possible mechanisms are presented. Detailed analysis of the spectra allows characterization of the internal energy of the platinum carbide photofragment.