6-(三氯甲基)-1,3,5-三嗪-2,4-二胺 | 16088-73-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 6-(三氯甲基)-1,3,5-三嗪-2,4-二胺
• 英文名称: 2,4-diamino-6-trichloromethyl-1,3,5-triazine
• 英文别名: Trichloracetoguanamin；6-trichloromethyl-[1,3,5]triazine-2,4-diamine；6-trichloromethyl-[1,3,5]triazine-2,4-diyldiamine；6-Trichlormethyl-[1,3,5]triazin-2,4-diyldiamin；1,3,5-Triazine-2,4-diamine, 6-(trichloromethyl)-；6-(trichloromethyl)-1,3,5-triazine-2,4-diamine
• CAS: 16088-73-6
• 化学式: C₄H₄Cl₃N₅
• 分子量: 228.468
• InChiKey: QHFYHZBGKSVKIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  90.7
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  6-(三氯甲基)-1,3,5-三嗪-2,4-二胺 、 氨 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Weddige, Journal fur praktische Chemie (Leipzig 1954), 1886, vol. <2> 33, p. 81

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 、 氨 作用下， 生成 6-(三氯甲基)-1,3,5-三嗪-2,4-二胺
  参考文献：
  名称：

  Weddige, Journal fur praktische Chemie (Leipzig 1954), 1886, vol. <2> 33, p. 81

  摘要：

  DOI：

文献信息

• STABILIZED FERTILIZER COMPOSITIONS AND METHODS FOR PREPARING SAME
  申请人：Tessenderlo Kerley, Inc.

  公开号：EP3626697A1

  公开（公告）日：2020-03-25

  Provided in the invention is a stabilized fertilizer composition (I) comprising - Urea (a), - One or more compounds (b), - One or more urease inhibitors (c1) and/or one or more nitrification inhibitors (c2), optionally provided in one or more carriers (d), said compounds (c) being different from compounds (b), - Optionally one or more additives (e) different from any of the above, and - Water (f) in an amount less than about 10 wt% and preferably less than about 5 wt%; wherein compounds (b) are selected from thiosulfates (b1) and/or from polysulfides (b2) and/or from urea-triazone compounds (b3); and wherein the ratio of urea (a) to compounds (b) is from 1:99 to 99:1, preferably from 2:98 to 98:2. Products of the invention can be made in various forms and in different ways. All of the materials of the invention are suitable for use in fertilizers and blend well with solid and liquid fertilizers standardly used. They have excellent shelf life and provide good urea-N protection.

  本发明提供了一种稳定肥料组合物 (I)，其中包括 - 尿素 (a) - 一种或多种化合物 (b) - 一种或多种脲酶抑制剂（c1）和/或一种或多种硝化抑制剂（c2），可选择提供在一种或多种载体（d）中，所述化合物（c）不同于化合物（b）、 - 可选的一种或多种添加剂（e），不同于上述任何一种添加剂，以及 - 水（f），含量小于约 10 wt%，最好小于约 5 wt%； 其中化合物 (b) 选自硫代硫酸盐 (b1) 和/或多硫化物 (b2) 和/或脲三嗪化合物 (b3)；以及 其中脲 (a) 与化合物 (b) 的比例为 1:99 至 99:1，最好为 2:98 至 98:2。 本发明的产品可以用不同的形式和方法制成。本发明的所有材料都适用于肥料，并能与标准使用的固体和液体肥料很好地混合。它们具有极佳的保质期，并提供良好的尿素-N 保护。
• NITRIFICATION INHIBITORS DESIGNED FOR UREA AND MANURE BASED FERTILISERS
  申请人：Mcknight, Gary, David

  公开号：EP3639667A1

  公开（公告）日：2020-04-22

  A composition comprising one or more nitrification inhibitors and one or more urease inhibitors in an organic liquid solvating system comprising a mixture of aprotic solvents wherein a first aprotic solvent is one or more of a) dimethyl sulfoxide, or b) dialkyl sulfoxide, diaryl sulfoxide, or an alkylaryl sulfoxide having the formula R1-S(O)-R2, wherein R1 is methyl, ethyl, n-propyl, phenyl or benzyl and R2 is ethyl, n-propyl, phenyl or benzyl, wherein the organic liquid solvating system meets the following criteria: a. environmentally safe, b. has a flashpoint above 62.8°C (145 ° F), c. inherently rated safe for contact with humans and animals, d. results in a composition comprising at least one of nitrification and urease inhibitors with a Chill Point < 4.4°C (40° F), and e. provide even application to fertilizer granules of urease and/or nitrification inhibitors while not causing clumping of the fertilizer granules. A composition comprising a fertilizer granule and said composition.

  一种组合物，包含在有机液体溶解体系中的一种或多种硝化抑制剂和一种或多种脲酶抑制剂，该有机液体溶解体系包含壬烷溶剂混合物，其中第一壬烷溶剂为 a) 二甲基亚砜，或 b) 二烷基亚砜，或具有式 R1-S(O)-R2 的烷基芳基亚砜中的一种或多种、二芳基亚砜、二芳基亚砜或烷基芳基亚砜，其式为 R1-S(O)-R2，其中 R1 为甲基、乙基、正丙基、苯基或苄基，R2 为乙基、正丙基、苯基或苄基，其中有机液体溶解体系符合以下标准： a. 对环境安全、 b. 闪点高于 62.8°C（145°F）、 c. 与人和动物接触的固有安全等级、 d. 产生一种包含至少一种硝化抑制剂和脲酶抑制剂的组合物，冷点 < 4.4°C (40° F)，以及 e. 将脲酶和/或硝化抑制剂均匀地施用到肥料颗粒上，同时不会造成肥料颗粒结块。 一种由肥料颗粒和所述组合物组成的组合物。
• METHOD FOR PRODUCING AN AMMONIUM-BASED SOLID, PARTICULATE COMPOSITION COMPRISING AN ADDITIVE
  申请人：Yara International ASA

  公开号：EP4015488A1

  公开（公告）日：2022-06-22

  A method is disclosed for producing an ammonium-based solid, particulate composition comprising an additive in a plant comprising a liquid section and a solid section comprising a particulation unit and an effluent gas treatment unit comprising a scrubber, a scrubber solution storage container and optionally a scrubber evaporator, the method comprising the steps of: (a) preparing a melt comprising an ammonium salt in the liquid section of the plant; (b) particulating the melt prepared in step (a) in the particulation unit thereby obtaining an ammonium-based solid, particulate composition and an effluent gas comprising ammonia; (c) preparing an aqueous scrubbing solution; (d) treating the effluent gas comprising ammonia from the particulation unit with the aqueous scrubbing solution prepared in step (c) in the scrubber of the effluent gas treatment unit thereby producing a scrubber solution; (e) storing the scrubber solution produced in step d) in the scrubber solution storage of the effluent gas treatment unit; and (f) optionally, concentrating the scrubber solution from the scrubber solution storage container in the scrubber evaporator thereby obtaining a concentrated scrubber solution; (g) adding the scrubber solution obtained from step e) or f) to the melt comprising an ammonium salt; wherein an additive is added in solid form to any one or more of the aqueous scrubbing solution prepared in step c), the scrubber solution in the scrubber solution storage, or the scrubber concentrator.

  本发明公开了一种方法，用于在包括一个液体部分和一个固体部分的工厂中生产一种铵基固体颗粒组合物，固体部分包括一个颗粒化单元和一个废气处理单元，废气处理单元包括一个洗涤器、一个洗涤器溶液储存容器和可选的一个洗涤器蒸发器，该方法包括以下步骤： (a) 在设备的液体部分制备包含铵盐的熔体； (b) 在微粒化装置中将步骤(a)中制备的熔体微粒化，从而获得铵基固体、微粒成分和含氨的废气； (c) 制备洗涤水溶液； (d) 在废气处理单元的洗涤器中，用步骤(c)中制备的水性洗涤溶液处理来自微粒化单 元的含氨废气，从而产生洗涤溶液； (e) 将步骤(d)中产生的洗涤溶液储存在废气处理装置的洗涤溶液储存器中；以及 (f) 可选地在洗涤器蒸发器中浓缩洗涤器溶液储存容器中的洗涤器溶液， 从而获得浓缩洗涤器溶液； (g) 将从步骤 e) 或 f) 中获得的洗涤溶液添加到包含铵盐的熔体中； 其中添加剂以固体形式添加到步骤 c) 中制备的洗涤水溶液、洗涤溶液储存器中的洗涤溶液或洗涤浓缩器中的任意一种或多种溶液中。
• METHOD FOR THE MANUFACTURE OF A UREA-BASED COMPOSITION COMPRISING THE ADDITION OF A LIQUID-FREE SOLID ADDITIVE
  申请人：Yara International ASA

  公开号：EP4015491A1

  公开（公告）日：2022-06-22

  A method is disclosed for the manufacture of a homogeneous, solid, particulate, urea-based composition comprising urea and an additive in a urea production plant comprising at least an evaporator section and a particulation section, further comprising one or more of a mixing section, an effluent gas treatment section and a scrubber solution storage section, wherein the method comprises at least the steps of : (i) in the evaporator section, concentrating a urea melt of about 80 weight% to about 95 to 99 weight% of urea; (ii) in the particulation section, particulating a urea or urea-based melt into a urea or urea-based composition; and further comprises one or more of steps of: (iii) in the mixing section, if present, mixing the urea melt of about 95 to 99 weight% with other fertilizer components to produce a urea-based melt; (iv) in the effluent gas treatment section, if present, treating the effluent gas from the particulation section comprising urea-based dust particles and ammonia gas with water to produce a scrubber solution; and (v) in the scrubber solution storage section, if present, storing the scrubber solution from the effluent gas treatment section; wherein the additive is introduced into the urea or urea-based composition as a particulate liquid-free solid, by adding the additive to one or more of (a) said urea-based melt in the mixing section, if present; (b) said effluent gas treatment section, if present; and (c) said scrubber solution storage section containing the scrubber solution, if present.

  本发明公开了一种在尿素生产装置中制造均质、固体、微粒、尿素基组合物的方法，该组合物包括尿素和添加剂，该装置至少包括蒸发段和微粒段，还包括混合段、废气处理段和洗涤溶液储存段中的一个或多个，其中该方法至少包括以下步骤： (i) 在蒸发段中，浓缩尿素熔体中约 80%至约 95 至 99%的尿素； (ii) 在微粒段，将尿素或尿素基熔体微粒化成尿素或尿素基组合物； 并进一步包括以下一个或多个步骤 (iii) 在混合段（如有），将约 95 至 99 重量％的尿素熔体与其他肥料成分混合，以产生脲基熔体； (iv) 在废气处理段（如有），用水处理来自微粒化段的废气（包括尿素基粉尘 颗粒和氨气），以产生洗涤溶液；以及 (v) 在洗涤溶液储存段（如果有），储存来自废气处理段的洗涤溶液； 其中，添加剂以无颗粒液体固体的形式引入尿素或尿素基组合物中，方法是将添加剂添加到以下一种或多种物质中 (a) 混合段中的脲基熔体（如果存在）； (b) 所述废气处理段（如有）；以及 (c) 含有洗涤溶液的洗涤溶液储存段（如果有）。
• METHOD FOR THE MANUFACTURE OF A UREA-BASED COMPOSITION COMPRISING THE ADDITION OF AN ADDITIVE IN AN AQUEOUS FORM
  申请人：Yara International ASA

  公开号：EP4015492A1

  公开（公告）日：2022-06-22

  A method is disclosed for the manufacture of a homogeneous, solid, particulate, urea-based composition comprising urea and one or more additives in a urea production plant comprising at least an evaporator section and a particulation section, further comprises one or more of a mixing section, an effluent gas treatment section and a scrubber solution storage section, wherein the method comprises at least the steps of: (i) in the evaporator section, concentrating a urea melt of about 80 weight% to about 95 to 99 weight% of urea; (ii) in the particulation section, particulating a urea or urea-based melt into a urea or urea-based composition; and further comprises one or more of the steps of: (iii) in the mixing section, if present, mixing the urea melt of about 95 to 99 weight% with other fertilizer components to produce a urea-based melt; (iv) in the effluent gas treatment section, if present, treating the effluent gas from the particulation section comprising urea-based dust particles and ammonia gas with water to produce a scrubber solution; and (v) in the scrubber solution storage section, if present, storing the scrubber solution from the effluent gas treatment section; wherein the additive is introduced into the urea or urea-based composition as an aqueous suspension, an aqueous dispersion, or an aqueous liquid, by adding the additive to one or more of (a) said urea melt of about 80 weight% upstream of the evaporation section. (b) said urea-based melt in the mixing section, if present; (c) said effluent gas treatment section, if present; (d) said scrubber solution storage section containing the scrubber solution, if present.

  本发明公开了一种在尿素生产装置中制造均质、固体、微粒、尿素基组合物的方法，该组合物包括尿素和一种或多种添加剂，该装置至少包括一个蒸发段和一个微粒段，还包括一个或多个混合段、一个废气处理段和一个洗涤溶液储存段，其中该方法至少包括以下步骤 (i) 在蒸发段中，浓缩尿素熔体中约 80% 至约 95 至 99% 的尿素； (ii) 在微粒段，将尿素或尿素基熔体微粒化成尿素或尿素基组合物； 并进一步包括以下一个或多个步骤 (iii) 在混合段（如有），将约 95 至 99 重量％的尿素熔体与其他肥料成分 混合，以产生尿素基熔体； (iv) 在废气处理段（如有），用水处理来自微粒化段的废气（包括尿素基粉尘 颗粒和氨气），以产生洗涤溶液；以及 (v) 在洗涤溶液储存段（如果有），储存来自废气处理段的洗涤溶液； 其中，添加剂以水悬浮液、水分散液或水溶液的形式引入尿素或尿素基组合物中，方法是将添加剂添加到以下一种或多种物质中 (a) 蒸发段上游的约 80 重量％的脲熔体。 (b) 混合段中的脲基熔体（如果有）； (c) 所述废气处理段（如有）； (d) 含有洗涤溶液的所述洗涤溶液储存段（如有）。