6-乙基-6-(2-甲氧基乙氧基)-2,5,7,10-四氧杂-6-硅杂十一烷 | 18044-51-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 6-乙基-6-(2-甲氧基乙氧基)-2,5,7,10-四氧杂-6-硅杂十一烷
• 中文别名: 6-乙基-6-(2-甲氧基乙氧基)-2,5,7,10-四氧杂-6-
• 英文名称: ethyl-tris(1,4-dioxapentyl) silane
• 英文别名: 6-ethyl-6-(2-methoxyethoxy)-2,5,7,10-tetraoxa-6-silaundecane；ethyl-tris(2-methoxyethoxy)silane
• CAS: 18044-51-4
• 化学式: C₁₁H₂₆O₆Si
• 分子量: 282.409
• InChiKey: FORHPIYYTQZPDW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.93
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  乙基三氯硅烷 、 乙二醇甲醚 反应 8.0h， 生成 6-乙基-6-(2-甲氧基乙氧基)-2,5,7,10-四氧杂-6-硅杂十一烷
  参考文献：
  名称：

  The reaction heats and PM5 semiempirical studies of complexes formed between silicon podand and monovalent cations

  摘要：

  Silicon podands (1-10) were synthesised and their complexation reaction of Na+ cations were studied by calorimetric and PM5 theoretical methods. Both methods provide evidence for formation of the respective complexes with Na+ cations of different stoichiometry. In most cases, only formation of the complexes of 1:1 stoichiometry has been observed. For compounds with longer oxaalkyl chains (9 and 10) the formation of 1:4 and 1:6 complexes has been found. The structures of the complexes are visualised and discussed. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.08.021

文献信息

• The reaction heats and PM5 semiempirical studies of complexes formed between silicon podand and monovalent cations
  作者：Bogusława Łęska、Piotr Przybylski、Joanna Wyrwał、Bogumił Brzezinski、Grzegorz Schroeder、Volodimir Rybachenko、Angelamaria Maia

  DOI：10.1016/j.molstruc.2004.08.021

  日期：2005.1

  Silicon podands (1-10) were synthesised and their complexation reaction of Na+ cations were studied by calorimetric and PM5 theoretical methods. Both methods provide evidence for formation of the respective complexes with Na+ cations of different stoichiometry. In most cases, only formation of the complexes of 1:1 stoichiometry has been observed. For compounds with longer oxaalkyl chains (9 and 10) the formation of 1:4 and 1:6 complexes has been found. The structures of the complexes are visualised and discussed. (C) 2004 Elsevier B.V. All rights reserved.