5,9-Dithia-3,7,11-triazatricyclo[6.3.0.02,6]undeca-1(8),2(6),3,10-tetraene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并噻唑
• 英文名称: 5,9-Dithia-3,7,11-triazatricyclo[6.3.0.02,6]undeca-1(8),2(6),3,10-tetraene
• 英文别名: 5,9-dithia-3,7,11-triazatricyclo[6.3.0.02,6]undeca-1(8),2(6),3,10-tetraene
• 化学式: C₆H₃N₃S₂
• 分子量: 181.2
• InChiKey: RYPVVLRAGATTSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  98
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• METHOD OF MAKING A PYRROLO BISTHIAZOLE HOMOPOLYMER
  申请人：Qatar Foundation For Education Science And Community Development

  公开号：EP3385298A1

  公开（公告）日：2018-10-10

  The method of making a pyrrolo bisthiazole homopolymer starts with dissolving a dibrominated pyrrolo[3,2-d:4,5-d']bisthiazole monomer having the formula: where R is an alkyl group, in anhydrous tetrahydrofuran (THF). Then, the solvated monomer is treated with 1 equivalent of a Turbo-Grignard reagent complex having the formula iPrMgCl·LiCl at 0°C to form a reaction mixture. The reaction mixture is stirred for 1 hour at room temperature, and after stirring, the reaction mixture is refluxed for 24 hours. A conjugated homopolymer product having the formula: where n is the number of repeating units of pyrrolo[3,2-d:4,5-d']bisthiazole, is recovered from the reaction mixture. The PBTz-based homopolymers showed broad absorption from 450 to 850 nm in thin film and excellent photochemical and thermal stability, making the polymers suitable for lightweight, low cost plastic electronic devices.

  制造吡咯双噻唑均聚物的方法首先是溶解具有以下式子的二溴化吡咯并[3,2-d:4,5-d']双噻唑单体： 其中 R 为烷基，溶于无水四氢呋喃 (THF)。然后，在 0°C 下用 1 个等量的 Turbo-Grignard 试剂复合物处理溶解的单体，该试剂复合物的化学式为 iPrMgCl-LiCl，形成反应混合物。反应混合物在室温下搅拌 1 小时，搅拌后回流 24 小时。共轭均聚物产物的化学式为 其中 n 为吡咯并[3,2-d:4,5-d']双噻唑的重复单元数，从反应混合物中回收。基于 PBTz 的均聚物在薄膜中显示出 450 至 850 纳米的宽吸收范围，以及出色的光化学和热稳定性，使这种聚合物适用于轻质、低成本的塑料电子设备。
• Method of making a pyrrolo bisthiazole homopolymer
  申请人：QATAR FOUNDATION FOR EDUCATION, SCIENCE AND COMMUNITY DEVELOPMENT

  公开号：US10927214B2

  公开（公告）日：2021-02-23

  The method of making a pyrrolo bisthiazole homopolymer starts with dissolving a dibrominated pyrrolo[3,2-d:4,5-d′]bisthiazole monomer having the formula: where R is an alkyl group, in anhydrous tetrahydrofuran (THF). Then, the solvated monomer is treated with 1 equivalent of a Turbo-Grignard reagent complex having the formula iPrMgCl.LiCl at 0° C. to form a reaction mixture. The reaction mixture is stirred for 1 hour at room temperature, and after stirring, the reaction mixture is refluxed for 24 hours. A conjugated homopolymer product having the formula: where n is the number of repeating units of pyrrolo[3,2-d:4,5-d′]bisthiazole, is recovered from the reaction mixture. The PBTz-based homopolymers showed broad absorption from 450 to 850 nm in thin film and excellent photochemical and thermal stability, making the polymers suitable for lightweight, low cost plastic electronic devices.

  制造吡咯双噻唑均聚物的方法首先是溶解具有以下式子的二溴化吡咯并[3,2-d:4,5-d′]双噻唑单体： 其中 R 为烷基，溶解在无水四氢呋喃（THF）中。然后，将溶解的单体与 1 个当量的 Turbo-Grignard 试剂复合物（其化学式为 iPrMgCl.LiCl ）在 0℃下处理，形成反应混合物。反应混合物在室温下搅拌 1 小时，搅拌后回流 24 小时。共轭均聚物产物的化学式为 其中 n 为吡咯并[3,2-d:4,5-d′]双噻唑的重复单元数，从反应混合物中回收。基于 PBTz 的均聚物在薄膜中显示出 450 至 850 纳米的宽吸收范围，以及出色的光化学和热稳定性，使这种聚合物适用于轻质、低成本的塑料电子设备。
• CONJUGATED POLYMERS
  申请人：Raynergy Tek Inc.

  公开号：EP2630179B1

  公开（公告）日：2021-04-14