3-(2,3-Dichloro-propyl)-3,4,4-trifluoro-[1,2]oxathietane 2,2-dioxide | 132145-59-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧硫杂环丁烷
• 英文名称: 3-(2,3-Dichloro-propyl)-3,4,4-trifluoro-[1,2]oxathietane 2,2-dioxide
• 英文别名: 3-(2,3-Dichloropropyl)-3,4,4-trifluorooxathietane 2,2-dioxide
• CAS: 132145-59-6
• 化学式: C₅H₅Cl₂F₃O₃S
• 分子量: 273.06
• InChiKey: DETDTRVHAKTXDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3-(2,3-Dichloro-propyl)-3,4,4-trifluoro-[1,2]oxathietane 2,2-dioxide 在 水 作用下， 以67.3%的产率得到4,5-Dichloro-2-fluoro-2-fluorosulfonyl-pentanoic acid
  参考文献：
  名称：

  [2,3-二氯丙基]三氟乙烯的磺化：新型氟化β-内酯及其衍生物的合成

  摘要：

  已经制备了两种新的烯烃，即CH 2 BrCHBrCH 2 CF ＝ CF 2和CH 2 ClCHClCH 2 CF ＝ CF 2作为氟代β-磺内酯的前体。新的氟化磺酸内酯，CH 2 ClCHClCH 2 CFCF2OSO 2，获得（来自的磺化CH 2 ClCHClCH 2 CFCF 2），连同其重新排列的异构体，CH 2 ClCHClCH 2 CF（SO 2 F）C（O）F以及水解产物CH 2 ClCHClCH 2 CF（SO 2 F）C（O）OH。

  DOI：

  10.1016/s0022-1139(00)82177-6
• 作为产物：
  描述：

  1,1,2-trifluoropentane-1,4-diene 在 三氧化硫 、 氯 、 sodium chloride 作用下， 以 氯仿 为溶剂， 生成 3-(2,3-Dichloro-propyl)-3,4,4-trifluoro-[1,2]oxathietane 2,2-dioxide
  参考文献：
  名称：

  [2,3-二氯丙基]三氟乙烯的磺化：新型氟化β-内酯及其衍生物的合成

  摘要：

  已经制备了两种新的烯烃，即CH 2 BrCHBrCH 2 CF ＝ CF 2和CH 2 ClCHClCH 2 CF ＝ CF 2作为氟代β-磺内酯的前体。新的氟化磺酸内酯，CH 2 ClCHClCH 2 CFCF2OSO 2，获得（来自的磺化CH 2 ClCHClCH 2 CFCF 2），连同其重新排列的异构体，CH 2 ClCHClCH 2 CF（SO 2 F）C（O）F以及水解产物CH 2 ClCHClCH 2 CF（SO 2 F）C（O）OH。

  DOI：

  10.1016/s0022-1139(00)82177-6

文献信息

• Proton conducting titanate, polymer nano-composite membrane including the same, and fuel cell adopting the polymer nano-composite membrane
  申请人：Kim Hae-kyoung

  公开号：US20070053826A1

  公开（公告）日：2007-03-08

  A proton conducting titanate includes titanate and a sulfonic acid group-containing moiety having proton conductivity introduced into the surface of the titanate, in which the sulfonic acid group-containing moiety is directly bound to the titanate via an ether bond (—O). A polymer nano-composite membrane includes the proton conducting titanate, and a fuel cell includes the polymer nano-composite membrane. The proton conducting titanate is provided with a sulfonic acid functional group having proton conductivity, which increases the proton conductivity of the polymer nano-composite membrane. The polymer nano-composite membrane includes the proton conducting titanate, and thus can have a controllable degree of swelling in a methanol solution, and the transmittance of the polymer nano-composite membrane can be reduced. The polymer nano-composite membrane can be used as a proton conducting membrane in fuel cells to improve the thermal stability, energy density, and fuel efficiency of the fuel cells.
• Composite film, flexible substrate including the composite film, and organic light emitting device including the flexible substrate
  申请人：Lim Jin-O

  公开号：US20110193068A1

  公开（公告）日：2011-08-11

  A composite film, a flexible substrate, and an organic light emitting device, the composite film including a composite including a sulfonic acid group containing moiety connected by an ether linkage (—O—) to an inorganic material having a nano-sized interlayer distance.
• US7842199B2
  申请人：——

  公开号：US7842199B2

  公开（公告）日：2010-11-30
• Sulfonation of [2,3-dichloropropyl]trifluoroethylene: synthesis of a new fluorinated β-sultone and derivatives
  作者：Javid Mohtasham、Gary L. Gard、Zhen-Yu Yang、Donald J. Burton

  DOI：10.1016/s0022-1139(00)82177-6

  日期：1990.10

  Two new olefins, CH2BrCHBrCH2CFCF2 and CH2ClCHClCH2CFCF2, have been prepared as precursors to fluoro β-sultones. The new fluorinated sultone, CH2ClCHClCH2CFCF2OSO2, was obtained (from the sulfonation of CH2ClCHClCH2CFCF2), along with its rearranged isomer, CH2ClCHClCH2CF(SO2F)C(O)F, and hydrolysis product, CH2ClCHClCH2CF(SO2F)C(O)OH.

  已经制备了两种新的烯烃，即CH 2 BrCHBrCH 2 CF ＝ CF 2和CH 2 ClCHClCH 2 CF ＝ CF 2作为氟代β-磺内酯的前体。新的氟化磺酸内酯，CH 2 ClCHClCH 2 CFCF2OSO 2，获得（来自的磺化CH 2 ClCHClCH 2 CFCF 2），连同其重新排列的异构体，CH 2 ClCHClCH 2 CF（SO 2 F）C（O）F以及水解产物CH 2 ClCHClCH 2 CF（SO 2 F）C（O）OH。