2-propylamino-4,6-bis(methylamino)borazine | 1246086-70-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: 2-propylamino-4,6-bis(methylamino)borazine
• 英文别名: 4-N,6-N-dimethyl-2-N-propyl-1,3,5,2,4,6-triazatriborinane-2,4,6-triamine
• CAS: 1246086-70-3
• 化学式: C₅H₁₉B₃N₆
• 分子量: 195.679
• InChiKey: NVZJWFGVGYOTDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.84
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  72.2
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  、 甲胺 以 甲苯 为溶剂， 以12.3 g的产率得到2-propylamino-4,6-bis(methylamino)borazine
  参考文献：
  名称：

  Facile synthesis of a melt-spinnable polyborazine from asymmetric alkylaminoborazine

  摘要：

  A novel asymmetric alkylaminoborazine monomer, 2-propylamino-4,6-bis(methylamino)borazine, was synthesized for the first time, and directly polymerized to give a melt-spinnable polyborazine (PBN). This asymmetric alkylaminoborazine was synthesized by an aminolysis reaction of 2,4,6-trichloroborazine (TCB) with different amines under mild conditions. This route turns out to be much cheaper and simpler than the conventional routes. The chemical composition, structure, molecular weights and ceramic yield were investigated by EA, FTIR, NMR, GPC and TG analysis. The PBN exhibits suitable rheological property for melt-spinning, which suggests that it is a potential precursor for BN fibers. (C) 2010 Ying De Wang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2010.04.041

文献信息

• Facile synthesis of a melt-spinnable polyborazine from asymmetric alkylaminoborazine
  作者：Yong Peng Lei、Ying De Wang、Yong Cai Song、Yi He Li、Hao Wang、Cheng Deng、Zheng Fang Xie

  DOI：10.1016/j.cclet.2010.04.041

  日期：2010.9

  A novel asymmetric alkylaminoborazine monomer, 2-propylamino-4,6-bis(methylamino)borazine, was synthesized for the first time, and directly polymerized to give a melt-spinnable polyborazine (PBN). This asymmetric alkylaminoborazine was synthesized by an aminolysis reaction of 2,4,6-trichloroborazine (TCB) with different amines under mild conditions. This route turns out to be much cheaper and simpler than the conventional routes. The chemical composition, structure, molecular weights and ceramic yield were investigated by EA, FTIR, NMR, GPC and TG analysis. The PBN exhibits suitable rheological property for melt-spinning, which suggests that it is a potential precursor for BN fibers. (C) 2010 Ying De Wang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.