2-azido-4,6-diphenyl-s-triazine | 63084-46-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2-azido-4,6-diphenyl-s-triazine
• 英文别名: 2-azido-4,6-diphenyl-1,3,5-triazine
• CAS: 63084-46-8
• 化学式: C₁₅H₁₀N₆
• 分子量: 274.285
• InChiKey: LODKIAUPEUDOML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-氯-4,6-二苯基-1,3,5-三嗪 以 乙腈 为溶剂， 生成 2-azido-4,6-diphenyl-s-triazine
  参考文献：
  名称：

  Compound oxidized styrylphosphine

  摘要：

  聚合物、共聚物和三元共聚物是通过以下方法制备的：（1）聚合至少选择自以下组的氧化苯基膦烯单体之一：(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，(c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2，(c.sub.6 h.sub.5).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2和(C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2；或（2）聚合对二苯基膦苯乙烯，然后用选择自以下组的有机叠氮化合物氧化所聚合的对二苯基膦苯乙烯单体：(C.sub.6 H.sub.5).sub.2 P(O)N.sub.3，(C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3，(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3)和C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2。共聚物也可以通过共聚苯乙烯和至少选择自以下组的氧化苯基膦烯单体之一来制备：(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，(c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2，(c.sub.6 h.sub.5 ).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2和(C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2

  公开号：

  US04168287A1

文献信息

• Heat resistant polymers of oxidized styrylphosphine
  申请人：——

  公开号：US04200721A1

  公开（公告）日：1980-04-29

  Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by: (1) polymerizing at least one oxidized styrylphosphine monomer selected from the group of: (C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 and (C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2 ; or (2) polymerizing p-diphenylphosphinestyrene and then oxidizing said polymerized p-diphenylphosphinestyrene monomer with an organoazide selected from the group of (C.sub.6 H.sub.5).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3) and C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2. Copolymers can also be prepared by copolymerizing styrene with at least one oxidized styrylphosphine monomer selected from the group of: (C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 and (C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2.

  基于苯乙烯单体的同聚物，共聚物和三聚物通过以下方法制备：（1）聚合至少一种氧化的苯乙烯基磷酰胺单体，所选单体来自以下组合：（C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，（C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，（C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2和（C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2].sub.2；或（2）聚合对二苯基膦基苯乙烯，然后用有机偶氮化物氧化聚合的对二苯基膦基苯乙烯单体，所选有机偶氮化物来自以下组合：（C.sub.6 H.sub.5).sub.2 P(O)N.sub.3，（C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3，（C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3（N.sub.3）和C.sub.6 H.sub.5C.sub.3 N.sub.3（N.sub.3）.sub.2。共聚物也可以通过与至少一种氧化的苯乙烯基磷酰胺单体共聚合而制备，所选单体来自以下组合：（C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，（C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，（C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2和（C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2].sub.2。
• US4092466A
  申请人：——

  公开号：US4092466A

  公开（公告）日：1978-05-30
• US4168287A
  申请人：——

  公开号：US4168287A

  公开（公告）日：1979-09-18
• US4200721A
  申请人：——

  公开号：US4200721A

  公开（公告）日：1980-04-29
• Compound oxidized styrylphosphine
  申请人：——

  公开号：US04168287A1

  公开（公告）日：1979-09-18

  Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by: (1) polymerizing at least one oxidized styrylphosphine monomer selected from the group of: (C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2, (c.sub.6 h.sub.5).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2 and (C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2 ; or (2) polymerizing p-diphenylphosphinestyrene and then oxidizing said polymerized p-diphenylphosphinestyrene monomer with an organoazide selected from the group of (C.sub.6 H.sub.5).sub.2 P(O)N.sub.3, (C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3, (C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3) and C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2. Copolymers can also be prepared by copolymerizing styrene with at least one oxidized styrylphosphine monomer selected from the group of: (C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2, (c.sub.6 h.sub.5 ).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2 and (C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2

  聚合物、共聚物和三元共聚物是通过以下方法制备的：（1）聚合至少选择自以下组的氧化苯基膦烯单体之一：(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，(c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2，(c.sub.6 h.sub.5).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2和(C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2；或（2）聚合对二苯基膦苯乙烯，然后用选择自以下组的有机叠氮化合物氧化所聚合的对二苯基膦苯乙烯单体：(C.sub.6 H.sub.5).sub.2 P(O)N.sub.3，(C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3，(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3)和C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2。共聚物也可以通过共聚苯乙烯和至少选择自以下组的氧化苯基膦烯单体之一来制备：(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，(c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2，(c.sub.6 h.sub.5 ).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2和(C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2