carbon monoxide;iron;trifluorophosphane | 53368-95-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: carbon monoxide;iron;trifluorophosphane
• CAS: 53368-95-9
• 化学式: C₄F₃FeO₄P
• 分子量: 255.858
• InChiKey: HWEJTZMBDHHRNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis[tris(trifluoromethyl)phosphine]tricarbonyliron(0) 在 PF₃ 作用下， 以 neat (no solvent) 为溶剂， 生成 carbon monoxide;iron;trifluorophosphane
  参考文献：
  名称：

  Burg, Anton B., Inorganic Chemistry, 1986, vol. 25, # 26, p. 4751 - 4755

  摘要：

  DOI：

文献信息

• IR laser pyrolysis and the isotopic labelling of organometallic compounds
  作者：Neil J. Bristow、Barry D. Moore、Martyn Poliakoff、Graham J. Ryott、James J. Turner

  DOI：10.1016/s0022-328x(00)98693-5

  日期：1984.1

  A homogeneous gas phase pyrolysis technique involving SF6 sensitization and a continuous wave (CW) CO2 laser, is described for preparing small quantities (∼ 100 mg) of organometallic compounds. Several reactions have been successfully carried out and the synthesis of Os(CO)5 from H2Os(CO)4 and CO is discussed in detail. With IR laser pyrolysis, room temperature reactors and sub-atmospheric pressures

  描述了一种涉及SF 6敏化和连续波（CW）CO 2激光的均相气相热解技术，用于制备少量（〜100 mg）的有机金属化合物。已成功进行了数个反应，并详细讨论了由H 2 Os（CO）4和CO合成Os（CO）5的方法。通过IR激光热解，可以将室温反应器和低于大气压的压力用于通常需要高压和高温的反应。
• Stereochemistry of phosphorus trihalide derivatives of iron carbonyl
  作者：J.B.Ph. Tripathi、M. Bigorgne

  DOI：10.1016/s0022-328x(00)83732-8

  日期：1967.8

  particularly from the point of vie of statellites due to 13CO-groups. It has been shown that these derivatives contain all the isomers geometrically expected for the trigonal bipyramidal structure around the iron atom. The isolation of these isomers was not possible; nevertheless, reaction mixtures containing only one isomer have been prepared.

  衍生物的Fe（CO）的红外光谱5 - Ñ（PF 3）ñ和Fe（CO）4（PCL 3）已经研究了在该区域4200-400cm -1特别是从由于statellites的VIE的点13合作组。已经显示出这些衍生物包含对于铁原子周围的三角双锥体结构几何上预期的所有异构体。分离这些异构体是不可能的。然而，已经制备了仅包含一种异构体的反应混合物。
• Sulfur hexafluoride sensitized infrared photodecomposition of iron pentacarbonyl
  作者：Tetsuro Majima、Tadahiro Ishii、Yoshiyasu Matsumoto、Michio Takami

  DOI：10.1021/ja00189a007

  日期：1989.3
• Phosphorus Trifluoride Substitution Compounds of Iron Pentacarbonyl
  作者：Ronald J. Clark

  DOI：10.1021/ic50020a011

  日期：1964.10
• Ultraviolet laser photolysis: Primary photochemistry of Fe(CO)₅ in PF₃
  作者：Gilbert Nathanson、Barbara Gitlin、Alan M. Rosan、James T. Yardley

  DOI：10.1063/1.440841

  日期：1981.1

  We have studied the photolysis of mixtures of Fe(CO)5 and PF3 with a KrF laser operating at 248 nm. The product yields of Fe(CO)2(PF3)3, Fe(CO)3(PF3)2, and Fe(CO)4PF3 have been measured as a function of laser fluence and mixture composition. A simple kinetic model appears to explain semiquantitatively the observed dependence of product yield upon mixture composition. This model has allowed us to determine that the primary photochemical yields at 248 nm for the fragments Fe(CO)2, Fe(CO)3, and Fe(CO)4 over the fluence range 0.1–200 mJ/cm2 are 0.55, 0.35, and 0.10, respectively, independent of laser fluence. This fragmentation results from a simple one-photon absorption process. We have found that CO ligands are exchanged readily in collisions of the above fragments with Fe(CO)5, with a bimolecular rate constant relative to that for trapping by PF3 of kM/kT=4. We have also found that these primary photofragments react with Fe(CO)5 to form unobserved products with a rate constant (relative to that for trapping by PF3) of kQ/kT=7.