tris(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl) phosphite | 30538-89-7

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 英文名称: tris(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl) phosphite
• CAS: 30538-89-7
• 化学式: C₂₇H₅₄N₃O₆P
• 分子量: 547.716
• InChiKey: WLGSYBIYACWXFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  37
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  98.1
• 氢给体数：
  3
• 氢受体数：
  9

文献信息

• Stabilizer composition
  申请人：——

  公开号：US20030060544A1

  公开（公告）日：2003-03-27

  A description is given of a stabilizer composition comprising A) at least one nitrogen compound having a molecular weight of at least 150, selected from a secondary amine in which all substituents positioned &agr; to the amine nitrogen atom are different than hydrogen, or, derived from the secondary amine, a tertiary amine, hydroxylamine, alkoxyamine or amide; and B) at least one iron compound. The stabilizer composition optionally comprises nitroxyl radicals. It is suitable for stabilizing nonliving organic material, especially polyolefins or homopolymers or copolymers of styrene, against the effects of light, heat or oxygen.

  描述了一种稳定剂组合物，该组合物包括 A) 至少一种氮化合物，其分子量至少为 150，选自一种仲胺，其中与胺氮原子相连的所有取代基都不同于氢，或由仲胺衍生的叔胺、羟胺、烷氧基胺或酰胺；以及 B) 至少一种铁化合物。 稳定剂组合物可选择包含硝基自由基。它适用于稳定非生物有机材料，特别是聚烯烃或苯乙烯的均聚物或共聚物，使其免受光、热或氧的影响。
• Method for producing polymers
  申请人：——

  公开号：US20030073793A1

  公开（公告）日：2003-04-17

  A process for the preparation of polymers is described, wherein at least one first ethylenically unsaturated monomer is subjected to a free radical polymerization in the presence of stable free radicals or sources of stable free radicals and of a compound having at least one free thiol group to give a polymer, and wherein the molar ratio of compound having a free thiol group to stable free radicals is from 0.05 to 1.1. The polymerization rate is substantially increased by the compound having a free thiol group.

  描述了一种制备聚合物的工艺，其中至少一种第一乙烯基不饱和单体在稳定自由基或稳定自由基源以及具有至少一个游离硫醇基团的化合物存在下进行自由基聚合，从而得到聚合物，具有游离硫醇基团的化合物与稳定自由基的摩尔比为 0.05 至 1.1。 具有游离硫醇基团的化合物可显著提高聚合速率。
• Inhibitor composition for stabilizing substances capable of free radical polymerization
  申请人：BASF Akitengesellshaft

  公开号：US20030097017A1

  公开（公告）日：2003-05-22

  An inhibitor mixture containing, as components, a) at least one nitroxyl radical (derivative), b) at least one phenol (derivative) and c) at least one chemical compound which contains at least one phosphorus atom which has the oxidation state +3 is preferably used for stabilizing compounds capable of free radical polymerization.

  抑制剂混合物的成分包括：a）至少一种硝基自由基（衍生物）；b）至少一种苯酚（衍生物）；c）至少一种含有至少一个氧化态为+3的磷原子的化合物。
• ETHYLENE POLYMER HAVING IMPROVED RESISTANCE AGAINST THERMOOXIDATIVE DEGRADATION IN THE PRESENCE OF LIQUID FUELS COMPRISING BIODIESEL AND OXYGEN AND PLASTIC FUEL TANK MADE OF IT
  申请人：Basell Polyolefine GmbH

  公开号：EP2303960A1

  公开（公告）日：2011-04-06
• METHOD TO IMPROVE THE BARRIER PROPERTIES OF ETHYLENE POLYMER AGAINST PERMEATION OF HYDROCARBONS AND PLASTIC FUEL TANK HAVING IMPROVED BARRIER PROPERTIES
  申请人：Basell Polyolefine GmbH

  公开号：EP2440585A1

  公开（公告）日：2012-04-18