Bromonickel | 71939-11-2

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: Bromonickel
• CAS: 71939-11-2
• 化学式: BrNi
• 分子量: 138.594
• InChiKey: SKQCHZRATRCBOH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.84
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  溴 、 镍 以 neat (no solvent, gas phase) 为溶剂， 生成 Bromonickel
  参考文献：
  名称：

  Perturbation analysis for the rotational spectrum of the NiBr radical in the X [sup 2]Π[sub 3/2] and A [sup 2]Δ[sub 5/2] states

  摘要：

  The millimeter- and submillimeter-wave spectra of the NiBr radical in the X 2Π3/2 and A 2Δ5/2 states were observed by a source-modulated microwave spectrometer. The NiBr radical was generated in a dc glow discharge through the mixture of Br2 vapor and Ar gas by the sputtering reaction with a Ni cathode. Observed transition frequencies were independently analyzed for both electronic states using a standard polynomial expression of a Hund’s case (c) approximation. Anomalous behavior of the effective molecular constants in the X 2Π3/2 state was interpreted as the result of the perturbation between the X 2Π3/2 and A 2Δ5/2 states. The deperturbed molecular constants were derived using a simplified supermultiplet Hamiltonian including the interaction terms between the two electronic states.

  DOI：

  10.1063/1.1752883

文献信息

• ISIGAKI, TAKEHO;KAMIEHSU, JOSIAKI
  作者：ISIGAKI, TAKEHO、KAMIEHSU, JOSIAKI

  DOI：——

  日期：——
• Perturbation analysis for the rotational spectrum of the NiBr radical in the X [sup 2]Π[sub 3/2] and A [sup 2]Δ[sub 5/2] states
  作者：Emi Yamazaki、Toshiaki Okabayashi、Mitsutoshi Tanimoto

  DOI：10.1063/1.1752883

  日期：——

  The millimeter- and submillimeter-wave spectra of the NiBr radical in the X 2Π3/2 and A 2Δ5/2 states were observed by a source-modulated microwave spectrometer. The NiBr radical was generated in a dc glow discharge through the mixture of Br2 vapor and Ar gas by the sputtering reaction with a Ni cathode. Observed transition frequencies were independently analyzed for both electronic states using a standard polynomial expression of a Hund’s case (c) approximation. Anomalous behavior of the effective molecular constants in the X 2Π3/2 state was interpreted as the result of the perturbation between the X 2Π3/2 and A 2Δ5/2 states. The deperturbed molecular constants were derived using a simplified supermultiplet Hamiltonian including the interaction terms between the two electronic states.