N-methylazacycloheptane N-oxide | 21369-55-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环庚烷
• 英文名称: N-methylazacycloheptane N-oxide
• 英文别名: N-methylhexamethyleneimine N-oxide；1-Methylhexamethylenimin-N-oxid；N-Methyl-hexamethylenimin-N-oxid；N-Methylazacycloheptan-N-oxid；1-methyl-hexamethylenimine N-oxide；1-Methylhexamethylenimin-1-oxyd；N-methylazacyclo-heptane-N-oxide；1-methyl-1-oxidoazepan-1-ium
• CAS: 21369-55-1
• 化学式: C₇H₁₅NO
• 分子量: 129.202
• InChiKey: JJIMINHSAIZIJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-methylazacycloheptane N-oxide 生成 N-(5-hexenyl)-N-methylhydroxylamine
  参考文献：
  名称：

  CIGANEK, ENGELBERT, J. ORG. CHEM., 55,(1990) N0, C. 3007-3009

  摘要：

  DOI：
• 作为产物：
  描述：

  1-甲基氮杂环庚烷 在 氧气 作用下， 以 水 为溶剂， 90.0 ℃ 、6.8 MPa 条件下， 生成 N-methylazacycloheptane N-oxide
  参考文献：
  名称：

  Selective autoxidation of electron-rich substrates under elevated oxygen pressures

  摘要：

  DOI：

  10.1021/jo00243a018

文献信息

• Reinforced cellulosic film
  申请人：VISKASE CORPORATION

  公开号：EP0712889A2

  公开（公告）日：1996-05-22

  The present invention relates to compounded fibrous dope compositions of amine oxide cellulose solutions having a uniformly dispersed second fibrous material, methods of producing the compositions, and shaped articles such as fibers, paper, films, and food casings produced from the compositions.

  本发明涉及氧化胺纤维素溶液（具有均匀分散的第二种纤维材料）的复合纤维涂料组合物、组合物的生产方法，以及用组合物生产的纤维、纸张、薄膜和食品外壳等成型物品。
• Sinterable structures and method
  申请人：Phillips Plastics Corporation

  公开号：US20030212154A1

  公开（公告）日：2003-11-13

  A method of producing an open, porous structure having an outer surface defining a shape having a bulk volume and having interconnecting openings extending throughout said volume and opening through said surface, and products resulting from the method. The method comprises preparing a viscous mixture comprising a sinterable powder dispersed in a sol of a polymer in a primary solvent, replacing the primary solvent with a secondary liquid in which the polymer is insoluble to produce a gel comprising an open polymeric network having the sinterable powder arranged therein, removing the secondary liquid from the gel; removing the polymer network, and sintering the sinterable powder to form the open, porous structure. Also disclosed are shaped, porous products resulting from methods of the invention.

  一种生产开放式多孔结构的方法，该结构的外表面限定了一个具有体积的形状，并具有延伸至整个所述体积并穿过所述表面的相互连接的开口，以及该方法产生的产品。该方法包括制备一种粘性混合物，该混合物包括分散在主溶剂中聚合物溶胶中的可烧结粉末；用聚合物不溶于其中的辅助液体代替主溶剂，以产生一种凝胶，该凝胶包括开放的聚合物网络，其中排列有可烧结粉末；从凝胶中移除辅助液体；移除聚合物网络，并烧结可烧结粉末以形成开放的多孔结构。本发明还公开了由本发明方法产生的成型多孔产品。
• Protein shaped body and method for the production thereof according to the nmmo method
  申请人：——

  公开号：US20040046277A1

  公开（公告）日：2004-03-11

  This invention relates to a method for producing proteinaceous shaped articles from globular proteins according to the NMMO method, and to proteinaceous shaped articles themselves that are made from globular proteins according to the NMMO method. According to the invention, a suspension consisting of aqueous NMMO and of these precrosslinked proteins is transferred into a spinning solution, whereby the suspension contains a polysaccharide and/or a polysaccharide is added to the extrusion solution. The spinning solution is extruded into a precipitation bath through a form tool and through an air gap. Afterwards, the shaped article is washed with an aqueous liquid without the use of solvents and is subsequently hardened using known crosslinking reactions. The produced solutions are processed for a diverse product-oriented processing, preferably on the basis of known wet and dry/wet spinning techniques, optionally in conjunction with multi-constituent spinning techniques. The produced solutions can be processed using spin casting or other shaping techniques in order to produce, by these means, e.g. monofil and polyfil filaments, staple fibers, microfibers, nonwovens, foils, membranes, coatings, films or other shaped articles.

  本发明涉及一种根据NMMO方法用球状蛋白质生产蛋白状物品的方法，以及根据NMMO方法用球状蛋白质制成的蛋白状物品本身。根据本发明，将由水性 NMMO 和这些预交联蛋白质组成的悬浮液转移到纺丝溶液中，悬浮液中含有多糖和/或在挤出溶液中加入多糖。纺丝溶液通过成型工具和气隙挤入沉淀槽。之后，在不使用溶剂的情况下，用水性液体清洗成型物品，然后使用已知的交联反应硬化。生产出的溶液可进行多种产品加工，最好采用已知的湿法和干法/湿法纺丝技术，也可选择结合多成分纺丝技术。生产出的溶液可以使用纺丝铸造或其他成型技术进行加工，以便通过这些方法生产单纤维和聚纤维长丝、短纤维、超细纤维、无纺布、箔、膜、涂层、薄膜或其他成型物品。
• CIGANEK, ENGELBERT, J. ORG. CHEM., 55,(1990) N0, C. 3007-3009
  作者：CIGANEK, ENGELBERT

  DOI：——

  日期：——
• CATALYSTS AND METHODS FOR POLYMER SYNTHESIS
  申请人：Novomer, Inc.

  公开号：US20130144033A1

  公开（公告）日：2013-06-06

  The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.