Trimethyl-((Z)-1-tributylstannanyl-hept-1-enyl)-silane | 140173-36-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Trimethyl-((Z)-1-tributylstannanyl-hept-1-enyl)-silane
• CAS: 140173-36-0
• 化学式: C₂₂H₄₈SiSn
• 分子量: 459.419
• InChiKey: SWXWPYPWPQRTLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.28
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Trimethyl-((Z)-1-tributylstannanyl-hept-1-enyl)-silane 在 甲醇 、 正丁基锂 、 四氯化钛 作用下， 反应 51.0h， 生成 (E)-2-butyloct-2-enal
  参考文献：
  名称：

  Selective Syntheses of (S)-1-Methylbutyl (E)-2,4-Dimethyl-2-Pentenoate, an Aggregation Pheromone Component ofRhyzopertha dominica, and of (E)-2-Butyl-2-Octenal, an Alarm Pheromone Component ofOecophylla longinodavia2-Substituted 1-Sdlyl-1-Stannylethenes 1)

  摘要：

  Two easily available stereodefined organobimetallic compounds, i.e. (Z)-1-trimethylsilyl-1-trimethylstannyl-3-methyl-1-butene, (Z)-1a, and (Z)-1-trimethylsilyl-1-tributylstannyl-1-heptene, (Z)-12, which serve as direct precursors to reagents which are synthetic equivalents of the 1-alkene 2d1 synthon 20, have been used as key intermediates in selective and efficient syntheses of two insect pheromone components, i.e. enantiomerically pure (S)-1-methylbutyl (E)-2,4-dimethyl-2-pentenoate (dominicalure-2), (S)(E)-10, and (E)-2-butyl-2-octenal, (E)-11, respectively.

  DOI：

  10.1080/00397919208019259

文献信息

• Selective Syntheses of (S)-1-Methylbutyl (E)-2,4-Dimethyl-2-Pentenoate, an Aggregation Pheromone Component of<i>Rhyzopertha dominica</i>, and of (E)-2-Butyl-2-Octenal, an Alarm Pheromone Component of<i>Oecophylla longinoda</i><i>via</i>2-Substituted 1-Sdlyl-1-Stannylethenes 1)
  作者：Renzo Rossi、Adriano Carpita、Tommaso Messeri

  DOI：10.1080/00397919208019259

  日期：1992.2

  Two easily available stereodefined organobimetallic compounds, i.e. (Z)-1-trimethylsilyl-1-trimethylstannyl-3-methyl-1-butene, (Z)-1a, and (Z)-1-trimethylsilyl-1-tributylstannyl-1-heptene, (Z)-12, which serve as direct precursors to reagents which are synthetic equivalents of the 1-alkene 2d1 synthon 20, have been used as key intermediates in selective and efficient syntheses of two insect pheromone components, i.e. enantiomerically pure (S)-1-methylbutyl (E)-2,4-dimethyl-2-pentenoate (dominicalure-2), (S)(E)-10, and (E)-2-butyl-2-octenal, (E)-11, respectively.