bis(hydrogen phosphato-O)[(1SR,4SR,8RS,11RS)-1,4,8,11-tetraazacyclotetradecane-κ(4)N]nickel(II) | 1029683-36-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: bis(hydrogen phosphato-O)[(1SR,4SR,8RS,11RS)-1,4,8,11-tetraazacyclotetradecane-κ(4)N]nickel(II)
• CAS: 1029683-36-0
• 化学式: C₁₀H₂₈N₄NiO₈P₂
• 分子量: 452.992
• InChiKey: RQLNJLWHVTUDFA-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  1,4,8,11-四氮杂环十四烷 、 磷酸 、 nickel(II) nitrate 以 乙醇 为溶剂， 生成 bis(hydrogen phosphato-O)[(1SR,4SR,8RS,11RS)-1,4,8,11-tetraazacyclotetradecane-κ(4)N]nickel(II)
  参考文献：
  名称：

  Bis(dihydrogen phosphato-O)[(1SR,4SR,8RS,11RS)-1,4,8,11-tetraazacyclotetradecane-κ⁴N]nickel(II)

  摘要：

  The Ni-II ion in the title compound. [Ni(H2PO4)(2-)(C10H24N4)] is six-coordinate in a distorted square bipyramidal environment. The crystal structure consists of two molecules of the title compound, each residing on a centre of inversion. Four tetramine N atoms of the macrocyclic ligand! are equatorial [average Ni-N distance = 2.07(1)Angstrom] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.12(3)Angstrom]. The structure of the title complex consists of a three-dimensional framework? which delimits intersecting a-axis, b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H ... O and N-H ... O, ensure the cohesion and stability of the molecular packing.

  DOI：

  10.1107/s0108270198008245