amidophosphoric acid bis-(2-chloro-ethyl ester) | 50413-98-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: amidophosphoric acid bis-(2-chloro-ethyl ester)
• 英文别名: Amidophosphorsaeure-bis-(2-chlor-aethylester)；Bis(2-chloroethyl) phosphoramidate；1-[amino(2-chloroethoxy)phosphoryl]oxy-2-chloroethane
• CAS: 50413-98-4
• 化学式: C₄H₁₀Cl₂NO₃P
• 分子量: 222.008
• InChiKey: SWBMUZMRRQHTFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  61.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  二(2-氯乙基)亚磷酸氢酯 在 四氯化碳 、 氨 作用下， 生成 amidophosphoric acid bis-(2-chloro-ethyl ester)
  参考文献：
  名称：

  Conversion of Tertiary Phosphites to Secondary Phosphonates. Diphenyl Phosphonate¹

  摘要：

  DOI：

  10.1021/ja01521a028

文献信息

• Intumescent composition
  申请人：GREAT LAKES CHEMICAL CORPORATION

  公开号：EP0008939A2

  公开（公告）日：1980-03-19

  There is disclosed an intumescent composition. The applicants disclose such compositions which impart durable flame retardancy to wood, which compositions comprise a cyclic nitrogen compound, a hydroxy-containing organo-phosphorus compound, and organo-phosphorus acid, and water, wherein: a) said cyclic nitrogen compound is wherein a, b, and c are integers selected from the group consisting of 1 and 2, a plus b plus c equal about 3 to 6, and X, X', and X" are independently selected from the group consisting of hydrogen and -CH3; b) said hydroxy-containing organo-phosphorus compound is selected from the group consisting of and and mixtures thereof, wherein d is an integer of from 0 to 2, e is an integer of from 0 to 2, f is an integer of from 1 to 3, and d plus e plus f equal 3; z is an integer of 0 to 1; x is an integer of 1 to 2, y is an integer of 1 to 2, and x plus y plus z eqal 3; R R2, and R3 are selected from the group consisting of alkyl radicals containing from about 1 to about 6 carbon atoms and haloalkyl radicals containing from about 2 to about 6 carbon atoms, provided that when R3 is haloalkyl it contains at least 3 carbon atoms; R4 and R5 are selected from the group consisting of hydrogen, alkyl radicals, and haloalkyl radicals, wherein said radicals contain from about 1 to about 6 carbon atoms; and the total number of carbon atoms in the R1, R2, R3, R4, and R5 groups does not exceed about 14; and c) said acid is selected from the group consisting of and mixtures thereof, wherein R6, R7, R8 and R9 are independently selected from the group consisting of hydrogen, alkyl of from about 1 to about 3 carbon atoms, haloalkyl of from about 1 to about 3 carbon atoms, and hydroxyalkyl of from 1 to about 3 carbon atoms, provided that the total number of carbon atoms in the R6, R7, R°, and R9 groups does not exceed about 5; wherein q is an integer of from 1 to 2, h and i are integers independently selected from the group consisting of 0, 1, and 2, and g plus h plus i equals 3; and wherein R'° and R" are independently selected from the group consisting of alkyl of from about 1 to about 6 carbon atoms, haloalkyl of from about 1 to about 6 carbons atoms and from 1 to about 3 halogen atoms, hydroxy-polyalkyleneoxy containing 2 to 6 carbon atoms and 2 to 6 oxygen atoms, alkoxy of from about 1 to about 6 carbon atoms, hydroxyalkoxy of from about 2 to about 6 carbon atoms, haloalkoxy of from about 2 to about 6 carbon atoms and from about 1 to about 3 halogen atoms, wherein R12 is selected from the group consisting of alkylene of from about 2 to about 6 carbon atoms, haloalkylene of from about 3 to about 6 carbon atoms and from about 1 to about 3 halogen atoms, polyalkyleneoxy containing 2 to 6 carbon atoms and 1 to 5 oxygen atoms, and hydroxyalkylene of from 3 to about 6 carbon atoms and 1 to 4 hydroxyls, and R13 and R14 are independently selected from the group consisting of hydrogen, hydroxyl, alkyl of from about 1 to about 6 carbon atoms, haloalkyl of from about 1 to about 6 carbon atoms and from about 1 to about 3 halogen atoms, hydroxy-polyalkyleneoxy containing about 2 to about 6 carbon atoms and 2 to 6 oxygen atoms, alkoxy of from about 1 to about 6 carbon atoms, hydroxyalkoxy of from about 2 to about 6 carbon atoms, and haloalkoxy of from about 2 to about 6 carbon atoms and 1 to about 3 halogen atoms, provided that the total number of carbon atoms in the R'° and R11 groups does not exceed about 8.

  本发明公开了一种膨胀剂组合物。申请人公开了这种能赋予木材持久阻燃性的组合物，该组合物由环状氮化合物、含羟基的有机磷化合物、有机磷酸和水组成，其中： a) 所述环状氮化合物为 其中 a、b 和 c 是选自 1 和 2 的整数，a 加 b 加 c 约等于 3 至 6，X、X'和 X "独立地选自氢和-CH3 组成的组； b) 所述含羟基的有机磷化合物选自由下列物质组成的组 和 及其混合物，其中 d 是 0 至 2 的整数，e 是 0 至 2 的整数，f 是 1 至 3 的整数，d 加 e 加 f 等于 3；z 是 0 至 1 的整数；x 是 1 至 2 的整数，y 是 1 至 2 的整数，x 加 y 加 z 等于 3；R R2 和 R3 选自由含约 1 至约 6 个碳原子的烷基和含约 2 至约 6 个碳原子的卤代烷基组成的组，但 R3 为卤代烷基时至少含 3 个碳原子；R4 和 R5 选自由氢、烷基和卤代烷基组成的组，其中所述基含有约 1 至约 6 个碳原子；且 R1、R2、R3、R4 和 R5 基团中的碳原子总数不超过约 14 个；以及 c) 所述酸选自以下组成的组 及其混合物，其中 R6、R7、R8 和 R9 独立地选自氢、约 1 至约 3 个碳原子的烷基、约 1 至约 3 个碳原子的卤代烷基和 1 至约 3 个碳原子的羟烷基组成的组，条件是 R6、R7、R° 和 R9 基团中的碳原子总数不超过约 5；其中 q 是 1 至 2 的整数，h 和 i 是独立选自 0、1 和 2 的整数，且 g 加 h 加 i 等于 3；其中 R'° 和 R "独立地选自由约 1 至约 6 个碳原子的烷基、约 1 至约 6 个碳原子和 1 至约 3 个卤素原子的卤代烷基、含 2 至 6 个碳原子和 2 至 6 个氧原子的羟基聚烯氧基、约 1 至约 6 个碳原子的烷氧基、约 2 至约 6 个碳原子的羟基烷氧基、约 2 至约 6 个碳原子和约 1 至约 3 个卤素原子的卤代烷氧基组成的组、 其中 R12 选自由约 2 至约 6 个碳原子的亚烷基、约 3 至约 6 个碳原子和约 1 至约 3 个卤素原子的卤代亚烷基、含 2 至 6 个碳原子和 1 至 5 个氧原子的聚亚烷氧基以及含 3 至约 6 个碳原子和 1 至 4 个羟基的羟基亚烷基组成的组，而 R13 和 R14 独立地选自由氢、羟基、约 1 至约 6 个碳原子的烷基、约 1 至约 3 个卤素原子的卤代烷基、约 2 至约 6 个碳原子的羟基烷氧基、约 2 至约 6 个碳原子的卤代烷氧基、约 2 至约 6 个碳原子的卤代烷氧基和约 1 至约 3 个卤素原子组成的组、约 1 至约 6 个碳原子和约 1 至约 3 个卤素原子的卤代烷基、含有约 2 至约 6 个碳原子和 2 至 6 个氧原子的羟基聚亚烷氧基、约 1 至约 6 个碳原子的烷氧基、约 2 至约 6 个碳原子的羟基烷氧基和约 2 至约 6 个碳原子和 1 至约 3 个卤素原子的卤代烷氧基，条件是 R'° 和 R11 基团中的碳原子总数不超过约 8 个。
• US4201677A
  申请人：——

  公开号：US4201677A

  公开（公告）日：1980-05-06
• US4345002A
  申请人：——

  公开号：US4345002A

  公开（公告）日：1982-08-17
• Conversion of Tertiary Phosphites to Secondary Phosphonates. Diphenyl Phosphonate¹
  作者：E. N. Walsh

  DOI：10.1021/ja01521a028

  日期：1959.6