| 104634-32-4

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 醌二甲烷类
• CAS: 104634-32-4
• 化学式: C₁₄H₁₀N
• 分子量: 192.24
• InChiKey: ZPFXLHABYAZOHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  4-(羟基苯基甲基)苯甲腈 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Observation of intramolecular dimer radical anion of 1,1-diarylmethanols bearing electron withdrawing groups at room temperature

  摘要：

  Transient absorption measurement of radical anions of 1,1-diarylmethanols bearing electron-withdrawing groups in dimethyl-formamide at room temperature has revealed that symmetric compounds form intramolecular dimer radical anions as an intermediate of their reductive C-O bond dissociation giving diarylmethyl radicals. The dimer radical. anions showed an absorption band in the near infrared region (NIR) (1000-1600 nm) characteristic to their charge resonance (CR) properties. On the contrary to 1, 1-diarylmethanols, corresponding radical anion of 1,3-diarylpropan-1-ol showed no CR band. It is suggested that formation of dimer radical anions is energetically favorable for diaryl compounds with one-atom spacer but unfavorable for them with three-atom spacer being different From the n = 3 rule for the favorable formation of intramolecular excimers. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(00)01089-7

文献信息

• Intrinsic Barriers of the Alternative Modes of Mesolytic Fragmentations of C−S Bonds
  作者：Przemyslaw Maslak、Jay Theroff

  DOI：10.1021/ja960735x

  日期：1996.1.1
• Observation of intramolecular dimer radical anion of 1,1-diarylmethanols bearing electron withdrawing groups at room temperature
  作者：Nobuyuki Ichinose、Junpei Hobo、Sachiko Tojo、Tetsuro Majima

  DOI：10.1016/s0009-2614(00)01089-7

  日期：2000.11

  Transient absorption measurement of radical anions of 1,1-diarylmethanols bearing electron-withdrawing groups in dimethyl-formamide at room temperature has revealed that symmetric compounds form intramolecular dimer radical anions as an intermediate of their reductive C-O bond dissociation giving diarylmethyl radicals. The dimer radical. anions showed an absorption band in the near infrared region (NIR) (1000-1600 nm) characteristic to their charge resonance (CR) properties. On the contrary to 1, 1-diarylmethanols, corresponding radical anion of 1,3-diarylpropan-1-ol showed no CR band. It is suggested that formation of dimer radical anions is energetically favorable for diaryl compounds with one-atom spacer but unfavorable for them with three-atom spacer being different From the n = 3 rule for the favorable formation of intramolecular excimers. (C) 2000 Elsevier Science B.V. All rights reserved.