[3-[[5-[[3-Bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenoxy]phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenyl] phosphate | 1426080-58-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: [3-[[5-[[3-Bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenoxy]phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenyl] phosphate
• 英文别名: [3-[[5-[[3-bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenoxy]phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenyl] phosphate
• CAS: 1426080-58-1
• 化学式: C₇₆H₅₂Cl₈N₆O₁₆P₆
• 分子量: 1774.75
• InChiKey: LBKAVDFFZIIQGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.6
• 重原子数：
  112
• 可旋转键数：
  32
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  269
• 氢给体数：
  0
• 氢受体数：
  22

反应信息

• 作为反应物：
  描述：

  [3-[[5-[[3-Bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenoxy]phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenyl] phosphate 、 对苯二酚 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 5.33h， 以55%的产率得到[3-[[3-[[3-[[5-[[3-Bis[3-[[3-bis(4-hydroxyphenoxy)phosphoryloxyphenyl]iminomethyl]phenoxy]phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenoxy]-[3-[[3-bis(4-hydroxyphenoxy)phosphoryloxyphenyl]iminomethyl]phenoxy]phosphoryl]oxyphenyl]methylideneamino]phenyl] bis(4-hydroxyphenyl) phosphate
  参考文献：
  名称：

  Synthesis, Characterization, and Thermogravimetric Studies of a Phosphorus-Containing Dendron Built from 1,5-Diaminonaphthalene at the Core

  摘要：

  A facile divergent synthesis of a phosphorus-containing dendron containing 1,5-diaminonaphthalene is described. The phosphorus-containing dendron, functionalized with a 1,5-diaminonaphthalene unit at the core and phenolic OH groups grafted at the periphery, has been accomplished in a versatile, simple fashion, using Schiff's condensation and nucleophilic substitution reactions with POCl3, 3-hydroxy-benzaldehyde, 4-hydroxy-benzaldehyde, and 3-amino-phenol iteratively. The structures of intermediate dendrons were characterized by infrared, NMR (H-1, C-13, and P-31), liquid chromatography-mass spectrometry, and C, H, N analysis. The structure of the final dendron (6) was confirmed by infrared, NMR (H-1, C-13, and P-31), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and C, H, N analysis. The thermal stability and degradation of the resulting final dendron was checked by thermal gravitometric analysis/differential thermal analysis.

  DOI：

  10.1080/00397911.2011.628773
• 作为产物：
  描述：

  [3-[[5-[[3-Bis[3-[(3-hydroxyphenyl)iminomethyl]phenoxy]phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis[3-[(3-hydroxyphenyl)iminomethyl]phenyl] phosphate 在 三乙胺 、 三氯氧磷 作用下， 以 四氢呋喃 为溶剂， 反应 5.33h， 以58%的产率得到[3-[[5-[[3-Bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenoxy]phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis[3-[(3-dichlorophosphoryloxyphenyl)iminomethyl]phenyl] phosphate
  参考文献：
  名称：

  Synthesis, Characterization, and Thermogravimetric Studies of a Phosphorus-Containing Dendron Built from 1,5-Diaminonaphthalene at the Core

  摘要：

  A facile divergent synthesis of a phosphorus-containing dendron containing 1,5-diaminonaphthalene is described. The phosphorus-containing dendron, functionalized with a 1,5-diaminonaphthalene unit at the core and phenolic OH groups grafted at the periphery, has been accomplished in a versatile, simple fashion, using Schiff's condensation and nucleophilic substitution reactions with POCl3, 3-hydroxy-benzaldehyde, 4-hydroxy-benzaldehyde, and 3-amino-phenol iteratively. The structures of intermediate dendrons were characterized by infrared, NMR (H-1, C-13, and P-31), liquid chromatography-mass spectrometry, and C, H, N analysis. The structure of the final dendron (6) was confirmed by infrared, NMR (H-1, C-13, and P-31), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and C, H, N analysis. The thermal stability and degradation of the resulting final dendron was checked by thermal gravitometric analysis/differential thermal analysis.

  DOI：

  10.1080/00397911.2011.628773