N,N-Dimethyl-1-chlor-N'-(dichlorphosphinyl)formamidin | 36055-50-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: N,N-Dimethyl-1-chlor-N'-(dichlorphosphinyl)formamidin
• 英文别名: N'-dichlorophosphoryl-N,N-dimethylchloroformamidine；N'-dichlorophosphoryl-N,N-dimethylcarbamimidoyl chloride
• CAS: 36055-50-2
• 化学式: C₃H₆Cl₃N₂OP
• 分子量: 223.426
• InChiKey: LCLUWJJRJSYBAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  32.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二甲基氢胺 在 三氯氧磷 作用下， 生成 N,N-Dimethyl-1-chlor-N'-(dichlorphosphinyl)formamidin
  参考文献：
  名称：

  Kosinskaya,I.M. et al., Journal of general chemistry of the USSR, 1974, vol. 44, p. 1242 - 1244

  摘要：

  DOI：

文献信息

• Kosinskaya,I.M. et al., Journal of general chemistry of the USSR, 1971, vol. 41, p. 2422 - 2424
  作者：Kosinskaya,I.M. et al.

  DOI：——

  日期：——
• The products of phosphorylation of N,N-dialkylureas and dialkylcyanamides with phosphorus pentachloride. NMR spectroscopy study
  作者：L. I. Larina、V. G. Rozinov、K. A. Chernyshev

  DOI：10.1134/s1070363212010112

  日期：2012.1

  The study by H-1 and P-31 NMR spectroscopy has shown that phosphorylation of N,N-dimethylurea and diethylcyanamide with phosphorus pentachloride results in the formation of N'-(N,N-dialkylchloroformamidino) trichlorophosphonium hexachlorophosphorates where the positive charge of the organyltrichlorophosphonium cation is delocalized over the system of the multiple bonds with participation of the lone electron pair of the nitrogen atom. Bis-N'-(N,N-dialkylchloroformamidino)dichlorophosphonium hexachlorophosphorates, dichlorides of N,N-dialkylchloroformamidinophosphonic and thiophosphonic acids are synthesized where the conjugation of the phosphorus-containing substituent with the chloroformamidinium part of the molecules is retained. Organyltetrachlorophosphoranes based on N,N-dimethylurea and diethylcyanamide exist in polar and nonpolar solvents as orhanyltrichlorophosphonium chlorides.