chromium(III)-meso-tetra(4-chlorophenyl)porphyrin | 84151-95-1

• 英文名称: chromium(III)-meso-tetra(4-chlorophenyl)porphyrin
• 英文别名: [(Cl)Cr(5,10,15,20-tetra(p-chlorophenyl)porphyrin)]；[(Cl)Cr(TCP)]；[(Cl)Cr(meso-tetra(p-chlorophenyl)porphyrin)]；chlorochromium(III) meso-tetrakis(4-chlorophenyl)porphyrinate
• CAS: 84151-95-1
• 化学式: C₄₄H₂₄Cl₅CrN₄
• 分子量: 837.962
• InChiKey: ZRPMYULKOQCDQV-YKKPBKTHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chromium(III)-meso-tetra(4-chlorophenyl)porphyrin 在 HCl 、 O₂ 作用下， 以 氯仿 为溶剂， 以30%的产率得到oxo(5,10,15,20-tetrakis(p-chlorophenyl)porphyrinato)chromium(IV)
  参考文献：
  名称：

  Liston, David J.; West, Bruce O., Inorganic Chemistry, 1985, vol. 24, # 10, p. 1568 - 1576

  摘要：

  DOI：
• 作为产物：
  描述：

  六羰基铬 、 5,10,15,20-tetra-(4-chlorophenyl)porphyrin 以 N,N-二甲基甲酰胺 为溶剂， 以81%的产率得到chromium(III)-meso-tetra(4-chlorophenyl)porphyrin
  参考文献：
  名称：

  Liston, David J.; West, Bruce O., Inorganic Chemistry, 1985, vol. 24, # 10, p. 1568 - 1576

  摘要：

  DOI：
• 作为试剂：
  描述：

  (S,Z)-henicos-7-en-10-ol 在 叔丁基过氧化氢 、 4-二甲氨基吡啶 、 dicobalt octacarbonyl 、 bis(acetylacetonate)oxovanadium 、 chromium(III)-meso-tetra(4-chlorophenyl)porphyrin 、 5%-palladium/activated carbon 、 氢气 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 60.0 ℃ 、6.21 MPa 条件下， 反应 65.25h， 生成 奥利司他
  参考文献：
  名称：

  Total Synthesis of Tetrahydrolipstatin, Its Derivatives, and Evaluation of Their Ability to Potentiate Multiple Antibiotic Classes against Mycobacterium Species

  摘要：

  DOI：

  10.1021/acsinfecdis.1c00283

文献信息

• Neely, Frank L.; Bottomley, Lawrence A., Inorganic Chemistry, 1997, vol. 36, # 24, p. 5432 - 5434
  作者：Neely, Frank L.、Bottomley, Lawrence A.

  DOI：——

  日期：——
• Stereoelectronic Aspects of Inter-Metal Nitrogen Atom Transfer Reactions between Nitridomanganese(V) and Chromium(III) Porphyrins
  作者：Lawrence A. Bottomley、Frank L. Neely

  DOI：10.1021/ic960919c

  日期：1997.11.1

  Reactions of nitridomanganese(V) porphyrins with chromium(III) porphyrins resulted in the irreversible formation of nitridochromium(V) porphyrins and manganese(III) porphyrins. The progress of these reactions has been followed spectrophotometrically, electrochemically, and spectroscopically by EPR. Kinetic analysis of the spectrophotometric data obtained during these reactions for a variety of substituted porphyrins showed the reactions to be first order in each of the reactants. Rate constants were dependent upon the electronic and steric effects of the porphyrin substituent, upon the identity of the anion bound to the chromium(III) reactant, and upon the solvent dielectric constant. We propose that the mechanism of these nitrogen atom transfer reactions involves the nucleophilic attack of the nitridomanganese porphyrin donor on the cationic chromium(III) porphyrin acceptor facilitating a net, two-electron redox process mediated by a heterobimetallic mu-nitrido intermediate. This report represents the first systematic study of the stereoelectronic effects involved in the complete, inter-metal nitrogen atom transfer between two metalloporphyrins.
• Bajju, Gauri D.; Ashu; Devi, Gita, Indian Journal of Heterocyclic Chemistry, 2018, vol. 28, # 2, p. 213 - 220
  作者：Bajju, Gauri D.、Ashu、Devi, Gita、Ahmed, Altaf、Dar, Umar Ali、Katoch, Sapna

  DOI：——

  日期：——