cyclopenta-1,3-diene;N-[[cyclopenta-2,4-dien-1-ylmethyl(diethylaminomethyl)phosphoryl]methyl]-N-ethylethanamine;iron(2+) | 200813-67-8

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: cyclopenta-1,3-diene;N-[[cyclopenta-2,4-dien-1-ylmethyl(diethylaminomethyl)phosphoryl]methyl]-N-ethylethanamine;iron(2+)
• CAS: 200813-67-8
• 化学式: C₂₁H₃₅FeN₂OP
• 分子量: 418.342
• InChiKey: UWUWAGFODZCZTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cyclopenta-1,3-diene;N-[[cyclopenta-2,4-dien-1-ylmethyl(diethylaminomethyl)phosphanyl]methyl]-N-ethylethanamine;iron(2+) 以 not given 为溶剂， 生成 cyclopenta-1,3-diene;N-[[cyclopenta-2,4-dien-1-ylmethyl(diethylaminomethyl)phosphoryl]methyl]-N-ethylethanamine;iron(2+)
  参考文献：
  名称：

  FcCH₂P(CH₂OH)₂: a new, reactive yet air-stable ferrocene-derived phosphine [Fc =(η-C₅H₅)FeC₅H₄]

  摘要：

  Reaction of FcCH(2)NMe(3)(+)I(-) with an excess of P(CH2OH)3 gives the air-stable ferrocenylphosphine FcCH(2)P(CH2OH)(2), characterised by an X-ray structure determination; reactivity towards reagents such as MeI, acrylonitrile and amines allows the synthesis of a range of new ferrocene-phosphine derivatives.

  DOI：

  10.1039/cc9960001551

文献信息

• Synthesis and reactivity of the ferrocene-derived phosphine [Fe(η-C5H5){η-C5H4CH2P(CH2OH)2}]
  作者：Nicholas J. Goodwin、William Henderson、Brian K. Nicholson、J. Kwabena Sarfo、John Fawcett、David R. Russell

  DOI：10.1039/a703666c

  日期：——

  The air-stable compound [Fe(η-C5H5)η-C5H4CH2P(CH2OH)2}] 1 has been prepared by the reaction of [Fe(η-C5H5)(η-C5H4CH2NMe3)]I with an excess of P(CH2OH)3. Compound 1 has been used to produce a range of other new compounds, thus demonstrating its versatility as a starting material; the phosphine oxide [Fe(η-C5H5)η-C5H4CH2P(O)(CH2OH)2}] 2, phosphine sulfide [Fe(η-C5H5)η-C5H4CH2P(S)(CH2OH)2}] 3, and other derivatives [Fe(η-C5H5)η-C5H4CH2P(CH2CH2CN)2}] 4, [Fe(η-C5H5)η-C5H4CH2P(CH2NEt2)2}] 5, [Fe(η-C5H5)η-C5H4CH2P(O)(CH2NEt2)2}] 6, [Fe(η-C5H5)η-C5H4CH2P(Me)(CH2OH)2}]I 7 and [Fe(η-C5H5)η-C5H4CH2P(Me)CH2OH}] 8. Crystal structure determinations for 1, 3 and 7 are reported and the hydrogen bonding of each structure described.

  空气稳定化合物 [Fe(η-C5H5)η-C5H4CH2P(CH2OH)2}] 1 通过 [Fe(η- )(η-C5H4CH2NMe3)]I 与过量 P(CH2OH)3 反应制备。化合物 1 已被用于合成一系列其他新化合物，从而展示了其作为起始材料的多样性；包括膦氧化物 [Fe(η- )η-C5H4CH2P(O)(CH2OH)2}] 2，膦硫化物 [Fe(η- )η-C5H4CH2P(S)(CH2OH)2}] 3，以及其他衍生物 [Fe(η- )η-C5H4CH2P(CH2CH2CN)2}] 4，[Fe(η- )η-C5H4CH2P(CH2NEt2)2}] 5，[Fe(η- )η-C5H4CH2P(O)(CH2NEt2)2}] 6，[Fe(η- )η-C5H4CH2P(Me)(CH2OH)2}]I 7 和 [Fe(η- )η-C5H4CH2P(Me)CH2OH}] 8。报道了 1、3 和 7 的晶体结构测定，并描述了每种结构的氢键。