[3-[(E)-[1,3-benzothiazol-2-yl(hexyl)hydrazinylidene]methyl]-4-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [3-[(E)-[1,3-benzothiazol-2-yl(hexyl)hydrazinylidene]methyl]-4-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• 化学式: C₅₂H₅₉N₃O₁₀S
• 分子量: 918.1
• InChiKey: HDZBSDBYEQHIHM-CDZCAJNNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  66
• 可旋转键数：
  34
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  180
• 氢给体数：
  0
• 氢受体数：
  14

文献信息

• METHOD FOR PRODUCING 2-HYDRAZINOBENZOTHIAZOLE DERIVATIVE
  申请人：DIC Corporation

  公开号：US20200165215A1

  公开（公告）日：2020-05-28

  The present invention provides a novel method for producing a 2-hydrazinobenzothiazole derivative. The present invention also provides a method for producing a compound by using the 2-hydrazinobenzothiazole derivative obtained by the production method, and a composition that contains the compound. The present invention also provides a polymerizable composition that is useful in producing film-shaped polymers and contains the compound obtained by the production method. The invention of the present application provides a method for producing a compound represented by general formula (I-C), the method including a step of reacting a compound represented by general formula (I-B) with a compound represented by general formula (I-A) in the presence of at least one compound selected from the group consisting of metal amides, metal hydrides, metal alkoxides, and organic alkali metals. A compound derived from the compound produced by the production method, and a composition that contains the compound are also provided.

  本发明提供一种生产2-联苯并噻唑酮衍生物的新方法。本发明还提供一种通过使用通过生产方法获得的2-联苯并噻唑酮衍生物生产化合物的方法，以及含有该化合物的组合物。本发明还提供一种可用于生产膜状聚合物的可聚合组合物，其中包含通过生产方法获得的化合物。本申请的发明提供了一种生产通式(I-C)所代表的化合物的方法，该方法包括在至少选择自金属胺、金属氢化物、金属烷氧化物和有机碱金属组成的群体中，通过将通式(I-B)所代表的化合物与通式(I-A)所代表的化合物在存在下反应的步骤。还提供了通过生产方法产生的化合物衍生物以及含有该化合物的组合物。
• POLYMERIZABLE COMPOUND, COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, LIQUID CRYSTAL DISPLAY ELEMENT, AND ORGANIC EL DEVICE
  申请人：DIC Corporation

  公开号：US20170260150A1

  公开（公告）日：2017-09-14

  It is an object of the present invention to provide a polymerizable compound having a good liquid crystal property, a good alignment property, sufficient solubility in solvents, high preservation stability in a solution state, and high optical stability; a composition including the polymerizable compound; a polymer produced by polymerizing the polymerizable compound, such as a resin produced using the polymerizable compound; an optically anisotropic body including the polymer; and a liquid crystal display element and an organic EL device that include the optically anisotropic body. As a result of conducting intensive studies in order to achieve the above object, the compound represented by General Formula (I) is developed.

  本发明的目的是提供一种具有良好液晶性能、良好对准性能、在溶剂中具有足够溶解性、在溶液状态下具有高保持稳定性和高光学稳定性的可聚合化合物；包括该可聚合化合物的组合物；通过聚合该可聚合化合物而产生的聚合物，如使用该可聚合化合物生产的树脂；包括聚合物的光学各向异性体；以及包括光学各向异性体的液晶显示元件和有机EL器件。为了实现上述目标，进行了深入研究，开发了由一般式（I）表示的化合物。
• Polymerizable compound, composition, polymer, optically anisotropic body, liquid crystal display element, and organic EL display
  申请人：DIC Corporation

  公开号：US10633353B2

  公开（公告）日：2020-04-28

  It is an object of the present invention to provide a polymerizable compound having a good liquid crystal property, a good alignment property, sufficient solubility in solvents, high preservation stability in a solution state, and high optical stability; a composition including the polymerizable compound; a polymer produced by polymerizing the polymerizable compound, such as a resin produced using the polymerizable compound; an optically anisotropic body including the polymer; and a liquid crystal display element and an organic EL device that include the optically anisotropic body. As a result of conducting intensive studies in order to achieve the above object, the compound represented by General Formula (I) is developed.

  本发明的目的是提供一种可聚合化合物，该化合物具有良好的液晶特性、良好的对准特性、在溶剂中的充分溶解性、在溶液状态下的高保存稳定性和高光学稳定性；一种组合物，该组合物包括可聚合化合物；通过聚合该可聚合化合物生产的聚合物，例如使用该可聚合化合物生产的树脂；包括该聚合物的光学各向异性体；以及包括该光学各向异性体的液晶显示元件和有机电致发光器件。为了实现上述目标，经过深入研究，开发出了通式（I）表示的化合物。
• Polymerizable compound, polymerizable composition, polymer, and optically anisotropic material
  申请人：ZEON CORPORATION

  公开号：US10647794B2

  公开（公告）日：2020-05-12

  The invention provides a polymerizable compound of formula (I), polymerizable composition, polymer, and optically anisotropic article capable of obtaining an optical film having a low melting point, excellent solubility, being manufactured at low cost, and of uniform polarized light conversion across a broad wavelength region. In formula (I): Y1 to Y6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—; G1 and G2 are independently a divalent C1-C20 aliphatic group; Z1 and Z2 are independently a C2-C10 alkenyl group substituted with a halogen atom; Ax is a C2-C30 organic group that includes at least one aromatic ring of an aromatic hydrocarbon ring or an aromatic hetero ring; Ay is H, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group; A1 is a trivalent aromatic group; A2 and A3 are independently a divalent C6-C30 aromatic group; and Q1 is H, or a C1-C6 alkyl group.

  本发明提供了一种可聚合的式(I)化合物、可聚合组合物、聚合物和光学各向异性制品，能够获得熔点低、溶解性好、制造成本低、在宽波长区域内偏振光转换均匀的光学薄膜。在式 (I) 中Y1 至 Y6 独立地为化学单键、-O-、-O-C(═O)-、-C(═O)-O-；G1 和 G2 独立地为二价 C1-C20 脂肪族基团；Z1 和 Z2 独立地为被卤原子取代的 C2-C10 烯基；Ax 是 C2-C30 有机基团，其中包括至少一个芳香烃环或芳香杂环；Ay 是 H、C1-C20 烷基、C2-C20 烯基、C3-C12 环烷基；A1 是三价芳香基团；A2 和 A3 独立地是二价 C6-C30 芳香基团；Q1 是 H 或 C1-C6 烷基。
• Composition including compound having mesogenic group, polymer and optically anisotropic body obtained by polymerizing polymerizable composition, and phase difference film
  申请人：DIC Corporation

  公开号：US10649124B2

  公开（公告）日：2020-05-12

  A polymerizable composition of the present invention has favorable solubility, and an optically anisotropic body using the polymerizable composition is unlikely to discolor and is excellent in heat resistance and light resistance. The problem to be solved by the present invention is to provide a polymer obtained by polymerizing the polymerizable composition and an optically anisotropic body using the polymer. The present invention relates to a polymerizable composition which includes a compound having at least one mesogenic group and satisfying an expression represented by Expression (1), and which satisfies an expression represented by Expression (2). 0.5≤YI/Δn≤500  Expression (2)

  本发明的可聚合组合物具有良好的溶解性，使用该可聚合组合物的光学各向异性体不易褪色，且具有优异的耐热性和耐光性。本发明要解决的问题是提供一种通过聚合该可聚合组合物而得到的聚合物和一种使用该聚合物的光学各向异性体。本发明涉及一种可聚合组合物，该组合物包括一种具有至少一个介原基并满足表达式（1）所表示的表达式的化合物，以及满足表达式（2）所表示的表达式的可聚合组合物。 0.5≤YI/Δn≤500 表达式 (2)