[4-(4-Ethylphenoxy)carbonylphenyl] 4-(3-prop-2-enoyloxypropoxy)benzoate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [4-(4-Ethylphenoxy)carbonylphenyl] 4-(3-prop-2-enoyloxypropoxy)benzoate
• 英文别名: [4-(4-ethylphenoxy)carbonylphenyl] 4-(3-prop-2-enoyloxypropoxy)benzoate
• 化学式: C₂₈H₂₆O₇
• 分子量: 474.5
• InChiKey: DXAIFCXEVLNMGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  35
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  88.1
• 氢给体数：
  0
• 氢受体数：
  7

文献信息

• CHOLESTERIC LIQUID CRYSTAL MIXTURE, FILM, INFRARED REFLECTING PLATE, LAMINATED ARTICLE, AND LAMINATED GLASS
  申请人：Fujifilm Corporation

  公开号：EP2832821A1

  公开（公告）日：2015-02-04

  A cholesteric liquid crystal mixture containing a compound represented by formula (Ia) : Z1-Y1-A1-Y3-M1-Y4-A2-Y2-Z2, a compound represented by formula (Ib) : Z3-Y5-A3-Y7-M2-P, and a tri- or higher functional polymerizable monomer suppresses deposition of a liquid crystal at the time of forming a film, exhibits a wide characteristic reflection bandwidth of a film to be obtained, and suppresses change of a reflection bandwidth caused when laminated glass is manufactured by laminating a liquid crystal film obtained by fixing a cholesteric liquid crystal phase of the film to be obtained with an interlayer film. Z1, Z2 and Z3 represent a polymerizable group; A1, A2 and A3 represent a spacer having an atom-bonding chain length of 1 to 30, provided that the spacer represents an alkylene group, or a linking group of multiple alkylene groups bonding to each other via -O- or -CO-; M1 and M2 represent (-T1-Y8)n-T2-; n indicates a natural number; when n is 2 or more, multiple (-T1-Y8)'s may be the same or different; T1 and T2 represent a saturated or unsaturated hydrocarbon ring, or a saturated or unsaturated heterocyclic ring, provided that the hydrocarbon ring and the heterocyclic ring may have a substituent; Y1, Y2, Y3, Y4, Y5, Y7 and Y8 each independently represent a single bond, -O-, -CO-, -O-CO-, -CO-O- or -O-CO-O-; and P represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms.

  一种胆甾型液晶混合物，含有由式 (Ia) ：Z1-Y1-A1-Y3-M1-Y4-A2-Y2-Z2、由式 (Ib) ：Z3-Y5-A3-Y7-M2-P，以及一种三官能团或更高官能团的可聚合单体，可抑制成膜时液晶的沉积，使获得的薄膜具有较宽的特性反射带宽，并可抑制通过将获得的薄膜的胆甾液晶相固定而获得的液晶薄膜与中间膜层压而制造层压玻璃时引起的反射带宽变化。Z1、Z2 和 Z3 代表可聚合基团；A1、A2 和 A3 代表原子键合链长度为 1 至 30 的间隔物，条件是间隔物代表亚烷基，或通过 -O- 或 -CO- 相互键合的多个亚烷基的连接基团；M1 和 M2 代表 (-T1-Y8)n-T2-；n 表示自然数；当 n 为 2 或更多时，多个 (-T1-Y8) 可以相同或不同；T1和T2代表饱和或不饱和烃环，或饱和或不饱和杂环，条件是烃环和杂环可以具有取代基；Y1、Y2、Y3、Y4、Y5、Y7和Y8各自独立地代表单键、-O-、-CO-、-O-CO-、-CO-O-或-O-CO-O-；P代表氢原子或具有1至15个碳原子的烷基。
• COMPOUND CONTAINING MESOGENIC GROUP, AND MIXTURE, COMPOSITION, AND OPTICALLY ANISOTROPIC BODY USING SAID COMPOUND
  申请人：DIC Corporation

  公开号：EP3088426A1

  公开（公告）日：2016-11-02

  The present invention relates to a compound containing a mesogenic group, which includes a silicon compound at a low concentration, a polymerizable compound containing the mesogenic group, a mixture and a composition using these compounds, a polymerizable mixture having the polymerizable compound, and a polymer, an optically anisotropic body, and a phase difference film using the polymerizable composition. According to the present invention, it is possible to obtain the optically anisotropic body and the phase difference film having satisfactory scratch resistance and adhesion, by using the polymerizable composition composed of the compound containing a mesogenic group, which includes a silicon compound at a low concentration. The polymer obtained by polymerizing the polymerizable liquid crystal composition of the present invention in a state where the composition is horizontally aligned, vertically aligned, or aligned in a hybrid manner or aligned in a cholesteric manner can be used as the optically anisotropic body having alignment performance, or as an optical compensation film, a phase difference film, a wide viewing angle film, a luminance-enhancing film, a reflective film, and a polarizing film.

  本发明涉及一种含有介原基的化合物，其中包括低浓度硅化合物、含有介原基的可聚合化合物、使用这些化合物的混合物和组合物、含有可聚合化合物的可聚合混合物以及聚合物、光学各向异性体和使用可聚合组合物的相位差薄膜。 根据本发明，通过使用由含有中生基的化合物组成的可聚合组合物（其中包括低浓度的硅化合物），可以获得具有令人满意的抗划伤性和粘附性的光学各向异性体和相位差膜。 本发明的可聚合液晶组合物在水平排列、垂直排列、混合排列或胆固醇排列的状态下聚合得到的聚合物可用作具有排列性能的光学各向异性体，或用作光学补偿膜、相位差膜、广视角膜、亮度增强膜、反射膜和偏振膜。
• Compound containing mesogenic group, and mixture, composition, and optically anisotropic body using said compound
  申请人：DIC Corporation

  公开号：US10473820B2

  公开（公告）日：2019-11-12

  There is provided a compound containing a mesogenic group, which includes a silicon compound at a low concentration, a polymerizable compound containing the mesogenic group, a mixture and a composition using these compounds, a polymerizable mixture having the polymerizable compound, and a polymer, an optically anisotropic body, and a phase difference film using the polymerizable composition. It is possible to obtain the optically anisotropic body and the phase difference film having satisfactory scratch resistance and adhesion, by using the polymerizable composition composed of the compound containing a mesogenic group, which includes a silicon compound at a low concentration.

  本发明提供了一种含有介原基的化合物（其中包括低浓度硅化合物）、一种含有介原基的可聚合化合物、一种使用这些化合物的混合物和组合物、一种含有可聚合化合物的可聚合混合物以及一种聚合物、一种光学各向异性体和一种使用该可聚合组合物的相位差薄膜。通过使用由包含低浓度硅化合物的含有介原基的化合物组成的可聚合组合物，可以获得具有令人满意的抗划伤性和粘附性的光学各向异性体和相位差膜。
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER MATERIAL, AND FILM
  申请人：FUJIFILM Corporation

  公开号：US20140183410A1

  公开（公告）日：2014-07-03

  A polymerizable liquid-crystal compound of formula (I) effective for preventing crystal deposition after coating with polymerizable liquid crystal (II) or a polymerizable liquid crystal similar thereto. P represents a polymerizable functional group; Sp represents a spacer or a single bond; Z 1 and Z 2 each represent —CO—O—; R 0 represents a linear alkyl group having 1-15 carbon atoms; R 2 , R 3 and R 4 each independently represent an alkyl group having 1-4 carbon atoms, an alkoxy group having 1-4 carbon atoms, an alkoxycarbonyl group having 2-5 carbon atoms, an acyloxy group having 2-5 carbon atoms, an acyl group having 2-4 carbon atoms, an amide group having 2-5 carbon atoms, a cyano group, an amino group, a hydroxyl group, or a halogen atom; r 1 , r 2 and r 3 indicate an integer from 0-4; when r 1 , r 2 and r 3 each are 2 or more, then R 2 , R 3 and R 4 each may be the same or different; however, when R 0 is a methyl group, then r 2 is not 1.
• CHOLESTERIC LIQUID CRYSTAL MIXTURE, FILM, SELECTIVE REFLECTIVE PLATE, LAMINATE, LAMINATED GLASS
  申请人：FUJIFILM CORPORATION

  公开号：US20140192286A1

  公开（公告）日：2014-07-10

  A cholesteric liquid-crystal mixture containing a compound represented by the general formula (Ia), a compound represented by the general formula (Ib), a fluorine-containing horizontal alignment agent and a polymerization initiator is capable of forming a film which is prevented from precipitation of liquid-crystal compounds therein, of which the haze is reduced and which has a broad reflection width. Z 1 —Y 1 -A 1 -Y 3 -M 1 -Y 4 -A 2 -Y 2 —Z 2 General Formula (Ia) Z 3 —Y 5 -A 3 -Y 7 -M 2 -P  General Formula (Ib)