4-[4-[6-(2-Methylprop-2-enoyloxy)hexoxy]benzoyl]oxybenzoic acid

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-[4-[6-(2-Methylprop-2-enoyloxy)hexoxy]benzoyl]oxybenzoic acid
• 英文别名: 4-[4-[6-(2-methylprop-2-enoyloxy)hexoxy]benzoyl]oxybenzoic acid
• 化学式: C₂₄H₂₆O₇
• 分子量: 426.466
• InChiKey: YGUVCYUPTHVVCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  31
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  99.1
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  [4-(Ethoxymethoxycarbonyl)phenyl] 4-[6-(2-methylprop-2-enoyloxy)hexoxy]benzoate 在 4-甲基苯磺酸吡啶 作用下， 以 乙醇 为溶剂， 以19.2 g的产率得到4-[4-[6-(2-Methylprop-2-enoyloxy)hexoxy]benzoyl]oxybenzoic acid
  参考文献：
  名称：

  具有水平电场驱动型液晶显示元件用液晶取 向膜的基板的制造方法

  摘要：

  本发明提供以高效率被赋予取向控制能力的、烧屏特性优异的水平电场驱动型液晶显示元件。本发明提供具有液晶取向膜的基板的制造方法，该液晶取向膜为通过下述方法得到的被赋予了取向控制能力的水平电场驱动型液晶显示元件用液晶取向膜，该方法包括：[I]将含有(A)在规定的温度范围内呈现液晶性的感光性的侧链型高分子、和(B)有机溶剂的聚合物组合物涂布在具有水平电场驱动用的导电膜的基板上以形成涂膜的工序；[II]对由[I]得到的涂膜照射偏振紫外线的工序；以及[III]对由[II]得到的涂膜进行加热的工序。

  公开号：

  CN107473969B

文献信息

• LIQUID CRYSTAL ALIGNING AGENT FOR PHOTO-ALIGNMENT, ALIGNING MATERIAL AND RETARDATION MATERIAL
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3299879A1

  公开（公告）日：2018-03-28

  There is provided a liquid crystal alignment agent for photo-alignment for providing an aligning member which has excellent photoreaction efficiency and is capable of aligning polymerizable liquid crystals with high sensitivity. A liquid crystal alignment agent for photo-alignment comprising (A) a resin having a side chain including a structure of Formula (1) and (B) a compound of Formula (2), an alignment member obtained from the liquid crystal alignment agent, and a retardation member: wherein X1 is a benzene ring which may be arbitrarily substituted with an substituent, R is a substituent selected from OH and NH2, R1, R2, R3, R4 and R5 are each independently a substituent selected from a hydrogen atom, a halogen atom, C1-6 alkyl, C1-6 haloalkyl, etc., and n is an integer of 0 or 1.

  本发明提供了一种用于光配准的液晶配准剂，用于提供一种配准构件，该配准构件具有优异的光反应效率，能够以高灵敏度配准可聚合液晶。一种用于光配准的液晶配准剂包括：(A) 具有包括式 (1) 结构的侧链的树脂；(B) 式 (2) 化合物；由液晶配准剂获得的配准构件；以及缓凝构件： 其中 X1 是可被取代基任意取代的苯环，R 是选自 OH 和 NH2 的取代基，R1、R2、R3、R4 和 R5 各自独立地是选自氢原子、卤素原子、C1-6 烷基、C1-6 卤代烷基等的取代基，n 是 0 或 1 的整数。
• Liquid crystal alignment agent for photo-alignment, aligning member, and retardation member
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US10428274B2

  公开（公告）日：2019-10-01

  A liquid crystal alignment agent for photo-alignment for providing an aligning member has excellent photoreaction efficiency and is capable of aligning polymerizable liquid crystals with high sensitivity. A liquid crystal alignment agent for photo-alignment includes (A) a resin having a side chain including a structure of Formula (1) and (B) a compound of Formula (2), an alignment member obtained from the liquid crystal alignment agent, and a retardation member: wherein X1 is a benzene ring which may be arbitrarily substituted with an substituent, R is a substituent selected from OH and NH2, R1, R2, R3, R4 and R5 are each independently a substituent selected from a hydrogen atom, a halogen atom, C1-6 alkyl, C1-6 haloalkyl, etc., and n is an integer of 0 or 1.

  一种用于光配准的液晶配准剂，用于提供配准构件，具有优异的光反应效率，能够以高灵敏度配准可聚合液晶。一种用于光配准的液晶配准剂包括（A）具有包括式（1）结构的侧链的树脂和（B）式（2）化合物、从液晶配准剂中获得的配准构件以及缓凝构件：其中 X1 是可被取代基任意取代的苯环，R 是选自 OH 和 NH2 的取代基，R1、R2、R3、R4 和 R5 各自独立地是选自氢原子、卤素原子、C1-6 烷基、C1-6 卤代烷基等的取代基、n 是 0 或 1 的整数。
• PHOTOSENSITIVE POLYMER AND PHOTOALIGNABLE PHASE DIFFERENCE FILM
  申请人：JNC Petrochemical Corporation

  公开号：US20140225047A1

  公开（公告）日：2014-08-14

  To provide a photosensitive polymer, a phase difference film using the photosensitive polymer, and an optical film using the phase difference film. A solution is a photosensitive polymer having a constitutional unit represented by formula (1): wherein, in formula (1), for example, R 1 is hydrogen or methyl; a is 2 or 3; p is an integer from 1 to 12; X 1 is —O—, —COO— or —OCO—; b is an integer from 0 to 3; A 1 is a divalent group selected from 1,4-phenylene or naphthalene-2,6-diyl, and in the divalent group, at least one of hydrogen may be replaced by fluorine or chlorine; Z 1 is a single bond, —COO—, —CH═CH—COO—, —CH 2 CH 2 —COO—, —CH 2 O— or —CONH—; W 1 and W 2 are hydrogen, fluorine or 1-5C alkyl or alkoxy; Y 1 is —O—; and R 2 is 1-20C alkyl, and at least one of —CH 2 — in the alkyl may be replaced by —O—.
• LIQUID CRYSTAL ALIGNMENT AGENT FOR PHOTO-ALIGNMENT, ALIGNING MEMBER, AND RETARDATION MEMBER
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US20180119016A1

  公开（公告）日：2018-05-03

  A liquid crystal alignment agent for photo-alignment for providing an aligning member has excellent photoreaction efficiency and is capable of aligning polymerizable liquid crystals with high sensitivity. A liquid crystal alignment agent for photo-alignment includes (A) a resin having a side chain including a structure of Formula (1) and (B) a compound of Formula (2), an alignment member obtained from the liquid crystal alignment agent, and a retardation member: wherein X1 is a benzene ring which may be arbitrarily substituted with an substituent, R is a substituent selected from OH and NH 2 , R 1 , R 2 , R 3 , R 4 and R 5 are each independently a substituent selected from a hydrogen atom, a halogen atom, C 1-6 alkyl, C 1-6 haloalkyl, etc., and n is an integer of 0 or 1.
• US9388259B2
  申请人：——

  公开号：US9388259B2

  公开（公告）日：2016-07-12