potassium cyclohexylsulfamate | 7758-04-5

中文名称

——

中文别名

——

英文名称

potassium cyclohexylsulfamate

英文别名

potassium cyclamate；potassium;N-cyclohexylsulfamate

CAS

7758-04-5

化学式

C₆H₁₂NO₃S*K

mdl

——

分子量

217.33

InChiKey

PALPTWOXTUVPKA-UHFFFAOYSA-M

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

-2.63
重原子数：

12
可旋转键数：

1
环数：

1.0
sp3杂化的碳原子比例：

1.0
拓扑面积：

77.6
氢给体数：

1
氢受体数：

4

反应信息

作为产物：

描述：

Cyclohexyl-sulfamic acid 2-hydroxy-phenyl ester 在氢氧化钾作用下，以水为溶剂，反应 1.0h，以99%的产率得到potassium cyclohexylsulfamate

参考文献：

名称：

Sulfonylamine-mediated sulfamation of amines. A mild, high yield synthesis of sulfamic acid salts

摘要：

DOI：

10.1021/jo01314a033

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文献信息

Process for bleaching keratin fibers

申请人：Javet Manuela

公开号：US20070231283A1

公开（公告）日：2007-10-04

The present patent application relates to a process for bleaching keratin fibers which is characterized by applying to the fiber a ready-to-use agent having a basic pH and containing: a) at least one bleach booster according to the general formula (I) wherein R1 is a hydrogen, R2 is hydrogen, a substituted or unsubstituted C1- to C12-alkyl group, a substituted or unsubstituted C1- to C12-monohydroxy-alkyl group, a substituted or unsubstituted C2- to C12-polyhydroxy alkyl group, or a substituted saturated, unsaturated or aromatic 4- to 8-membered carbocycle or heterocycle, and R3 is a OR-Group, with R being equal to hydrogen, an ammonium group, or an alkali metal, or an earth alkali metal atom; b) at least one appropriate type-2 bleach-stable direct dye; and c) at least one oxidant, and after an exposure time of 5 to 60 minutes at a temperature of 10 to 70° C. rinsing the fiber with water as well as the use of special type-2 bleach-stable direct dyes for acquiring a natural looking bleaching of keratin fibers, particularly human hair, without undesired undertones.

本专利申请涉及一种漂白角蛋白纤维的方法，其特征在于将具有碱性pH值的即用型剂涂覆于纤维上，该剂含有：a）至少一种漂白增强剂，其一般式为（I），其中R1为氢，R2为氢、取代或未取代的C1-C12烷基、取代或未取代的C1-C12单羟基烷基、取代或未取代的C2-C12多羟基烷基或取代的饱和、不饱和或芳香4-8成员碳环或杂环，R3为OR-基团，其中R等于氢、铵基或碱金属或碱土金属原子；b）至少一种适当的2型漂白稳定直接染料；以及c）至少一种氧化剂，经过5至60分钟的暴露时间，在10至70℃的温度下，用水冲洗纤维，以及使用特殊的2型漂白稳定直接染料，以获得天然外观的角蛋白纤维漂白，特别是人类头发，无不良底色。
Agent for simultaneous lightening and coloring of keratin fibres containing a sulfamate bleach booster

申请人：Wella Aktiengesellschaft

公开号：EP1759685A1

公开（公告）日：2007-03-07

The present patent application relates to a ready-to-use agent for simultaneously lightening and dyeing keratin fibers (especially human hair), having a basic pH and being characterized by containing a) at least one bleach booster according to the general formula (I) wherein R1 is a hydrogen, R2 is hydrogen, a substituted or unsubstituted C1- to C12-alkyl group, a substituted or unsubstituted C1- to C12-monohydroxy-alkyl group, a substituted or unsubstituted C2- to C12-polyhydroxy alkyl group, or a substituted saturated, unsaturated or aromatic 4- to 8-membered carbocycle or heterocycle, and R3 is a OR-Group, with R being equal to hydrogen, an ammonium group or an alkali metal or an earth alkali metal atom; and b) at least one direct dye and/or at least one oxidation dye/dye precursor and c) at least one oxidant; a multi-component-kit and a method for simultaneous lightening and coloring hair.

本专利申请涉及一种即用型药剂，用于同时对角蛋白纤维（尤其是人类头发）进行淡化和染色，该药剂具有碱性 pH 值，其特征在于含有 a) 至少一种符合通式（I）的漂白增效剂； b) 至少一种符合通式（II）的漂白增效剂； c) 至少一种符合通式（I）的漂白增效剂。其中 R1 是氢；R2 是氢、取代或未取代的 C1 至 C12 烷基、取代或未取代的 C1 至 C12 单羟基烷基、取代或未取代的 C2- 至 C12 多羟基烷基或取代的饱和、不饱和或芳香的 4 至 8 元碳环或杂环；R3 是 OR 基团，其中 R 等于氢、铵基团或碱金属或土碱金属原子；以及 b) 至少一种直接染料和/或至少一种氧化染料/染料前体；以及 c) 至少一种氧化剂；一种多组分套件和一种同时美白和染发的方法。
DUBOIS G. E.; STEPHENSON R. A., J. ORG. CHEM., 1980, 45, NO 26, 5371-5373

作者：DUBOIS G. E.、 STEPHENSON R. A.

DOI：——

日期：——
AGENT FOR SIMULTANEOUS LIGHTENING AND COLORING OF KERATIN FIBRES CONTAINING A SULFAMATE BLEACH BOOSTER

申请人：The Procter and Gamble Company

公开号：EP1919440A2

公开（公告）日：2008-05-14
PROCESS FOR BLEACHING KERATIN FIBERS

申请人：The Procter and Gamble Company

公开号：EP1919439A2

公开（公告）日：2008-05-14

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potassium cyclohexylsulfamate | 7758-04-5

分子结构分类

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ADMET

反应信息

文献信息

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