indium(III) borate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 英文名称: indium(III) borate
• 英文别名: indium orthoborate；indium(III) orthoborate；indium borate；2,4,5-trioxa-1-bora-3-indabicyclo[1.1.1]pentane
• 化学式: BO₃*In
• 分子量: 173.629
• InChiKey: JNOXFAKBEFRROH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.33
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  indium(III) oxide 、 硼酸 在 草酸 作用下， 生成 indium(III) borate
  参考文献：
  名称：

  A Lewis acid–base paired InBO₃ catalyst: synthesis and high selectivity for isopropanol dehydrogenation

  摘要：

  由于 InBO3 纳米粒子表面具有大量路易斯碱性，因此在高温催化异丙醇转化过程中，采用溶解热法制备的 InBO3 纳米粒子主要表现出丙酮选择性。

  DOI：

  10.1039/d3dt00941f

文献信息

• Growth of Bulk InBO₃Crystals
  作者：N. G. Kononova、A. E. Kokh、T. B. Bekker、P. P. Fedorov、E. A. Tkachenko

  DOI：10.1023/b:inma.0000048223.23945.f4

  日期：2004.11

  Conditions are optimized for top-seeded solution growth of bulk indium orthoborate, InBO3, crystals using the Na2O-BaO-B2O3 flux system. InBO3 has a hexagonal unit cell and is isostructural with calcite; a = 4.812 Angstrom, c = 15.47 Angstrom, microhardness of 11 +/- 0.70 GPa. InBO3 crystals are essentially insoluble in common organic and inorganic solvents.
• Low temperature preparation and characterization of In1−xLnxBO3 (x=0.0 and 0.05; Ln=Gd, Eu, Dy and Sm): ESR of In0.95Gd0.05BO3 and emission of In0.95Eu0.05BO3
  作者：Radha Velchuri、B. Vijaya Kumar、V. Rama Devi、K. Ravi Kumar、G. Prasad、M. Vithal

  DOI：10.1016/j.saa.2009.08.003

  日期：2009.10

  Indium borate and rare earth Substituted indium borates (In(1-x)Ln(x)BO(3) (x=0.0 and 0.05; Ln=Gd. Eu, Dy and Sm)) are prepared at low temperature by metathesis reaction using InCl3, LnCl(3) and NaBO2. They are characterized by powder XRD and infrared spectroscopy. All the compositions (In(1-x)Ln(x)BO(3)) crystallize in hexagonal lattice with calcite structure. These borates gave characteristic IR vibrations of planar BO3 group. Spin-Hamiltonian parameters for Gd3+ are deduced from room temperature electron spin resonance spectrum of In0.95Gd0.05BO3. The electron spin resonance spectrum of In0.95Gd0.05BO3 gave several anisotropic lines with g > 2.0. The ESR spectrum of the sample belongs to the "intermediate" category with 1/4
• Rudenko, Inorganic Materials, <hi>1998</hi>, vol. 34, # 12, p. 1253 - 1254
  作者：Rudenko

  DOI：——

  日期：——
• Levin, E. M.; Roth, R. S.; Martin, J. B., American Mineralogist, <hi>1961</hi>, vol. 46, p. 1030 - 1055
  作者：Levin, E. M.、Roth, R. S.、Martin, J. B.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.7, 5.6.3, page 98 - 98
  作者：

  DOI：——

  日期：——