calcium magnesium phosphate | 25618-23-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱土金属氧阴离子化合物
• 英文名称: calcium magnesium phosphate
• 英文别名: calcium;magnesium;phosphate
• CAS: 25618-23-9
• 化学式: 3Ca*3Mg*4O₄P
• 分子量: 573.034
• InChiKey: KMQAPZBMEMMKSS-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -3.59
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.2
• 氢给体数：
  0
• 氢受体数：
  4

制备方法与用途

用途是生产肌醇和植酸的主要原料。

反应信息

• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 calcium magnesium phosphate
  参考文献：
  名称：

  Characterization and Mechanical Performance of the Mg-Stabilized beta-Ca3(PO4)2 Prepared from Mg-Substituted Ca-Deficient Apatite

  摘要：

  制备镁稳定的β-磷酸三钙（β-TCP）采用了水相沉淀法，随后通过粉末X射线衍射、傅里叶变换红外光谱（FT-IR）、拉曼光谱和元素分析对其粉末进行表征。缺钙的羟基磷灰石向β-TCP的转变发生于700–800°C的温度范围内。计算所得的晶格参数值证实了镁所起的稳定作用。镁稳定的β-TCP粉末的热稳定性可维持至1400°C，从而拓宽了烧结温度范围，而无转化为不希望的α-TCP的可能。因此，与纯β-TCP相比，镁稳定的β-TCP的机械性能得到了改善。

  DOI：

  10.1111/j.1551-2916.2006.01158.x

文献信息

• A magic angle spinning NMR study of the phase diagram Ca3−xZnx(PO4)2
  作者：R.J.B. Jakeman、A.K. Cheetham、N.J. Clayden、C.M. Dobson

  DOI：10.1016/0022-4596(89)90124-2

  日期：1989.1

  The phase diagram Ca3−xZnx(PO4)2 has been investigated by31P magic angle spinning NMR (MASNMR). The study demonstrates how MASNMR can be used to make clear distinction between regions of solid solution, line phases, and biphasic mixtures. The31P MASNMR spectrum of the complex phosphate, β-Ca3(PO4)2, has been rationalized in terms of the known structure, and the broadness of the observed resonances

  通过31 P幻角旋转NMR（MASNMR）研究了相图Ca 3− x Zn x（PO 4）2。该研究证明了如何使用MASNMR来明确区分固溶体，线相和双相混合物的区域。的31的复合磷酸盐的p个MASNMR光谱，β-的Ca 3（PO 4）2，已被合理化在已知的结构方面，和观察到的共振的广度已被归因于由一种金属的部分占据所述病症地点。31的强度和线宽的变化P MASNMR谐振，如锌取代了β-钙钙3（PO 4）2的框架，以形成固体溶液，被解释通过类比与同晶固体溶液的Ca 3- X镁X（PO 4）2。中间相α-的CaZn 2（PO 4）2已被鉴定为具有在任一端构件没有溶解性和在10.0和2.2 ppm的特征是两个不同的各向同性共振。Ca 3（PO 4）2，CaZn 2（PO 4）的高温形式的光谱）2和Zn 3（PO 4）2。
• Synthesis, crystal structure and luminescence characteristics of a novel red phosphor Ca19Mg2(PO4)14:Eu3+ for light emitting diodes and field emission displays
  作者：Ge Zhu、Zhipeng Ci、Yurong Shi、Meidan Que、Qian Wang、Yuhua Wang

  DOI：10.1039/c3tc31263a

  日期：——

  In order to explore a new family of phosphate phosphors, the synthesis and crystal structure of a novel phosphate family, Ca19M2(PO4)14 (M = Mg, Zn, Mn), were investigated. Eu3+ doped Ca19Mg2(PO4)14 red phosphor was also successfully synthesized with the objective of application in ultraviolet-based light-emitting diodes (LEDs) and field emission displays (FEDs). The characteristic photoluminescence properties were studied in detail by photoluminescence excitation (PLE), emission (PL) spectra and decay times. The Ca19Mg2(PO4)14:0.06Eu3+ phosphor offers higher brightness and thermal stability than the commercial Y2O3:Eu3+. The unexpected temperature-dependent luminescence from higher 5D1 states was observed and was explained via the configuration coordinate diagram. The cathodoluminescence (CL) spectra as a function of accelerating voltage and probe current were also measured. Excellent degradation properties with good color stability were obtained by continuous low-voltage electron-beam excitation of the phosphor. The results indicate that the phosphor Ca19Mg2(PO4)14:0.06Eu3+ can be a suitable red-emitting phosphor candidate for LEDs and FEDs.

  为了探索新的磷酸盐荧光粉家族，我们研究了新型磷酸盐家族 Ca19M2(PO4)14（M = Mg、Zn、Mn）的合成和晶体结构。此外，还成功合成了掺杂 Eu3+ 的 Ca19Mg2(PO4)14 红色荧光粉，并将其应用于紫外发光二极管（LED）和场发射显示器（FED）。通过光致发光激发（PLE）、发射（PL）光谱和衰减时间详细研究了其光致发光特性。与商用 Y2O3:Eu3+ 相比，Ca19Mg2(PO4)14:0.06Eu3+ 荧光粉具有更高的亮度和热稳定性。从更高的 5D1 状态中观察到了意想不到的随温度变化的发光现象，并通过构型坐标图得到了解释。此外，还测量了阴极发光（CL）光谱与加速电压和探针电流的函数关系。通过对荧光粉进行持续的低压电子束激发，获得了具有良好颜色稳定性的优异降解特性。结果表明，Ca19Mg2(PO4)14:0.06Eu3+ 荧光粉可作为 LED 和 FED 的合适红色发光荧光粉。
• Lazoryak, B. I.; Khoina, S. V.; Golubev, V. N., Russian Journal of Inorganic Chemistry, 1990, vol. 35, p. 777 - 780
  作者：Lazoryak, B. I.、Khoina, S. V.、Golubev, V. N.、Aziev, R. G.

  DOI：——

  日期：——
• Lazoryak, B. I.; Khoina, S. V.; Golubev, V. N., Russian Journal of Inorganic Chemistry, <hi>1991</hi>, vol. 36, p. 397 - 400
  作者：Lazoryak, B. I.、Khoina, S. V.、Golubev, V. N.、Ivanov, L. N.

  DOI：——

  日期：——
• Characterization and Mechanical Performance of the Mg-Stabilized beta-Ca3(PO4)2 Prepared from Mg-Substituted Ca-Deficient Apatite
  作者：Sanjeevi Kannan、Alexandra F. Lemos、Jorge H. G. Rocha、Jose M. F. Ferreira

  DOI：10.1111/j.1551-2916.2006.01158.x

  日期：——

  The preparation of Mg‐stabilized β‐tricalcium phosphate (β‐TCP) was carried out by an aqueous precipitation method and the characterization of the powders was performed by powder X‐ray diffraction, FT‐IR spectra, Raman spectroscopy, and elemental analysis. The transformation of calcium‐deficient apatite into β‐TCP has occurred in the range of 700°–800°C. The calculated values for lattice parameters confirm the stabilization role played by Mg. The thermal stability of the Mg‐stabilized β‐TCP powders was evident until 1400°C, thus broadening the sintering temperature range without transformation into the undesirable α‐TCP. Accordingly, the mechanical properties of the Mg‐stabilized β‐TCP were improved in comparison with those of pure β‐TCP.

  制备镁稳定的β-磷酸三钙（β-TCP）采用了水相沉淀法，随后通过粉末X射线衍射、傅里叶变换红外光谱（FT-IR）、拉曼光谱和元素分析对其粉末进行表征。缺钙的羟基磷灰石向β-TCP的转变发生于700–800°C的温度范围内。计算所得的晶格参数值证实了镁所起的稳定作用。镁稳定的β-TCP粉末的热稳定性可维持至1400°C，从而拓宽了烧结温度范围，而无转化为不希望的α-TCP的可能。因此，与纯β-TCP相比，镁稳定的β-TCP的机械性能得到了改善。