1,4-Bis-butan

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: 1,4-Bis-butan
• 英文别名: Tert-butyl(4-tert-butylphosphanylbutyl)phosphane；tert-butyl(4-tert-butylphosphanylbutyl)phosphane
• 化学式: C₁₂H₂₈P₂
• 分子量: 234.302
• InChiKey: AEVFFBLAMQDDCH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,4-二溴丁烷 、 二-叔丁基膦 在 正丁基锂 作用下， 生成 1,4-Bis-butan
  参考文献：
  名称：

  Wurst, K.; Straehle, J., Zeitschrift fur Naturforschung, B: Chemical Sciences, 1993, vol. 48, # 4, p. 425 - 430

  摘要：

  DOI：

文献信息

• METAL COMPLEXES
  申请人：Kunz Doris

  公开号：US20130284977A1

  公开（公告）日：2013-10-31

  The present invention relates to bisimidazolium salts, to novel mono- and biscarbenes derived therefrom, and to metal complexes which contain corresponding mono- and biscarbenes as ligands, to a process for the preparation of the bisimidazolium salts according to the invention, the mono- and biscarbenes according to the invention and to the metal complexes according to the invention, and to the use of the bisimidazolium salts according to the invention, the mono- and biscarbenes according to the invention and to the use of the metal complexes according to the invention.

  本发明涉及双咪唑盐、由此衍生的新型单咪唑和双咪唑，以及包含相应单咪唑和双咪唑作为配体的金属配合物，以及根据本发明制备双咪唑盐、单咪唑和双咪唑以及金属配合物的方法，以及使用本发明的双咪唑盐、单咪唑和双咪唑以及金属配合物的用途。
• Metal complexes
  申请人：Kunz Doris

  公开号：US10290819B2

  公开（公告）日：2019-05-14

  The present invention relates to bisimidazolium salts, to novel mono- and biscarbenes derived therefrom, and to metal complexes which contain corresponding mono- and biscarbenes as ligands, to a process for the preparation of the bisimidazolium salts according to the invention, the mono- and biscarbenes according to the invention and to the metal complexes according to the invention, and to the use of the bisimidazolium salts according to the invention, the mono- and biscarbenes according to the invention and to the use of the metal complexes according to the invention.

  本发明涉及双咪唑鎓盐、由其衍生的新型一碳烯和二碳烯、含有相应一碳烯和二碳烯作为配体的金属配合物、根据本发明制备双咪唑鎓盐的工艺、根据本发明的双咪唑鎓盐，根据本发明的单碳烯和双碳烯，根据本发明的金属络合物，以及根据本发明的双咪唑鎓盐，根据本发明的单碳烯和双碳烯，以及根据本发明的金属络合物的用途。
• ORGANISCHE ELEKTROLUMINESZENZVORRICHTUNG
  申请人：Merck Patent GmbH

  公开号：EP2297275A1

  公开（公告）日：2011-03-23
• KOMPLEXE ZUR VERWENDUNG IN OPTO-ELEKTRONISCHEN BAUTEILEN
  申请人：Merck Patent GmbH

  公开号：EP2297276A1

  公开（公告）日：2011-03-23
• Complexes for Use In Optoelectronic Components
  申请人：Yersin Hartmut

  公开号：US20110108769A1

  公开（公告）日：2011-05-12

  The invention relates to the use of a multi-nuclear metal or transition metal complex in an organic electronic device, said complex having a small ΔE spacing, particularly between 50 cm −1 and 2000 cm −1 , between the lowest triplet state and the singlet state that is higher and is achieved by thermal backfilling from the triplet. The invention further relates to the use of the strong absorptions of such multinuclear metal complexes, particularly in OSCs.