tin(IV) phosphate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 英文名称: tin(IV) phosphate
• 英文别名: tin phosphate；Tin(4+);phosphate
• 化学式: 4O₄P*3Sn
• 分子量: 736.015
• InChiKey: AGUITFDKURIPEN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -3.21
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  Sn3(PO4)4F3*2C14H29N(CH3)3Br, hexagonal 在 air 作用下， 以 neat (no solvent, solid phase) 为溶剂， 生成 tin(IV) phosphate
  参考文献：
  名称：

  Hexagonal and Cubic Thermally Stable Mesoporous Tin(IV) Phosphates with Acidic and Catalytic Properties

  摘要：

  DOI：

  10.1002/1521-3773(20020503)41:9<1594::aid-anie1594>3.0.co;2-w
• 作为试剂：
  描述：

  甲醇 在 tin(IV) phosphate 、 steam 作用下， 生成 聚合甲醛 、 methane
  参考文献：
  名称：

  Abkin; Medwedew, vol. 11, # 1, p. 30

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: MVol.C2, 16.9.4, page 254 - 255
  作者：

  DOI：——

  日期：——
• �ber metall-dialkyl-phosphate
  作者：E. Hayek、E. Rhomberg

  DOI：10.1007/bf00913834

  日期：——
• Styrene–tin (IV) phosphate nanocomposite for photocatalytic degradation of organic dye in presence of visible light
  作者：Bhim Singh Rathore、Deepak Pathania

  DOI：10.1016/j.jallcom.2014.03.160

  日期：2014.9

  Styrene-tin (IV) phosphate nanocomposite (ST/TPNC) ion exchanger was used as efficient photocatalyst for the degradation of methylene blue dye from aqueous system in the presence of solar light. ST/TPNC exhibited a high efficiency in heterogeneous photocatalytic process for the removal of MB from the water system. The degradation efficiency after 2 h illumination was 80%. The degradation of MB follows the pseudo-first-order kinetics with rate constant 0.00702 min (1). The nanocomposite ion exchanger was explored for its ion exchange capacity, pH titration, elution behavior, elution concentration and distribution coefficient (K-d). ST/TPNC exhibited a higher ion exchange capacity (1.83 meg/g) compared to its inorganic counterpart (0.55 meg/g). ST/TPNC was characterized using some techniques such as Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). (C) 2014 Elsevier B.V. All rights reserved.
• Krylov, V. N.; Borisov, S. M.; Burov, A. G., Radiokhimiya, <hi>1989</hi>, vol. 31, p. 36 - 40
  作者：Krylov, V. N.、Borisov, S. M.、Burov, A. G.

  DOI：——

  日期：——
• Hexagonal and Cubic Thermally Stable Mesoporous Tin(<scp>IV</scp>) Phosphates with Acidic and Catalytic Properties
  作者：Christian Serre、Aline Auroux、Antonella Gervasini、Maryvonne Hervieu、Gérard Férey

  DOI：10.1002/1521-3773(20020503)41:9<1594::aid-anie1594>3.0.co;2-w

  日期：2002.5.3