Calcium;lithium;phosphate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱土金属氧阴离子化合物
• 英文名称: Calcium;lithium;phosphate
• 化学式: 10Ca*Li*7O₄P
• 分子量: 1072.52
• InChiKey: JKDBPVARNVYJPG-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -6.2
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  calcium chloride 、 Calcium;lithium;phosphate 以 水 为溶剂， 生成 lithium chloride
  参考文献：
  名称：

  GB633008

  摘要：

  公开号：
• 作为产物：
  描述：

  tricalcium diphosphate 、 lithium carbonate 以 solid 为溶剂， 生成 Calcium;lithium;phosphate
  参考文献：
  名称：

  Radioluminescence of double and triple monophosphates of calcium, alkali, and rare-earth elements with the whitlockite structure

  摘要：

  DOI：

  10.1007/bf00938128

文献信息

• Rose, H., Annalen der Physik, 1849, vol. 77, p. 288 - 301
  作者：Rose, H.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Li: SVol., 5, page 136 - 139
  作者：

  DOI：——

  日期：——
• Luminescence of emission-tunable Ca10Li(PO4)7:Eu2+, Sr2+, Mn2+ phosphors with various Eu2+ centers for LED applications
  作者：Jia Zhang、Zhenghe Hua、Shizheng Wen

  DOI：10.1016/j.jallcom.2015.02.117

  日期：2015.7

  Ca10Li(PO4)(7):Eu2+, Sr2+, Mn2+ (CLP:Eu2+, Sr2+, Mn2+) phosphors were prepared by solid-state reaction method, and their photoluminescence properties were investigated. The phase purity was examined by XRD patterns; the optical bandgaps of the host materials were determined to be about 5.35 eV from the diffuse reflection spectra. The Eu2+ single-doped CLP exhibits several overlapping emission bands which are derived from various Eu2+ centers, and the excitation spectra are broadened and enhanced gradually with increasing either monitoring wavelength or Eu2+ concentration. When the Sr2+ ions are doped into CLP: Eu2+, the excitation bands are further extended in width and increased in intensity, which make the CLP:Eu2+ more suitable for the LED chips. Correspondingly, the emission spectra show a continuous enhancement for long-wavelength emissions, accompanied by a gradual decay for short-wavelength emissions. These observations could be due to the adjustment of the crystal structure by introducing Sr2+ ions into CLP which further affects the spectral features. In the CLP:Eu2+, Sr2+, Mn2+ system, warm white emission was obtained with low correlated color temperature. In sum, multicolor-emitting CLP:Eu2+, Sr2+, Mn2+ phosphors were developed by adjusting the dopants contents, and the above results indicate their potential applications in LEDs. (C) 2015 Elsevier B.V. All rights reserved.
• �ber die Isotypie zwischen Phosphaten der allgemeinen Zusammensetzung MeLi[PO4] und den Silikaten der Olivin-Monticellit-Reihe
  作者：Erich Thilo

  DOI：10.1007/bf01481845

  日期：1941.4
• Luminescence in LiCaPO4
  作者：S.D. More、M.N. Meshram、S.P. Wankhede、P.L. Muthal、S.M. Dhopte、S.V. Moharil

  DOI：10.1016/j.physb.2010.12.077

  日期：2011.3

  Phase pure LiCaPO4 was prepared by following a specific procedure involving several annealing steps, not exceeding the temperature 800 degrees C at any stage. Luminescence of Cu+ and Eu2+ activators is studied. A single emission band is observed for both the activators in contrast to two bands reported in earlier literature. It is argued that in the earlier work the samples were contaminated by alpha Ca-3(PO4)(2) phase, which could be responsible for these differences. Thermoluminescence of LiCaPO4:Eu2+ was found to be four times more than the commercial phosphor LiF-TLD 100. Phase pure LiCaPO4 shows interesting luminescence properties different than those reported in the literature and hence it should prove fruitful to probe this material in future. (C) 2011 Elsevier B.V. All rights reserved.