magnesium perchlorate hexahydrate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱土金属氧阴离子化合物
• 英文名称: magnesium perchlorate hexahydrate
• 英文别名: nagnesium hexaaqua perchlorate；Magnesium;perchlorate;hexahydrate
• 化学式: 2ClO₄*H₁₂MgO₆
• 分子量: 331.298
• InChiKey: VTYUWWCAUCSDER-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -10.08
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  6
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  magnesium carbonate 在 HClO₄ 作用下， 以 水 为溶剂， 生成 magnesium perchlorate hexahydrate
  参考文献：
  名称：

  An adiabatic calorometry study of [Mg(H2O)6](ClO4)2

  摘要：

  DOI：

  10.1016/0378-4363(81)90178-9

文献信息

• ——
  作者：E. Mikuli、A. Migdał-Mikuli、J. Mayer

  DOI：10.1023/a:1010112801504

  日期：——

  The results of DSC measurements in the temperature range 140-370 K on nine crystalline compounds of the type [M(H2O)(6)](ClO4)(2), where M=Mg, Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg, are discussed. Anomalies detected in the DSC curves are related to the existence of solid-solid phase transitions and/or to the melting points of these compounds. In consequence of two different hypothetical structural modifications of [Fe(H2O)(6)](ClO4)(2), two DSC curves are obtained. For the compounds with M=Fe, Cd and Hg, new phase transitions have been discovered. The transition temperatures of the other phase transitions are in good agreement with literature data obtained by adiabatic calorimetry. For the compounds with M=Mg, Ni and Cd, DTA measurements were also carried out and the melting points of theses compounds were established.