copper(II) di(2-ethylhexyl)phosphate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: copper(II) di(2-ethylhexyl)phosphate
• 英文别名: copper(II) di-2-ethylhexyl phosphate；copper di-2-ethylhexyl phosphate；copper di-2-ethylhexylphosphate
• 化学式: C₃₂H₆₈CuO₈P₂
• 分子量: 706.381
• InChiKey: PEYZLLZXMOXZJA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.92
• 重原子数：
  22.0
• 可旋转键数：
  14.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  58.59
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  copper(II) di(2-ethylhexyl)phosphate 在 barium(II) chloride 作用下， 以 四氯化碳 、 水 、 苯 为溶剂， 以66.1%的产率得到
  参考文献：
  名称：

  Stoyanov, E. S.; Mikhailov, V. A.; Popov, V. M., Koordinatsionnaya Khimiya, 1990, vol. 16, p. 200 - 205

  摘要：

  DOI：
• 作为产物：
  描述：

  二(2-乙基己基)磷酸酯 、 copper(II) sulfate 以 四氯化碳 为溶剂， 生成 copper(II) di(2-ethylhexyl)phosphate
  参考文献：
  名称：

  10.1007/s11504-008-3035-1

  摘要：

  A unit was designed for investigating the effects of low electrostatic fields on exchange reactions in extraction systems. The dynamics of oxalic acid transfer across the interface during the reextraction of copper ions under the action of copper oxalate deposition was studied. The peculiarities of reextraction dynamics were explained by the formation and migration of discontinuities in the copper alkyl phosphate film along the interphase surface under the action of an electrostatic field. The dynamics of the process is characterized by the appearance of specific exchange rate maxima and by a drastic decrease in the rate in the presence of an electric field.

  DOI：

  10.1007/s11504-008-3035-1

文献信息

• Golovanov, V. I.; Ishimova, I. N., Russian Journal of Inorganic Chemistry, <hi>1987</hi>, vol. 32, p. 77 - 80
  作者：Golovanov, V. I.、Ishimova, I. N.

  DOI：——

  日期：——
• 10.1007/s11504-008-3035-1
  作者：Zhang, Dongxiang、Tarasov

  DOI：10.1007/s11504-008-3035-1

  日期：——

  A unit was designed for investigating the effects of low electrostatic fields on exchange reactions in extraction systems. The dynamics of oxalic acid transfer across the interface during the reextraction of copper ions under the action of copper oxalate deposition was studied. The peculiarities of reextraction dynamics were explained by the formation and migration of discontinuities in the copper alkyl phosphate film along the interphase surface under the action of an electrostatic field. The dynamics of the process is characterized by the appearance of specific exchange rate maxima and by a drastic decrease in the rate in the presence of an electric field.
• Stoyanov, E. S.; Mikhailov, V. A.; Popov, V. M., Koordinatsionnaya Khimiya, <hi>1990</hi>, vol. 16, p. 200 - 205
  作者：Stoyanov, E. S.、Mikhailov, V. A.、Popov, V. M.

  DOI：——

  日期：——