作者:Anders G. Nord、Theodor Stefanidis
DOI:10.1016/0025-5408(81)90288-9
日期:1981.9
Abstract A number of γ-(Zn, Me ) 3 (PO 4 ) 2 solid solutions with the “γ-Zn 3 (PO 4 ) 2 ” structure have been prepared and equilibrated at about 1070 K ( Me = Mg, Mn, Fe, Co, Ni, Cu, and Cd ). Approximate homogeneity ranges are given. The monoclinic unit cell dimensions have been accurately determined from Guinier-Hagg photographs. The structure contains five- and six-coordinated cations. Correlations
摘要 制备了许多具有“γ-Zn 3 (PO 4 ) 2 ”结构的γ-(Zn, Me ) 3 (PO 4 ) 2 固溶体,并在约1070 K ( Me = Mg, Mn, Fe 、Co、Ni、Cu 和 Cd)。给出了近似的同质性范围。单斜晶胞尺寸已从 Guinier-Hagg 照片中准确确定。该结构包含五个和六个配位的阳离子。指出了同质性范围、晶胞尺寸、阳离子半径和阳离子分布之间的相关性,并且还将这些相与同型 (Mg, Me 3 (PO 4 ) 2 和 (Co, Me ) 3 (PO 4 ) 2 固溶体进行了比较.