(9-乙酰氧基-3,8,10-三乙基-7,8,10-三甲基-1,5-二氧杂-9-氮杂螺[5.5]十一碳-3-基)甲基硬脂酸酯 | 376588-17-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂螺癸烷衍生物
• 中文名称: (9-乙酰氧基-3,8,10-三乙基-7,8,10-三甲基-1,5-二氧杂-9-氮杂螺[5.5]十一碳-3-基)甲基硬脂酸酯
• 中文别名: (1aR,11aS)-1a,10,11,11a-四氢四苯并[3,4-b]噁丙烯
• 英文名称: 9-Acetoxy-3,8,10-triethyl-7,8,10-trimethyl-1,5-dioxa-9-azaspiro[5.5]undec-3-ylmethyl Stearate
• 英文别名: Octadecanoic acid, [9-(acetyloxy)-3,8,10-triethyl-7,8,10-trimethyl-1,5-dioxa-9-azaspiro[5.5]undec-3-yl]methyl ester；(9-acetyloxy-3,8,10-triethyl-8,10,11-trimethyl-1,5-dioxa-9-azaspiro[5.5]undecan-3-yl)methyl octadecanoate
• CAS: 376588-17-9
• 化学式: C₃₈H₇₁NO₆
• 分子量: 637.985
• InChiKey: GGZAHARVCVECSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.3
• 重原子数：
  45
• 可旋转键数：
  24
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  74.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  十八烷酰氯 、 9-aza-3-hydroxymethyl-7,8,10-trimethyl-3,8,10-triethyl-1,5-dioxaspiro[5.5]undecane 在 甲基叔丁基醚 作用下， 以 吡啶 、 水 为溶剂， 反应 18.0h， 生成 (9-乙酰氧基-3,8,10-三乙基-7,8,10-三甲基-1,5-二氧杂-9-氮杂螺[5.5]十一碳-3-基)甲基硬脂酸酯
  参考文献：
  名称：

  Process for reducing the molecular weight of polypropylene

  摘要：

  本发明涉及选自HALS（立体位阻胺）化合物组和新型羟胺酯的已知羟胺酯的使用，用于控制聚丙烯的降解。

  公开号：

  US07030196B2

文献信息

• USE OF PHOSPHOROUS-CONTAINING ORGANIC OXYIMIDES AS FLAME RETARDANTS AND/OR AS STABILIZERS FOR PLASTICS, FLAME-RETARDANT AND/OR STABILIZED PLASTIC COMPOSITIONS, METHOD FOR THE PRODUCTION THEREOF, MOULDED PART, PAINT AND COATINGS
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

  公开号：US20170260366A1

  公开（公告）日：2017-09-14

  The present invention relates to the use of phosphorous-containing organic oxyimides according to the general formula (I) as flame retardant for plastic materials, as radical generators in plastic materials and/or stabilisers for plastics. In addition, the present invention relates to a flame-retardant plastic material moulding compound in which the previously described phosphorous-containing organic oxyimides are integrated, and also to a method for the production of the previously mentioned plastic material composition. Furthermore, the present invention relates to a moulded article, a paint or a coating from the previously mentioned flame-retardant plastic material composition.

  本发明涉及根据一般式(I)的含磷有机氧亚胺化合物作为塑料材料的阻燃剂，作为塑料材料中的自由基发生剂和/或塑料的稳定剂。此外，本发明涉及一种阻燃塑料材料成型复合物，其中集成了前述的含磷有机氧亚胺化合物，并且涉及一种用于制备前述塑料材料组合物的方法。此外，本发明涉及一种从前述阻燃塑料材料组合物制成的成型制品、涂料或涂层。
• Hydroxylamine esters as polymerization initiators
  申请人：——

  公开号：US20030216494A1

  公开（公告）日：2003-11-20

  The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.

  该发明涉及新型环状和开链羟胺酯以及包括这些羟胺酯和乙烯基不饱和单体或寡聚物的可聚合组合物。该发明还涉及用作聚合引发剂以及用于控制聚丙烯降解和实现聚乙烯分子量控制增加的已知羟胺酯，所述羟胺酯来自HALS化合物和新颖羟胺酯的组合。
• PHOTORESIST COMPOSITIONS
  申请人：Kura Hisatoshi

  公开号：US20120038996A1

  公开（公告）日：2012-02-16

  The present invention relates to a radically polymerizable composition comprising a hydroxylamine ester used to manufacture color filters. The invention further relates to novel hydroxylamine esters. The invention further relates to the use of hydroxylamine esters in all liquid crystal display components requiring post-baking. The present invention relates to a radically polymerizable composition comprising: (a) at least one alkaline developable resin; (b) at least one acrylate monomer; (c) at least a photoinitiator; (d) at least one hydroxylamine ester compound of formula (I) wherein R a represents an acyl radical; one of R b and R c represents hydrogen and the other one represents a substituent; or R b and R c both represent hydrogen or identical or different substituents; or R b and R c together represent oxygen; or R b and R c together form a ring; R 1 -R 4 each represent C 1 -C 6 alkyl; and R 5 and R 6 each represent independently of one another hydrogen, C 1 -C 6 alkyl or C 6 -C 10 aryl; or R 5 and R 6 together represent oxygen.

  本发明涉及一种含有羟胺酯的根本聚合组合物，用于制造彩色滤光片。本发明还涉及新颖的羟胺酯。本发明还涉及在需要后烘烤的所有液晶显示组件中使用羟胺酯。本发明涉及一种根本聚合组合物，包括：（a）至少一种碱性可开发树脂；（b）至少一种丙烯酸酯单体；（c）至少一种光引发剂；（d）至少一种羟胺酯化合物，其化学式为（I），其中R_a表示酰基基团；R_b和R_c中的一个表示氢，另一个表示取代基；或R_b和R_c都表示氢或相同或不同的取代基；或R_b和R_c一起表示氧；或R_b和R_c一起形成一个环；R_1-R_4各自表示C1-C6烷基；R_5和R_6各自独立地表示氢、C1-C6烷基或C6-C10芳基；或R_5和R_6一起表示氧。
• PHENYLPHOSPHONATE FLAME RETARDANT COMPOSITIONS
  申请人：Xalter Rainer

  公开号：US20120108712A1

  公开（公告）日：2012-05-03

  The present invention relates to flame retardant polymer compositions which comprise mixtures of melamine or guanidine phenylphosphonates and mixtures with 2,2,6,6-tetraalkyl-piperidines. The mixtures are especially useful for the manufacture of flame retardant compositions based on thermoplastic polymers.

  本发明涉及阻燃聚合物组合物，其包含三聚氰胺或鸟氨酸苯基膦酸盐和2,2,6,6-四烷基哌啶的混合物。这些混合物特别适用于基于热塑性聚合物的阻燃组合物的制造。
• Process for reducing the molecular weight of polypropylene
  申请人：Ciba Specialty Chemicals Corporation

  公开号：US07030196B2

  公开（公告）日：2006-04-18

  The invention relates to the use of known hydroxylamine esters selected from the group consisting of HALS (sterically hindered amine) compounds and novel hydroxylamine esters for the controlled degradation of polypropylene.

  本发明涉及选自HALS（立体位阻胺）化合物组和新型羟胺酯的已知羟胺酯的使用，用于控制聚丙烯的降解。