氟磷酸二环己基酯 | 587-15-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 氟磷酸二环己基酯
• 英文名称: dicyclohexyl phosphorofluoridate
• 英文别名: fluorophosphoric acid dicyclohexyl ester；Fluorophosphorsaeure-dicyclohexylester；Phosphorsaeure-dicyclohexylester-fluorid；Dicyclohexyl-fluorphosphat；Phosphorofluoridic acid, dicyclohexyl ester；[cyclohexyloxy(fluoro)phosphoryl]oxycyclohexane
• CAS: 587-15-5
• 化学式: C₁₂H₂₂FO₃P
• 分子量: 264.277
• InChiKey: NLPYJEIDHPZCCR-UHFFFAOYSA-N

物化性质

• 沸点：
  215°C

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  dicyclohexyl chlorophosphate 在 氟化铵 、 丙酮 作用下， 生成 氟磷酸二环己基酯
  参考文献：
  名称：

  Tichy; Truchlik, Chemicke Zvesti, 1958, vol. 12, p. 345,348

  摘要：

  DOI：

文献信息

• IMIDIC ACID COMPOUND HAVING DIVALENT ANION AND PROCESS FOR PRODUCING THE SAME
  申请人：Central Glass Co., Ltd.

  公开号：EP3222624A1

  公开（公告）日：2017-09-27

  Provided is a novel imidic acid compound having a divalent anion useful as a pharmaceutical intermediate, an agrochemical intermediate, an acid catalyst, a battery electrolyte or an antistatic agent. The imidic acid compound is a divalent imidic acid compound represented by the following general formula (1) or (2). [In formulae (1) and (2), R1 to R3 represent a fluorine atom or an organic groups selected from a linear or branched C1-10 alkoxy group, a C2-10 alkenyloxy group, a C2-10 alkynyloxy group, a C3-10 cycloalkoxy group, a C3-10 cycloalkenyloxy group and a C6-10 aryloxy group, and wherein a fluorine atom, an oxygen atom or an unsaturated bond may also be present in the organic group. M1 and M2 represent protons, metal cations or onium cations.]

  本文提供了一种具有二价阴离子的新型亚胺酸化合物，可用作医药中间体、农用化学品中间体、酸催化剂、电池电解液或抗静电剂。该亚胺酸化合物是由以下通式（1）或（2）表示的二价亚胺酸化合物。 [在式(1)和(2)中，R1 至 R3 代表一个氟原子或一个有机基团，该有机基团选自直链或支链 C1-10 烷氧基、C2-10 烯氧基、C2-10 烷炔氧基、C3-10 环烷氧基、C3-10 环烯氧基和 C6-10 芳氧基，其中有机基团中还可能存在一个氟原子、一个氧原子或一个不饱和键。M1和M2代表质子、金属阳离子或鎓阳离子]。
• Imidic acid compound having divalent anion and process for producing the same
  申请人：CENTRAL GLASS CO., LTD.

  公开号：US10287165B2

  公开（公告）日：2019-05-14

  Provided is a novel imidic acid compound having a divalent anion useful as a pharmaceutical intermediate, an agrochemical intermediate, an acid catalyst, a battery electrolyte or an antistatic agent. The imidic acid compound is a divalent imidic acid compound represented by the following general formula (1) or (2). [In formulae (1) and (2), R1 to R3 represent a fluorine atom or an organic groups selected from a linear or branched C1-10 alkoxy group, a C2-10 alkenyloxy group, a C2-10 alkynyloxy group, a C3-10 cycloalkoxy group, a C3-10 cycloalkenyloxy group and a C6-10 aryloxy group, and wherein a fluorine atom, an oxygen atom or an unsaturated bond may also be present in the organic group. M1 and M2 represent protons, metal cations or onium cations.]

  本文提供了一种具有二价阴离子的新型亚胺酸化合物，可用作医药中间体、农用化学品中间体、酸催化剂、电池电解液或抗静电剂。该亚胺酸化合物是由以下通式（1）或（2）表示的二价亚胺酸化合物。 [在式 (1) 和 (2) 中，R1 至 R3 代表氟原子或有机基团，这些有机基团选自直链或支链 C1-10 烷氧基、C2-10 烯氧基、C2-10 烷炔氧基、C3-10 环烷氧基、C3-10 环烯氧基和 C6-10 芳氧基，其中有机基团中还可能存在氟原子、氧原子或不饱和键。M1和M2代表质子、金属阳离子或鎓阳离子]。
• Trichloroisocyanuric Acid–KF as an Efficient Reagent for One-Pot Synthesis of Dialkylfluorophosphates from Dialkylphosphites
  作者：J. Acharya、A. K. Gupta、Deepak Pardasani、D. K. Dubey、M. P. Kaushik

  DOI：10.1080/00397910802215880

  日期：2008.10.22

  Trichloroisocyanuric acid-KF afforded dialkylfluorophosphates from dialkylphosphites at room temperature through a facile electrophilic-nucleophilic metathesis.
• 198. Esters containing phosphorus. Part VI. Preparation of esters of fluorophosphonic acid by means of phosphorus oxydichlorofluoride
  作者：N. B. Chapman、B. C. Saunders

  DOI：10.1039/jr9480001010

  日期：——
• Single step fluorination of dialkylphosphites: trichloroacetonitrile–KF as an efficient reagent for the synthesis of dialkyl fluorophosphates
  作者：A.K. Gupta、J. Acharya、D. Pardasani、D.K. Dubey

  DOI：10.1016/j.tetlet.2008.02.051

  日期：2008.3

  The use of trichloroacetonitrite and KF mixture is described as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkyl fluorophosphates via in situ formation of dialkyl chlorophosphates in one-pot. (C) 2008 Elsevier Ltd. All rights reserved.