氢氧化铋 | 10361-43-0

• 物质功能分类: 无机化工 - 无机碱
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 中文名称: 氢氧化铋
• 英文名称: bismuth hydroxide
• 英文别名: Bismuth hydrate；bismuth;trihydroxide
• CAS: 10361-43-0
• 化学式: BiH₃O₃
• 分子量: 260.002
• InChiKey: TZSXPYWRDWEXHG-UHFFFAOYSA-K

物化性质

• 密度：
  d15 4.962
• 溶解度：
  不溶于水；溶于酸溶液

计算性质

• 辛醇/水分配系数(LogP)：
  -0.91
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3
• 氢给体数：
  3
• 氢受体数：
  3

安全信息

• TSCA：
  Yes
• 海关编码：
  28259085

SDS

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Section 1. Chemical Product and Company Identification
Bismuth hydroxide Catalog
Common Name/
Number(s).
Trade Name
CAS# 10361-43-0
Manufacturer
RTECS Not available.
SPECTRUM QUALITY PRODUCTS INC.
TSCA TSCA 8(b) inventory: Bismuth
hydroxide
Commercial Name(s) Not available.
CI# Not available.
Synonym Not available.
IN CASE OF EMERGENCY
Not available.
Chemical Name
Chemical Family Not available. CALL [phone]
Bi(OH)3
Chemical Formula
SPECTRUM QUALITY PRODUCTS INC.

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Section 2.Composition and Information on Ingredients
Exposure Limits
TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3)
Name CAS # % by Weight
1) Bismuth hydroxide 10361-43-0 100
Toxicological Data Not applicable.
on Ingredients

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Section 3. Hazards Identification
Potential Acute Health Effects Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of
inhalation.
Potential Chronic Health Hazardous in case of ingestion.
Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.
Effects
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Bismuth hydroxide

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Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention if irritation
occurs.
Skin Contact Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact Not available.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation Not available.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious Ingestion Not available.

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Section 5. Fire and Explosion Data
Flammability of the Product Non-flammable.
Auto-Ignition Temperature Not applicable.
Flash Points Not applicable.
Flammable Limits Not applicable.
Not available.
Products of Combustion
Fire Hazards in Presence of Not applicable.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
of Various Substances Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media Not applicable.
and Instructions
Special Remarks on Not available.
Fire Hazards
Special Remarks on Explosion Not available.
Hazards

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Section 6. Accidental Release Measures
Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system.
Bismuth hydroxide

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Section 7. Handling and Storage
Precautions No specific safety phrase has been found applicable for this product.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.

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Section 8. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spill to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits Not available.

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Section 9. Physical and Chemical Properties
Physical state and appearance Solid. Odor Not available.
Taste Not available.
Molecular Weight 260.02 g/mole
Not available.
Color
Not available.
pH (1% soln/water)
Boiling Point Not available.
Decomposes.
Melting Point
Critical Temperature Not available.
Specific Gravity 4.36 (Water = 1)
Vapor Pressure Not applicable.
Vapor Density Not available.
Volatility Not available.
Odor Threshold Not available.
Not available.
Water/Oil Dist. Coeff.
Ionicity (in Water) Not available.
Dispersion Properties Not available.
Solubility Very slightly soluble in cold water.

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Section 10. Stability and Reactivity Data
Stability The product is stable.
Not available.
Instability Temperature
Conditions of Instability Not available.
Incompatibility with various Not available.
substances
Corrosivity Non-corrosive in presence of glass.
Bismuth hydroxide
Not available.
Special Remarks on
Reactivity
Not available.
Special Remarks on
Corrosivity
Polymerization Will not occur.

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Section 11. Toxicological Information
Routes of Entry Ingestion.
Toxicity to Animals LD50: Not available.
LC50: Not available.
Chronic Effects on Humans Not available.
Other Toxic Effects on
Hazardous in case of ingestion.
Humans Slightly hazardous in case of skin contact (irritant), of inhalation.
Special Remarks on
Not available.
Toxicity to Animals
Special Remarks on Due to the presence of dark line on gums, chronic bismuth toxicity may complicate diagnosis of chronic lead
Chronic Effects on Humans toxicity.
Special Remarks on other Not available.
Toxic Effects on Humans

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Section 12. Ecological Information
Ecotoxicity Not available.
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
Toxicity of the Products The products of degradation are more toxic.
of Biodegradation
Special Remarks on the Not available.
Products of Biodegradation

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Section 13. Disposal Considerations
Waste Disposal

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Section 14. Transport Information
DOT Classification Not a DOT controlled material (United States).
Identification Not applicable.
Not applicable.
Special Provisions for
Transport
DOT (Pictograms)
Bismuth hydroxide

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Section 15. Other Regulatory Information and Pictograms
TSCA 8(b) inventory: Bismuth hydroxide
Federal and State
Regulations
California
Proposition 65
Warnings
Other Regulations Not available.
WHMIS (Canada) Not controlled under WHMIS (Canada).
Other Classifications
DSCL (EEC) This product is not classified according
to the EU regulations.
Health Hazard
HMIS (U.S.A.) 1 National Fire Protection
0 Flammability
0 Association (U.S.A.)
Fire Hazard
1 0 Reactivity
Health
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.
Safety glasses.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

用途

氢氧化铋用作吸附剂，制人造牙齿的原料，也可用于制备铋盐。它是一种新型无机铋催化剂，在阴极电泳漆体系中应用广泛，可以替代有毒的有机锡催化剂，从而制备环保型涂料。该物质溶于浓酸和甘油，不溶于水、乙醇及浓碱；遇热水或加热至415℃会分解，并在100℃时失去1分子水。

制法

氢氧化铋可由铋盐与氢氧化钠反应制得，也可通过将硝酸铋与碳酸铵按5:1的比例溶解于水中来制备。

水中溶解度 (g/100ml)

在20℃时，每100毫升水中的溶解克数为2.868×10^-7。

用途

氢氧化铋作为通用试剂用于制造铋盐，并且在芸香苷及栎精的吸收以及核糖核酸的水解中有应用。此外，它还能从受辐照的铀中分离出钚。

反应信息

• 作为反应物：
  描述：

  氢氧化铋 生成 Bismuth oxide
  参考文献：
  名称：

  SUGIYAMA, KADZUO

  摘要：

  DOI：
• 作为产物：
  描述：

  Wismutnitrat 生成 氢氧化铋
  参考文献：
  名称：

  MERCUIRO, J. P.;LAMBACHRI, A.;FRIT, B., SCI. CERAM. 14: PROC. 14TH INT. CONF., CANTERBURY, SEPT. 7-9TH, 1987, STO+

  摘要：

  DOI：
• 作为试剂：
  描述：

  2-甲基-9H-1,2,3,4-四氢吡啶并(3,4-b)吲哚 在 氢氧化铋 、 水 、 C₂₅H₃₀N₂O₂ 、 copper(ll) bromide 作用下， 以 乙腈 为溶剂， 以32 %的产率得到donaxanine
  参考文献：
  名称：

  以 H2O 和 O2 作为氧源的铜催化四氢-β-咔啉的氧化骨架重排

  摘要：

  在铜催化单电子转移氧化的温和条件下，开发了前所未有的四氢-β-咔啉（TH β Cs）含氧骨架重排反应，其中H 2 O和O 2作为氧源生成独特的2 -羟基-3-过氧化物二氢吲哚中间体。该过程涉及多步骤序列，以便能够以有效的方式将 TH β Cs 转化为多纳沙宁型杂环。

  DOI：

  10.1002/anie.202313687

文献信息

• Investigation of the formation process of zeolite-like 3D frameworks constructed with ε-Keggin-type polyoxovanadomolybdates with binding bismuth ions and preparation of a nano-crystal
  作者：Zhenxin Zhang、Masahiro Sadakane、Toru Murayama、Wataru Ueda

  DOI：10.1039/c4dt01227e

  日期：——

  Reaction conditions for the synthesis of an ε-Keggin-type polyoxometalate-based 3D framework, (NH4)2.8H0.9[ε-VMo9.4V2.6O40Bi2]·7.2H2O (denoted as Mo–V–Bi oxide), are studied. It is found that the reaction time, temperature, pH of the solution, and starting compounds affect the production of Mo–V–Bi oxide. The crystal size of Mo–V–Bi oxide is controllable by changing bismuth compounds. Nanometer-sized Mo–V–Bi oxide is produced using a water-soluble bismuth compound, Bi(NO3)3·5H2O, whereas micrometer to submicrometer-sized Mo–V–Bi oxide is produced using Bi(OH)3, which is less soluble in water. The particle size of the material affects the properties of the material, such as surface area and catalysis. The investigation of the formation process of the material is carried out with Raman spectroscopy, which indicates that mixing (NH4)6Mo7O24·4H2O, VOSO4·5H2O, and bismuth ions in water produces the ε-Keggin polyoxovanadomolybdate together with a ball-shaped polyoxovanadomolybdate, [Mo72V30O282(H2O)56(SO4)12]36− (denoted as Mo72V30}). By heating the reaction mixture, the ε-Keggin polyoxovanadomolybdate assembles with bismuth ions to form Mo–V–Bi oxide, whereas Mo72V30} assembles with other vanadium and molybdenum ions to form orthorhombic Mo–V oxide.

  研究了合成一种基于ε-Keggin型多氧金属酸盐的3D框架（NH4）2.8H0.9[ε-VMo9.4V2.6O40Bi2]·7.2 （记为Mo-V-Bi氧化物）的反应条件。研究发现，反应时间、温度、溶液的pH值和起始化合物会影响Mo-V-Bi氧化物的生成。通过改变铋化合物，可以控制Mo-V-Bi氧化物的晶体尺寸。使用水溶性铋化合物Bi（NO3）3·5 可以生成纳米大小的Mo-V-Bi氧化物，而使用Bi（OH）3可以生成微米到亚微米大小的Mo-V-Bi氧化物，Bi（OH）3在水中的溶解度较低。材料的粒径会影响材料的性质，如表面积和催化性。使用拉曼光谱仪对材料的形成过程进行了研究，结果表明，将（NH4）6Mo7O24·4 、VOSO4·5 和铋离子混合在水中，可以生成ε-Keggin型多氧钒钼酸盐和球形多氧钒钼酸盐[Mo72V30O282（H2O）56（SO4）12]36∙（记
• LOGINOV, A. A.;MEDKOV, M. A.;DAVIDOVICH, R. L.
  作者：LOGINOV, A. A.、MEDKOV, M. A.、DAVIDOVICH, R. L.

  DOI：——

  日期：——
• LOGINOV, A. A.;DAVIDOVICH, R. L.;MEDKOV, M. A.
  作者：LOGINOV, A. A.、DAVIDOVICH, R. L.、MEDKOV, M. A.

  DOI：——

  日期：——

表征谱图