phosphoric acid tris-(1-ethyl-propyl) ester | 17513-84-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: phosphoric acid tris-(1-ethyl-propyl) ester
• 英文别名: Tris--phosphat；Tri--phosphat；Tris-(1-aethyl-propyl)-phosphat；Tripentan-3-yl phosphate
• CAS: 17513-84-7
• 化学式: C₁₅H₃₃O₄P
• 分子量: 308.398
• InChiKey: ALCLDNINWGASPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-戊醇 在 吡啶 、 三氯氧磷 作用下， 生成 phosphoric acid tris-(1-ethyl-propyl) ester
  参考文献：
  名称：

  Conformation of Organophosphorus Compounds. II. Proton Magnetic Resonance Studies of Some Phosphites, Phosphonites, Phosphates, Phosphonates and Additional Phosphinates

  摘要：

  DOI：

  10.1021/ja00877a010

文献信息

• Quaternary ammonium salt, electrolyte, electrolyte solution and electrochemical device
  申请人：Nishida Tetsuo

  公开号：US20100038578A1

  公开（公告）日：2010-02-18

  A quaternary ammonium salt of the formula (1), electrolytic solution and electrochemical device using the salt wherein R 1 is straight-chain or branched alkyl having 1 to 4 carbon atoms, R 2 is straight-chain or branched alkyl having 1 to 3 carbon atoms, and X − is N(CN) 2 − , SCN − , NO 3 − , NCO − or NO 2 − .

  一种具有以下化学式（1）的四元铵盐，以及使用该盐的电解液和电化学器件，其中R1为具有1至4个碳原子的直链或支链烷基，R2为具有1至3个碳原子的直链或支链烷基，X-为N(CN)2−、SCN−、NO3−、NCO−或NO2−。
• PHOSPHORIC ACID DIESTER SALT, PRODUCTION METHOD THEREFOR, NON-AQUEOUS ELECTROLYTIC SOLUTION FOR POWER STORAGE ELEMENT, AND POWER STORAGE ELEMENT
  申请人：STELLA CHEMIFA CORPORATION

  公开号：US20180237461A1

  公开（公告）日：2018-08-23

  Disclosed is a phosphoric acid diester salt which can suppress deterioration of charge-discharge characteristics of a power storage element, and can suppress the rise in internal resistance after storage at high temperature, a production method therefor, a non-aqueous electrolytic solution for a power storage element, and a power storage element. Disclosed is a phosphoric acid diester salt represented by the following chemical formula (1): wherein M n+ represents a hydrogen ion, an alkali metal ion, an alkali earth metal ion, an aluminum ion, a transition metal ion, or an onium ion; R 1 and R 2 are different from each other and represent a hydrocarbon group having 1 to 10 carbon atoms, or a hydrocarbon group having 1 to 10 carbon atoms and having at least one of a halogen atom, a heteroatom, and an unsaturated bond; and n represents a valence.

  本发明公开了一种磷酸二酯盐，可以抑制电力储存元件的充放电特性恶化，可以抑制高温储存后内阻上升，以及其生产方法、用于电力储存元件的非水电解质溶液和电力储存元件。本发明公开了一种由下式（1）表示的磷酸二酯盐：其中Mn+表示氢离子、碱金属离子、碱土金属离子、铝离子、过渡金属离子或离子离子；R1和R2不同，表示具有1至10个碳原子的烃基，或具有1至10个碳原子且具有卤素原子、杂原子和不饱和键中的至少一个的烃基；n表示价数。
• Nonaqueous electrolyte and nonaqueous-electrolyte secondary battery
  申请人：Maruo Tatsuya

  公开号：US20060035137A1

  公开（公告）日：2006-02-16

  A nonaqueous electrolyte which contains an ionic liquid having general formula (1) below and a melting point not higher than 50° C., a compound which reductively decomposes at a more noble potential than the ionic liquid, and a lithium salt. In formula (1), R 1 to R 4 are each independently an alkyl group of 1 to 5 carbons or an alkoxyalkyl group of the formula R′—O—(CH 2 ) n — (R′ being methyl or ethyl, and the letter n being an integer from 1 to 4), and any two from among R 1 , R 2 , R 3 and R 4 may together form a ring, with the proviso that at least one of R 1 to R 4 is an alkoxyalkyl group of the above formula. X is a nitrogen atom or a phosphorus atom, and Y is a monovalent anion.

  一种非水电解质，包含具有通式（1）且熔点不高于50°C的离子液体，一个在比离子液体更高的电位下还原分解的化合物和一个锂盐。在公式（1）中，R1到R4各自独立地是1到5个碳的烷基或公式R′—O—（CH2）n—的烷氧基烷基（其中R′为甲基或乙基，字母n为1到4的整数），其中任意两个来自R1、R2、R3和R4的基团可以形成一个环，但至少有一个基团来自上述公式的烷氧基烷基。X是氮原子或磷原子，Y是一价阴离子。
• Nonaqueous electrolyte, electrical double-layer capacitors, and nonaqueous electrolyte secondary cells
  申请人：Maruo Tatsuya

  公开号：US20060034035A1

  公开（公告）日：2006-02-16

  Secondary cells and electrical double-layer capacitors of excellent charge-discharge efficiency, stability and low-temperature properties can be obtained using nonaqueous electrolytes which contain an ionic liquid that has general formula (1) below and is liquid at not higher than 50° C. and an ion-conductive polymer. In formula (1), R 1 to R 4 are each independently an alkyl group of 1 to 5 carbons or an alkoxyalkyl group of the formula R′—O—(CH 2 ) n —(R′ being methyl or ethyl, and the letter n being an integer from 1 to 4), and any two from among R 1 , R 2 , R 3 and R 4 may together form a ring, with the proviso that at least one of R 1 to R 4 is an alkoxyalkyl group of the above formula. X is a nitrogen atom or a phosphorus atom, and Y is a monovalent anion.

  非水电解质中含有一种具有通式（1）的离子液体和离子导电聚合物，可以获得具有优异的充放电效率、稳定性和低温性能的二次电池和电容器。该离子液体在不高于50°C的温度下为液体。 在式（1）中，R1至R4分别独立地表示1到5个碳原子的烷基或具有以下通式的烷氧烷基（其中R′为甲基或乙基，字母n为1到4的整数），而R1、R2、R3和R4中的任意两个可以共同形成一个环，但至少R1至R4中的一个是上述通式的烷氧烷基。X是氮原子或磷原子，Y是一价阴离子。
• Quaternary Ammonium Salt, Electrolyte, Electrolyte, Solution and Electrochemical Device
  申请人：Nishida Tetsuo

  公开号：US20080050657A1

  公开（公告）日：2008-02-28

  A quaternary ammonium salt of the formula (1) wherein R 1 is straight-chain or branched alkyl having 1 to 4 carbon atoms, R 2 is straight-chain or branched alkyl having 1 to 3 carbon atoms, and X − is CF 3 CO 2 − , CF 3 SO 3 BF 3 − , ClBF 3 − , AlF 4 − , CF 3 BF 3 − , C 2 F 5 BF 3 − , N(SO 2 F) 2 − , PF 6 − , AsF 6 − or SbF 6 − .

  化合物的中文翻译如下： 一种公式为（1）的季铵盐，其中R1为1至4个碳原子的直链或支链烷基，R2为1至3个碳原子的直链或支链烷基，X-为CF3CO2-，CF3SO3BF3-，ClBF3-，AlF4-，CF3BF3-，C2F5BF3-，N（SO2F）2-，PF6-，AsF6-或SbF6-。