tris(undec-10-en-1-yl) phosphate | 77510-79-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: tris(undec-10-en-1-yl) phosphate
• 英文别名: tri(10-undecenyloxy) phosphate；Tri-10-undecenyl phosphate；tris(undec-10-enyl) phosphate
• CAS: 77510-79-3
• 化学式: C₃₃H₆₃O₄P
• 分子量: 554.835
• InChiKey: WBNCQHVGIWAHMN-UHFFFAOYSA-N

物化性质

• 沸点：
  587.1±19.0 °C(Predicted)
• 密度：
  0.921±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  13.1
• 重原子数：
  38
• 可旋转键数：
  33
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  10-十一烯-1-醇 在 三乙胺 、 三氯氧磷 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以60%的产率得到tris(undec-10-en-1-yl) phosphate
  参考文献：
  名称：

  超支化不饱和聚磷酸盐作为空气中长期光子上转换的保护基质

  摘要：

  储存在有机分子三重态中的能量，能够通过发射过程（磷光）或非发射过程（三重态-三重态转移）进行能量转移，在分子氧的存在下会主动消散。原因是光激发的单线态氧反应性很强，所以体系中的光敏分子很快被氧化。氧化导致进一步的效率损失和各种不希望的副作用。在这项工作中，我们开发了一个结构多样的超支化不饱和聚（磷酸酯）库，可以有效清除单线态氧，但不与基态（即三线态）的分子氧反应。三重态-三重态湮灭光子上转换被选为一种高度氧敏感的过程，作为长期保护免受单线态氧猝灭的证据，在环境条件下光子上转换的效率与几种不饱和多磷酸盐的无氧环境中的光子上转换效率相当. 实验结果进一步与核磁共振光谱和理论计算相关，证明磷酸盐中心的重要性。这些结果为高效太阳能电池打开了技术窗口，也为可持续太阳能上转换设备打开了技术窗口，收集了宽带太阳光激发光谱。实验结果进一步与核磁共振波谱和理论计算相关，证明磷酸盐中心的重要性。这些结果为高效

  DOI：

  10.1021/ja5049412

文献信息

• Long-term stable photoactive composition, such as phosphorescent composition or TTA-photon upconversion composition
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP2851407A1

  公开（公告）日：2015-03-25

  A long-term stable photoactive composition, such as a phosphorescent composition or a TTA-photon upconversion composition, contains at least one compound, which has a triplet state capable of energy transfer via an emissive process or a non-emissive process, and at least one compound capable of reacting with singlet oxygen, wherein the at least one compound capable of reacting with singlet oxygen comprises at least one terminal unsaturated carbon-carbon bond, and wherein the at least one compound capable of reacting with singlet oxygen is contained in the composition in such an amount that the number of terminal unsaturated carbon-carbon bonds is at least 100 times higher in the composition than the number of molecules of all compounds having a triplet state capable of energy transfer via an emissive process or a non-emissive process.

  一种长期稳定的光活性组合物，如磷光组合物或 TTA 光子上转换组合物，包含至少一种化合物，该化合物具有能够通过发射过程或非发射过程进行能量转移的三重态，以及至少一种能够与单线态氧反应的化合物，其中至少一种能够与单线态氧反应的化合物包含至少一个末端不饱和碳-碳键、其中至少一种能与单线态氧反应的化合物在组合物中的含量，使组合物中末端不饱和碳-碳键的数量比所有具有能通过发射过程或非发射过程进行能量转移的三重态的化合物分子数量至少高 100 倍。
• CAPSULE SUITABLE FOR NON-INVASIVE SIMULTANEOUS OXYGEN CONTENT AND TEMPERATURE SENSING IN A LIVING OBJECT
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP3072942A1

  公开（公告）日：2016-09-28

  A capsule suitable for oxygen and temperature sensing contains: i) at least one first sensitizer compound being capable of energy transfer to triplet oxygen, ii) at least one compound being capable of reacting with and inactivating singlet oxygen, iii) at least one second sensitizer compound being capable of absorbing radiation at a second frequency v2 and of emitting light at a fourth frequency v4, iv) at least one emitter compound, wherein the at least one second sensitizer compound is capable of transferring energy to the at least one emitter compound and wherein the at least one emitter compound, after obtaining energy transferred from the at least one second sensitizer compound, is capable of emitting light at a third frequency v3, wherein the following equation is fulfilled: v3>v2, wherein the upper energy limit of the first triplet energy band of the first sensitizer compound is lower than the lower energy limit of the second triplet energy band of the second sensitizer compound and lower than the lower energy limit of the third triplet energy band of the emitter compound, and wherein the third triplet band of the emitter compound at least partially overlaps with the second triplet energy band of the second sensitizer compound.

  适用于氧气和温度传感的胶囊包含 i) 至少一种能与三重态氧发生能量转移的第一敏化剂化合物、 至少一种能与单线态氧反应并使其失活的化合物、 iii) 至少一种第二敏化剂化合物能够以第二频率 v2 吸收辐射，并以第四频率 v4 发射光、 iv) 至少一种发射器化合物，其中至少一种第二敏化剂化合物能够将能量传递给至少一种发射器化合物，其中至少一种发射器化合物在获得至少一种第二敏化剂化合物传递的能量后，能够以第三频率 v3 发射光，其中满足以下等式：v3>v2、 其中，第一敏化剂化合物的第一三重能带的能量上限低于第二敏化剂化合物的第二三重能带的能量下限，且低于发射器化合物的第三三重能带的能量下限，发射器化合物的第三三重能带至少与第二敏化剂化合物的第二三重能带部分重叠。
• Capsule suitable for non-invasive simultaneous oxygen content and temperature sensing in a living object
  申请人：MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V.

  公开号：US10739334B2

  公开（公告）日：2020-08-11

  A capsule suitable for oxygen and temperature sensing contains: i) at least one first sensitizer compound being capable of energy transfer to triplet oxygen, ii) at least one compound being capable of reacting with and inactivating singlet oxygen, iii) at least one second sensitizer compound being capable of absorbing radiation at a second frequency v2 and of emitting light at a fourth frequency v4, iv) at least one emitter compound, wherein the at least one second sensitizer compound is capable of transferring energy to the at least one emitter compound and wherein the at least one emitter compound, after obtaining energy transferred from the at least one second sensitizer compound, is capable of emitting light at a third frequency v3, wherein the following equation is fulfilled: v3>v2, wherein the upper energy limit of the first triplet energy band of the first sensitizer compound is lower than the lower energy limit of the second triplet energy band of the second sensitizer compound and lower than the lower energy limit of the third triplet energy band of the emitter compound, and wherein the third triplet band of the emitter compound at least partially overlaps with the second triplet energy band of the second sensitizer compound.

  适用于氧气和温度传感的胶囊包括 i) 至少一种能与三重态氧发生能量转移的第一敏化剂化合物、 至少一种能与单线态氧反应并使其失活的化合物、 iii) 至少一种第二敏化剂化合物能够以第二频率 v2 吸收辐射，并以第四频率 v4 发射光、 iv) 至少一种发射器化合物，其中至少一种第二敏化剂化合物能够将能量传递给至少一种发射器化合物，其中至少一种发射器化合物在获得至少一种第二敏化剂化合物传递的能量后，能够以第三频率 v3 发射光，其中满足以下等式：v3>v2、 其中，第一敏化剂化合物的第一三重能带的能量上限低于第二敏化剂化合物的第二三重能带的能量下限，且低于发射器化合物的第三三重能带的能量下限，发射器化合物的第三三重能带至少与第二敏化剂化合物的第二三重能带部分重叠。
• LONG-TERM STABLE PHOTOACTIVE COMPOSITION, SUCH AS PHOSPHORESCENT COMPOSITION OR TTA-PHOTON UPCONVERSION COMPOSITION
  申请人：MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V.

  公开号：US20160222286A1

  公开（公告）日：2016-08-04

  A long-term stable photoactive composition, namely a phosphorescent composition or a TTA-photon upconversion composition, contains: a) at least one compound, which has a triplet state capable of energy transfer via an emissive process or a non-emissive process, wherein the at least one compound having a triplet state is i) at least one phosphorescent compound and/or ii) at least one sensitizer compound being capable of absorbing radiation at a first frequency v 1 and at least one emissive compound, wherein the at least one sensitizer compound is capable of transferring energy to the at least one emissive compound and wherein the at least one emissive compound, after obtaining energy transferred from the at least one sensitizer compound, is capable of emitting light at a second frequency v 2 , wherein the following equation is fulfilled: v 2 >v 1 , wherein the at least one sensitizer compound is capable of a triplet-triplet energy transfer to the at least one emissive compound and wherein the at least one emissive compound is preferably capable of a triplet-triplet annihilation, and b) at least one compound capable of reacting with singlet oxygen, wherein the at least one compound capable of reacting with singlet oxygen comprises at least one terminal unsaturated carbon-carbon bond and is selected from the group consisting of compounds having anyone of the general formulae (I) to (X).
• US4287042A
  申请人：——

  公开号：US4287042A

  公开（公告）日：1981-09-01