nickel(II) sulfite | 7757-95-1

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: nickel(II) sulfite
• 英文别名: nickel sulphite；nickel sulfite；nickel (II) sulfonate；nickel(2+);sulfite
• CAS: 7757-95-1
• 化学式: Ni*O₃S
• 分子量: 138.754
• InChiKey: LONQOCRNVIZRSA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.01
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  82.4
• 氢给体数：
  0
• 氢受体数：
  4

ADMET

毒理性

• 副作用

皮肤致敏剂 - 一种可以诱导皮肤产生过敏反应的制剂。

Skin Sensitizer - An agent that can induce an allergic reaction in the skin.

来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

反应信息

• 作为反应物：
  描述：

  nickel(II) sulfite 以 neat (no solvent) 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  Erdoes, E., Collection of Czechoslovak Chemical Communications, 1962, vol. 27, p. 1428 - 1437

  摘要：

  DOI：
• 作为产物：
  描述：

  nickel(II) hydrazinesulfinate 以 neat (no solvent) 为溶剂， 生成 nickel(II) sulfite 、 nickel(II) sulfide
  参考文献：
  名称：

  Thermal degradation kinetics of Co(II), Ni(II), and Zn(II) hydrazinesulfinates in air, oxygen and nitrogen atmospheres

  摘要：

  Cobalt, nickel and zinc hydrazinesulfinate complexes of the molecular formula M(N2H3SOO)(2) where M=Co, Ni and Zn, respectively, have been prepared and characterized by analytical and spectral techniques. The thermal decomposition of these complexes have been studied in three different atmospheres, viz. static air, oxygen and nitrogen. In static air, cobalt and zinc complexes give respective metal sulfites while the nickel complex yield nickel sulfate. In oxygen atmosphere, cobalt complex gives a mixture of oxide and sulfate while the nickel and zinc complexes yield the respective metal oxide. In the nitrogen atmosphere, the complexes decompose to yield a mixture of metal sulfide and metal sulfite in the case of cobalt and nickel while zinc complex gives ZnO. The above complexes have also been subjected to sudden heating at high temperatures ca. 500degreesC, i.e. combustion, which resulted in the formation of metal oxide in the case of cobalt while the nickel complex gives nickel sulfide as the final product. However, the zinc complex gives mixture of zinc oxide and zinc sulfate. The kinetic parameters were evaluated for these complexes using Coats-Redfern equation. The parameters have been studied on the basis of TG-data and in most of the cases, the decomposition is found to follow first order kinetics. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(02)00395-7

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: MVol.B2, 1.7, page 562 - 582
  作者：

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  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: MVol.B2, 1.5.3, page 498 - 514
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: MVol.B1, 125, page 273 - 275
  作者：

  DOI：——

  日期：——
• Fordos, M.-J.; Gelis, A., Journal fur praktische Chemie (Leipzig 1954), 1843, vol. 29, p. 288 - 294
  作者：Fordos, M.-J.、Gelis, A.

  DOI：——

  日期：——
• Schweitzer, P., American Chemist, 1871, vol. 1, p. 296 - 298
  作者：Schweitzer, P.

  DOI：——

  日期：——