dipyrido<1,2-a:2',1'-f>-1,3,4,6-tetraazapentalene | 100460-12-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并[1，2-a]吡啶
• 英文名称: dipyrido<1,2-a:2',1'-f>-1,3,4,6-tetraazapentalene
• 英文别名: Lkcosovcyrgfcy-uhfffaoysa-；2,8,10,16-tetrazatetracyclo[7.7.0.02,7.011,16]hexadeca-1(9),3,5,7,10,12,14-heptaene
• CAS: 100460-12-6
• 化学式: C₁₂H₈N₄
• 分子量: 208.222
• InChiKey: LKCOSOVCYRGFCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dipyrido<1,2-a:2',1'-f>-1,3,4,6-tetraazapentalene 、 乙醇 以48%的产率得到
  参考文献：
  名称：

  PEREIRA, DAVID E.;PETRIC, ANDREJ;LEONARD, NELSON J., TETRAHEDRON, 44,(1988) N 11, 3149-3158

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(2-pyridylamino)imidazo<1,2-a>pyridine 在 碘苯二乙酸 作用下， 以 various solvent(s) 为溶剂， 反应 0.5h， 生成 dipyrido<1,2-a:2',1'-f>-1,3,4,6-tetraazapentalene
  参考文献：
  名称：

  Access to the 1,3,4,6-tetraazapentalene ring system

  摘要：

  DOI：

  10.1016/s0040-4039(00)94895-0

文献信息

• A masked [π8 + π2] cycloaddition reaction involving the 1,3,4,6-tetraazapentalene ring system
  作者：David E Pereira、Nelson J Leonard

  DOI：10.1016/s0040-4039(00)84928-x

  日期：1986.1

  Dipyrido[1,2-2′,1′-]-1,3,4,6-tetraazapentalene () undergoes an [α8 + α[2] cycloaddition reaction with dimethyl acetylenedicarboxylate to give, upon CN bond cleavage, a substituted 1-azacycl[3.2.2]azine ().

  吡啶并[1,2- 2'，1'- ] -1,3,4,6- tetraazapentalene（ ）经历了一个[ α 8 + α [2]环加成反应与乙炔二，得到，在CN键裂解，取代的1-氮杂环[3.2.2]嗪（）。
• CRUICKSHANK, K. A.;SUMOTO, KUNIHIRO;LEONARD, N. J., TETRAHEDRON LETT., 1985, 26, N 23, 2723-2726
  作者：CRUICKSHANK, K. A.、SUMOTO, KUNIHIRO、LEONARD, N. J.

  DOI：——

  日期：——
• PEREIRA, DAVID E.;PETRIC, ANDREJ;LEONARD, NELSON J., TETRAHEDRON, 44,(1988) N 11, 3149-3158
  作者：PEREIRA, DAVID E.、PETRIC, ANDREJ、LEONARD, NELSON J.

  DOI：——

  日期：——
• PEREIRA D. E.; LEONARD N. J., TETRAHEDRON LETT., 27,(1986) N 35, 4129-4132
  作者：PEREIRA D. E.、 LEONARD N. J.

  DOI：——

  日期：——
• Transparent contacts for organic devices
  申请人：Forrest R. Stephen

  公开号：US20070132369A1

  公开（公告）日：2007-06-14

  A multicolor organic light emitting device employs vertically stacked layers of double heterostructure devices which are fabricated from organic compounds. The vertical stacked structure is formed on a glass base having a transparent coating of ITO or similar metal to provide a substrate. Deposited on the substrate is the vertical stacked arrangement of three double heterostructure devices, each fabricated from a suitable organic material. Stacking is implemented such that the double heterostructure with the longest wavelength is on the top of the stack. This constitutes the device emitting red light on the top with the device having the shortest wavelength, namely, the device emitting blue light, on the bottom of the stack. Located between the red and blue device structures is the green device structure. The devices are configured as stacked to provide a staircase profile whereby each device is separated from the other by a thin transparent conductive contact layer to enable light emanating from each of the devices to pass through the semitransparent contacts and through the lower device structures while further enabling each of the devices to receive a selective bias. The devices are substantially transparent when de-energized, making them useful for heads-up display applications.

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