4'-cyanobiphenyl-4-yl 4-{[6-(acryloyloxy)hexyl]oxy}benzoate | 130166-92-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4'-cyanobiphenyl-4-yl 4-{[6-(acryloyloxy)hexyl]oxy}benzoate
• 英文别名: 4[4[6-Acryloxyhex-1-yl)oxyphenyl]carboxy-biphenyl-4'-carbonitrile；[4-(4-cyanophenyl)phenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• CAS: 130166-92-6
• 化学式: C₂₉H₂₇NO₅
• 分子量: 469.537
• InChiKey: XJSHMVGXIABVNW-UHFFFAOYSA-N

物化性质

• 熔点：
  110-111 °C
• 沸点：
  649.2±55.0 °C(Predicted)
• 密度：
  1.21±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  35
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  85.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-(6-(丙烯酰氧基)己氧基)苯甲酸 在 4-二甲氨基吡啶 、 三乙胺 、 fluoro-N,N,N',N'-tetramethylformamidinium hexafluorophosphate 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 生成 4'-cyanobiphenyl-4-yl 4-{[6-(acryloyloxy)hexyl]oxy}benzoate
  参考文献：
  名称：

  TFFH as an Excellent Reagent for Acylation of Alcohols, Thiols and Dithiocarbamates

  摘要：

  描述了一种使用TFFH作为偶联剂，从相应的羧酸合成酯和硫酯的方便且简单的程序。还描述了使用TFFH作为偶联剂，从羧酸和1,3-噻唑烷-2-硫酮制备N-酰基二硫代氨基甲酸盐的方法。

  DOI：

  10.1055/s-2004-831250

文献信息

• Photoresponsive Heterocyclic Azo Compound, Method for Producing the Same, and Optical Information Recording Medium
  申请人：Fukuda Takashi

  公开号：US20070242322A1

  公开（公告）日：2007-10-18

  There are provided a novel optical information recording material or medium excellent in various holographic optical information recording properties such as sensitivity, response speed, long-term storage stability, and repeatability, and a substance therefor. A photoresponsive heterocyclic azo compound contains an oligomer or polymer having a photoresponsive moiety in at least one of the main chain and side chain, and the photoresponsive moiety is a building block represented by the following formula (1): wherein HC 1 and HC 2 each represent a ring structure, at least one of them being a heterocyclic structure containing 1 or more heteroatom in the ring, R 1 and R 2 each represent a hydrogen atom or a substituent connected to the ring structure and may be the same or different ones, s and t each represent the number thereof, and X 1 and X 2 each represent a terminal group or a linking group, at least one of them being a linking group connected to the main chain of the oligomer or polymer and the terminal group being a hydrogen atom or a substituent.

  提供了一种新型的光学信息记录材料或介质，具有各种全息光学信息记录性能，如灵敏度、响应速度、长期存储稳定性和重复性，以及一种物质。一种光响应杂环偶氮化合物包含在主链和侧链中至少有一个具有光响应基团的寡聚物或聚合物，其中光响应基团是由以下公式（1）表示的构建块：其中HC1和HC2各代表一个环结构，其中至少一个是含有1个或多个杂原子的杂环结构，R1和R2各代表氢原子或连接到环结构的取代基，可以是相同或不同的，s和t各代表其数量，X1和X2各代表端基或连接基团，其中至少一个是连接到寡聚物或聚合物的主链的连接基团，而端基是氢原子或取代基。
• Side-chain liquid crystal polymer, liquid crystal composition, retardation film, method for producing retardation film, transfer laminate, optical member, method for producing optical member, and display device
  申请人：DAI NIPPON PRINTING CO., LTD.

  公开号：US11332670B2

  公开（公告）日：2022-05-17

  A side-chain liquid crystal polymer including two or more kinds of constitutional units represented by the following general formula (I) and a liquid crystal constitutional unit which contains a side chain including a liquid crystal moiety, where the two or more kinds of constitutional units represented by the general formula (I) include a constitutional unit (a) represented by the general formula (I) and a constitutional unit (b) which is represented by the general formula (I) and is different from the constitutional unit (a) in carbon atom number of a linking group represented by L1 or L1′. The general formula (I) is:

  一种侧链液晶聚合物，包括两种或两种以上由以下通式(I)表示的构型单元和一种液晶构型单元，该液晶构型单元含有包括液晶分子的侧链，其中由通式(I)表示的两种或两种以上的构型单元包括由通式(I)表示的构型单元(a)和由通式(I)表示的构型单元(b)，后者与由L1或L1′表示的连接基团的碳原子数不同于构型单元(a)。通式(I)为
• US20140256896A1
  申请人：——

  公开号：US20140256896A1

  公开（公告）日：2014-09-11
• POLYMERIZABLE COMPOSITION AND FILM USING THE SAME
  申请人：DIC Corporation

  公开号：US20170190819A1

  公开（公告）日：2017-07-06

  It is an object of the present invention to provide a polymerizable liquid crystal composition that has an excellent storage stability and that enables a film formed by application of the composition to a base material and the subsequent exposure to heat or active energy rays to have a good adhesion to the base material. It is another object of the present invention to provide an optically anisotropic body that is produced using such a polymerizable composition and that has a good orientation. In particular, the present invention provides a polymerizable liquid crystal composition containing a polymerizable adhesion enhancer and a polymerizable liquid crystal compound. In addition, the present invention also provides an optically anisotropic body containing such a polymerizable liquid crystal composition.
• COMPOSITION FOR OPTICAL FILM, OPTICAL FILMS, ANTIREFLECTION FILMS, AND DISPLAY DEVICE
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20170212287A1

  公开（公告）日：2017-07-27

  A composition for an optical film including a liquid crystal, and polysiloxane including a structural unit represented by Chemical Formula 1A and a structural unit represented by Chemical Formula 1B: wherein, in Chemical Formulae 1A and 1B, groups L 1 , L 2 , R 1 , R 2 , X, and Y are the same as in the detailed description.